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Monitoring the Dynamic Process of Formation of Plasmonic Molecular Junctions during Single Nanoparticle Collisions 下载免费PDF全文
Jing Guo Jie Pan Shuai Chang Xuewen Wang Na Kong Wenrong Yang Jin He 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(15)
The capability to study the dynamic formation of plasmonic molecular junction is of fundamental importance, and it will provide new insights into molecular electronics/plasmonics, single‐entity electrochemistry, and nanooptoelectronics. Here, a facile method to form plasmonic molecular junctions is reported by utilizing single gold nanoparticle (NP) collision events at a highly curved gold nanoelectrode modified with a self‐assembled monolayer. By using time‐resolved electrochemical current measurement and surface‐enhanced Raman scattering spectroscopy, the current changes and the evolution of interfacial chemical bonding are successfully observed in the newly formed molecular tunnel junctions during and after the gold NP “hit‐n‐stay” and “hit‐n‐run” collision events. The results lead to an in‐depth understanding of the single NP motion and the associated molecular level changes during the formation of the plasmonic molecular junctions in a single NP collision event. This method also provides a new platform to study molecular changes at the single molecule level during electron transport in a dynamic molecular tunnel junction. 相似文献
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本文从实际应用出发,详尽论述了“智能耳诊机”软、硬件设计的方法。对从事单片机开发应用的工程技术人员有较高的参考价值。 相似文献
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High quality single crystals of YBa2Cu3O7- (YBCO) have been grown in yttria-stabilized zirconia crucibles by using a flux method. This method yields crystals with area 3 to 4 times larger than a previous method, and 3 to 5 times more crystals. Several crystals as large as 3×4mm2 in thea-b plane are routinely obtained from each crucible. The samples typically range from 10 to 60 m thick. The superconductivity transition temperatureT
c
of the crystals, measured by magnetic susceptibility, falls in the range 92.5 to 93 K and the smallest transition width (10 to 90%) is less than 0.25 K. Compared with the previous method, the surface is generally smoother, with less flux, and larger untwinned regions of 1 x 1 mm2 are usually found. 相似文献
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Crystalline zinc oxide particles of nanometre size (< 20 nm) particles were produced from a zinc acetate solution by using a filter expansion aerosol generator (FEAG). The FEAG is an aerosol generator that is operated at 60 torr reactor pressure and produces droplets of around 2 m. The shape of the particles produced by the FEAG were distinctively different from those produced by the ultrasonic spray source (USS). Results from scanning electron microscopy (SEM) and X-ray diffractometry (XRD) indicated that crystalline zinc oxide particles of nanometre size were produced at 600 °C in 0.02 s residence time. Weight loss of these particles, determined by thermogravimetric analysis (TGA), was 3 wt%. Based on the morphology change as a function of the reactor temperature and solute concentration, we proposed that the nanometre particles were formed by uniform precipitation at the drying stage and decomposition followed by disintegration into nanometre particles. It was also shown that exothermic decomposition of the solute was not required for the disintegration of the primary particles in the FEAG process. This result opened up an opportunity for producing carbon-free nanometre particles from nitrate salts by using the FEAG. 相似文献
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近年来,支持多标准的LDPC译码器已逐渐成为研究的热点.与传统译码器相比,所设计的LDPC译码器具有以下优点:1.实现了一个码率、码长可配置结构,进而可以支持多种标准;2.采用了一种改进型TPMP算法,使译码器的存储器容量大大减少,避免了因分块LDPC码的非规则性所造成的数据冲突问题;3.采用基于SIMD处理器的硬件结构,实现了硬件的高度规整性,易于芯片布局布线;4.设计了一个6级可配置流水线,可分时构造校验节点处理单元和变量节点处理单元,提高了硬件利用率和系统数据吞吐率.用这种架构实现了一个同时支持CMMB和DTMB两个标准的多标准LDPC译码器;芯片规模为75万门,时钟频率为220MHz,数据吞吐率为300Mbps. 相似文献
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