颗粒增强铝基涂层的组织结构与摩擦学性能

选用常规微米尺度Al2O3粉体和纳米结构Al2O3-TiO2粉体作为硬质颗粒,采用等离子喷涂方法在45钢基体上制备了Al2O3/Al2O3-TiO2颗粒增强铝基复合涂层,采用扫描电镜(SEM)、X射线衍射仪(XRD)和维氏硬度计观察和测试涂层的形貌、物相及显微硬度,通过滑动摩擦磨损试验分析涂层的摩擦学性能。结果显示,Al/Al2O3涂层的表面形貌和纯铝涂层非常相似,Al/Al2O3-TiO2涂层表面可以看到未熔、半熔和全熔的增强相存在。Al/Al2O3涂层的主要物相为Al和α-Al2O3,Al/Al2O3-TiO2涂层的主要物相为Al、α-Al2O3和TiO。随着增强相加入量的提高,Al/Al2O3涂层和Al/Al2O3-TiO2涂层的硬度不断提高;当添加量为30%时,硬度分别比未加增强相时提高了67%和76%。加入增强相的涂层的平均摩擦因数都有较大幅度的减小,加入30%Al2O3的Al/Al2O3涂层的磨损量比未加入增强相涂层的磨损量下降85.6%,Al/Al2O3-TiO2涂层的磨损量比未加入增强相涂层的磨损量下降74%左右,表明硬质颗粒Al2O3和Al2O3-TiO2的加入,可显著提高涂层的耐磨性。     

Nanocomposite Lanthanum Zirconate Thermal Barrier Coating Deposited by Suspension Plasma Spray Process

This work seeks to develop an innovative nanocomposite thermal barrier coating (TBC) exhibiting low thermal conductivity and high durability compared with that of current TBCs. To achieve this objective, nanosized lanthanum zirconate particles were selected for the topcoat of the TBC system, and a new process—suspension plasma spray—was employed to produce desirable microstructural features: the nanocomposite lanthanum zirconate TBC contains ultrafine splats and high volume porosity, for lower thermal conductivity, and better durability. The parameters of plasma spray experiment included two main variables: (i) spray distance varying from 40 to 80 mm and (ii) the concentration of suspension 20, 25, and 30 wt.%, respectively. The microstructure of obtained coatings was characterized with scanning electron microscope and x-ray diffraction. The porosity of coatings is in the range of 6-10%, and the single phase in the as-sprayed coatings was pyrochlore lanthanum zirconate.     

Review of laser welding monitoring

Laser welding, as a highly efficient processing technology, has been widely applied to manufacturing industry. This paper makes an overview on real time monitoring of laser welding. It begins with a detailed introduction to six typical sensors (photodiode, visual, spectrometer, acoustical sensor, pyrometer, plasma charge sensor) in laser welding detection. Then it makes a review on multi-sensor fusion technology in both laser welding monitoring and adaptive control. Last, subjects for future research concerning welding monitoring and control have been proposed. The paper concludes that the real-time monitoring of laser welding can provide a great amount of valid information about welding status to help effectively identify weld defects and realize adaptive control.     

大口径光学元件斜入射反射波前误差测量和计算

针对测量高功率激光驱动装置中大口径矩形反射光学元件的波前误差时测量角度和使用角度不完全相同引入的测量误差,提出了将测量角度下的反射波前转换到使用角度的反射波前的换算及恢复方法。首先分析了将斜入射测量角度下的波前转换到使用角度下波前的余弦换算方法,得到了实际测量角度与实际使用角度下的波前误差计算关系;然后计算并分析了双三次插值算法本身引起的中频PSD1(功率谱密度)误差,指出在满足有效口径测量的情况下,选择的入射角度应该与实际使用的角度尽可能的相接近。最后,基于410mm×410mm的熔石英反射镜开展了误差分析和实验验证。利用该方法将0°反射波前换算到45°反射波前,并将得到的测试结果与45°直接测量得到的测试结果进行了比较。结果显示上述结果的PV值相差0.01λ,RMS值相差0.003λ,PSD1值相差0.08nm;表明该换算方法不仅能够准确计算出使用角度下反射波前的低频误差,而且能获得相对准确的中频段PSD1误差。     

Modeling single chain elasticity of single-stranded DNA: A comparison of three models

The dominant models of polymers, i.e., the freely jointed chain (FJC) model, the wormlike chain (WLC) model and the freely rotating chain (FRC) model are modified by integrating the inherent single-molecule elasticity obtained from quantum mechanics (QM) ab-initio calculations. The QM modified models have been utilized to generate fitting curves for single-stranded DNA obtained in organic solvent. The analyses on the deviation between the fitting curve and the experimental force curve demonstrate that the QM-FRC and QM-FJC model are suitable for ssDNA, but not the QM-WLC model. We also find that one repeating unit of ssDNA is corresponding to a Kuhn segment in QM-FJC model or two rotating units in QM-FRC. Having close correlation to the inherent elasticity and real molecular structure of the polymer, QM-FJC and QM-FRC are emerging as structure relevant models.     

Solid polymerization and supramolecular chirality formation of azobenzene substituted diacetylene Langmuir–Blodgett films

An azobenzene mesogen-substituted diacetylene (NADA) monolayer has been transferred onto the solid substrate by the traditional Langmuir–Blodgett (LB) method. Solid-state polymerization of NADA LB films can be sensitized in visible light region. In situ UV–vis absorption measurement enables us to study polymerization kinetics of NADA LB films. The polymerization process can be described as a first order rate equation and polymerization rate constants are characterized in detail. Furthermore, achiral NADA molecules can form chiral LB films through overcrowded packing of the azobenzene moiety.     

某住宅楼桩基工程事故分析与处理

通过分析某住宅楼桩基承载力未达到设计要求的原因 ,提出了桩基施工时注意事项。     

Separation of nickel, cobalt and copper by solvent extraction with P204

Separation of nickel, cobalt and copper by solvent extraction with P204@钱东 @王开毅 @潘春跃 @唐有根 @蔡春林 @蒋金枝~~Project ( 99JJY2 0 0 10 )supportedbytheNaturalScienceFoundationofHunanProvince     

福州软土固结状态初步分析

利用卡氏作图法可求取土层的前期固结压力Pc,结合计算出的土层自重压力Po,可获得土层的超固结比OCR.在收集有关资料的基础上,对福州软土的前期固结压力和超固结比进行数理统计和对比分析,进而对各层软土的固结状态作出评价和分析.     

基于Video Charger视频点播系统的设计与实现

探讨了VideoChagrger的逻辑组成、交互与配置方式，及详细的资源需求分析，给出了据此建立VOD系统的系列解决方案。