基于微博重复发送的垃圾用户甄别

针对微博平台上的垃圾用户甄别问题,本文提出了基于微博重复发送行为的垃圾用户行为建模和甄别算法。在真实微博垃圾用户数据分析的基础上,本建模方法综合考虑了微博垃圾用户的行为信息、社交网络信息和文本信息,从不同的角度对垃圾用户进行了分析和建模。在真实数据集上的实验证明了方法的有效性,并且对模型中若干参数进行了优化,同时也分析了垃圾用户行为信息、社交网络信息和文本信息对模型的影响程度。     

基于模糊控制的组合式焊接电源的研究

针对大功率焊机电源功率合成结构复杂,稳定性不高等问题,设计一种基于模糊PID的组合式焊机电源.系统采用分散逻辑控制法解决并联系统中出现的环流问题,同时利用CAN总线实现模块间实时通信,改变了传统功率合成中单机孤立运行模式,保证了系统安全稳定运行.与传统的控制策略相比,模糊控制具有不依赖于精确数学模型,鲁棒性较强,控制方式简单等优点.实验结果表明,该系统具有较宽的功率调节范围,性能稳定可靠.     

Endemic error correction model and quantitative analysis of precise point positioning

To identify the endemic error of the precise point positioning which cannot be weakened or eliminated in precise point positioning (PPP) zero-difference model, the 24 h observation data acquired from CHAN station on Oct 31st, 2010, were adopted for analyses, different correction models of various errors were discussed and their influences on traditional zero-difference model were analyzed. The results show that the errors cannot be ignored. They must be corrected with suitable models and estimated with auxiliary parameters. The influence magnitudes of all errors are defined, and the results have guiding significance to improve the accuracy of precise point positioning zero-difference model.     

两台变压器的经济运行对节能降损的影响分析

随着能源的日益短缺,各行各业对节能降损越来越重视.在电力行业中,配网损耗中的60％是由变压器贡献的,因此实现变压器的经济运行对用电企业的节能降损具有重要要义.以江门地区某工厂为实例进行了计算论证,针对性的提出了两台同容量和不同容量变压器经济运行的方法.     

低渗透污染土水动力弥散参数试验研究

污染土的治理中通常采用降低渗透性的措施来控制其二次污染。通过获得其水动力弥散参数可以对其二次污染进行评价和预测,但是现有的土柱试验以及求解方法不适用于低渗透污染土水动力弥散参数的测定和求解。针对低渗透污染土水动力弥散参数试验和求解的问题,提出采用改进的柔性壁渗透仪测定其污染物的穿透曲线,根据所获得的穿透曲线,采用数值反演的方法计算污染土的水动力弥散参数。结果表明,采用柔性壁渗透仪和数值反演的方法,能够满足低渗透污染土水动力弥散参数测定的需要。     

Study on conductivity and redox stability of iron orthovanadate

FeVO₄ was synthesised by conventional solid state technique. Impedance measurements using a silver electrode were unsuccessful due to a solid state reaction between FeVO₄ and Ag, forming α-AgVO₃ and α-Fe₂O₃ at the interface. Impedance measurements, with a platinum electrode, reaffirmed that FeVO₄ exhibits semiconductor behaviour in air. In a reducing atmosphere, 5% H₂/Ar, high electronic conductivity, from 1 S cm⁻¹ at 300 °C to 2 S cm⁻¹ at 700 °C, was observed with an activation energy of 0.13(1) eV. X-ray diffraction, thermogravimetric analysis and differential scanning calorimetry data determined that the change in electronic conductivity was due to the degradation of the material into FeV₂O₄ and α-Fe₂O₃. It is believed that the conduction was due to electron hopping between vanadium d-orbitals. Neither FeVO₄ nor FeV₂O₄ are deemed suitable as anode materials for solid oxide fuel cells, due to redox instability.     

原位化学氧化接枝聚合法制备PANI/AMTES-ATP复合材料

首先用偶联剂苯胺甲基三乙氧基硅烷(AMTES)对凹凸棒土(ATP)进行表面修饰(AMTES-ATP),然后通过苯胺单体在AMTES-ATP表面的原位化学氧化接枝聚合,制备了基于共价键结合的聚苯胺(PANI)/AMTES-ATP复合材料.利用透射电镜(TEM),红外光谱(FTIR),X射线衍射(XRD),紫外-可见漫反射光谱(UV-vis-DRS)和热重-差热(TG-DTA)分析等技术对复合材料进行了表征.结果表明,复合材料中PANI高分子链是通过偶联剂AMTES以化学键的方式与ATP相结合的,AMTES的桥连作用增加了两相间的接触面积,使PANI在ATP表面形成均匀的包覆层.PANI与ATP之间存在较强的相互作用力,限制了PANI的生长和结晶.由于ATP表面的界电限域效应,使PANI以伸展分子链构象存在.ATP的加入和两相间作用力的存在使复合材料中PANI的热稳定性能有明显的提高.     

3-丙酰氨基-N,N-二丙酸甲酯基苯胺的合成研究

用无水三氯化铝作催化剂在较低温度下将3-氨基丙酰苯胺和丙烯酸甲酯转化为3-丙酰氨基-N,N-二丙酸甲酯基苯胺,其产品收率达到89%,纯度高于92%。     

Photoluminescence of face-centered-cubic structure silicon nanoparticles deposited by pulsed laser ablation

Face-centered-cubic(fcc) structure silicon nanoparticles(Si-nps) are synthesized by using nanosecond pulse excimer laser ablation of Si target in Ar ambient.The nonequilibrium environment caused by the plume confined in argon ambient gas is responsible for the formation of fcc Si-nps.Photoluminescence(PL),transmission electron microscopy,and X-ray photoelectron spectroscopy are used to characterize these Si-nps.Broad PL spectrum is obtained with a double-peak at 403 and 503 nm by an exciting laser of 325 nm...