Preparation of branched polyacrylonitrile through self‐condensing vinyl copolymerization

Branched polyacrylonitrile (PAN) was prepared through a self‐condensing vinyl copolymerization of acrylonitrile and 2‐(2‐bromopropionyloxy)ethyl acrylate (BPEA). The branched architecture of the product was confirmed by NMR spectra and the average degree of branching (DB ) was estimated. Through a comparison of the intrinsic viscosity of the product with that of its linear analogue, the contraction factor g′ was calculated. It was found that the viscosity of the branched PAN was obviously lower that that of linear PAN. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Preparation and adsorption behavior of a cellulose‐based,mixed‐mode adsorbent with a benzylamine ligand for expanded bed applications

A novel mixed‐mode expanded bed adsorbent with anion‐exchange properties was explored with benzylamine as the functional ligand. The cellulose composite matrix, densified with stainless steel powder, was prepared with the method of water‐in‐oil suspension thermal regeneration. High activation levels of the cellulose matrix were obtained with allyl bromide because of the relative inertness of the allyl group under the conditions of the activation reaction. After the formation of the bromohydrin with N‐bromosuccinimide and coupling with benzylamine, the activated matrix was derived to function as a mixed‐mode adsorbent containing both hydrophobic and ionic groups. The protein adsorption capacity was investigated with bovine serum albumin as a model protein. The results indicated that the prepared adsorbent could bind bovine serum albumin with a high adsorption capacity, and it showed salt tolerance. Effective desorption was achieved by a pH adjustment across the isoelectric point of the protein. The interactions between the cell and adsorbent were studied, and the bioadhesion was shielded by the adjustment of the salt concentration above 0.1M. Stable fluidization in the expanded bed was obtained even in a 2% (dry weight) yeast suspension. The direct capture of target proteins from a biomass‐containing feedstock without extra dilution steps could be expected with the mixed‐mode adsorbent prepared in this work, and this would be especially appropriate for expanded bed adsorption applications. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Establishing a System for Food Recalls to Protect Food Quality and Safety in China

There are no explicit laws concerning food recalls in China; moreover, some related regulations have weaknesses. China should first create a system of laws and regulations governing food recalls, establish a system to recall defective food, and strengthen administrative and legal remedial mechanisms related to consumer rights.     

Low-Temperature Annealing Effect of RF Inductor With FeNi-SiO2 Granular Film

A low-temperature annealing process in vacuum is proposed to enhance the inductance of RF inductors with FeNi-SiO₂ magnetic granular films. Due to the great improvement of soft magnetic property in the 200degC and 350degC annealed film, the inductance is enhanced by 9.6% (200degC) and 8.3% (350degC), respectively, compared with the case of as-deposited film inductor. The peak value of quality factor, which is 9.18 for the as-deposited film inductor, is also increased to 9.27 (200degC ) and 12.27 (350degC), respectively.     

浅析改进的SET协议在电子商务中的作用

随着网络的发展，电子商务越来越引起人们的注意，如何保证传输数据的安全性成为电子商务能否普及的最重要因素之一。本文根据信息隔离和隐藏的原则改进了SET协议，改进后的SET协议允许持卡人参与帐目汇报，以及在电子商务中提供信用卡代理以便隐藏信用卡卡号。改进后的SET协议可有效对抗小范围内交易的机密侵密和大范围内的数据聚合。     

冷却水污垢及其对冷却器换热的影响

分析了冷却器的结垢机理 ,提出了冷却器污垢层、污垢热阻随运行时间的规律 ,以及污垢热阻与换热系数、换热面积的关系式 ,并通过算例阐述了污垢热阻对冷却器的影响程度 ,进而定性地分析了污垢热阻对空分装置的影响。     

一种网络服务自动部署方法

为满足网络服务使用者对网络服务部署的功能性和非功能性需求,运用Petri网的方法进行了互联网动态多变环境下的网络服务自动部署的研究,建立了一种基于Petri网的网络服务部署网模型,从形式化的角度描述了网络服务功能的部署情况,提出了一种按照服务质量来选择最优网络服务部署的算法。仿真的结果表明,与目前常用的固定部署算法和随机部署算法相比,按照该方法得到的网络服务部署能最好地满足服务使用者对服务的非功能性方面的需求。     

添加VC的TiB2基硬质材料研究

对添加VC的TiB2基硬质材料进行了研究。通过实验测定了硬度、横向断裂强度、高温强度以及耐磨性等性能，通过观察SEM照片研究了VC对TiB2基硬质材料组织结构的影响。综合各种指标，我们确定在TiB2-Fe—Mo硬质材料中VC的最佳添加量为0．5％。     

改性β沸石上合成1,4-二氧六环的研究

在真空条件下将改性 β沸石用于二甘醇合成 1,4 -二氧六环的反应 ,考察了反应温度、反应时间和催化剂用量对催化剂活性的影响 ,并对该催化剂的稳定性进行了考察。结果表明 ,在最佳反应条件下 ,二甘醇转化率达到 89 6 9% ,1,4 -二氧六环的选择性达到 95 0 1%。