Photoinitiated crosslinking of ethylene‐vinyl acetate copolymers and characterization of related properties

Photoinitiated crosslinking of EVA in the presence of benzophenone (BP) as photoinitiator and triallyl isocyanurate (TAIC) as crosslinker and characterization of the related properties have been studied by gel determination, heat extension, DSC, DMTA, TGA, and mechanical measurements. The photoinitiated crosslinking efficiency of the EVA‐BP‐TAIC system and various factors affecting the crosslinking process, such as photoinitiator and crosslinker and their concentrations, irradiation temperature, and irradiation atmosphere were studied in detail and optimized by comparison of gel contents. The results show that the EVA samples with a thickness of 1 mm are readily crosslinked to a gel content of above 80% with 5 s UV‐irradiation under optimum conditions. The data from the heat extension and DSC show that the crosslinking density of photocrosslinked EVA increase and their crystallinities decrease with increasing the UV‐irradiation time. At the same time, photocrosslinking of EVA leads to a lowering of the melt temperature and a decrease of heat of fusion. The DMTA results show that photocrosslinking increases the amorphous phase and storage modulus of the crosslinked EVA, but does not change the glass transition temperature. The data from TGA and mechanical tests give evidence that the thermal stability and mechanical properties of photocrosslinked EVA samples are much better than those of the uncrosslinked EVA. POLYM. ENG. SCI., 47:1761–1767, 2007. © 2007 Society of Plastics Engineers     

Low-temperature catalytic combustion of methane over MnO x –CeO2 mixed oxide catalysts: Effect of preparation method

The effect of preparation method on MnO _x –CeO₂ mixed oxide catalysts for methane combustion at low temperature was investigated by means of BET, XRD, XPS, H₂-TPR techniques and methane oxidation reaction. The catalysts were prepared by the conventional coprecipitation, plasma and modified coprecipitation methods, respectively. It was found that the catalyst prepared by modified coprecipitation was the most active, over which methane conversion reached 90% at a temperature as low as 390 °C. The XRD results showed the preparation methods had no effect on the solid solution structure of MnO _x –CeO₂ catalysts. More Mn⁴⁺ and richer lattice oxygen were found on the surface of the modified coprecipitation prepared catalyst with the help of XPS analysis, and its reduction and BET surface area were remarkably promoted. These factors could be responsible for its higher activity for methane combustion at low temperature.     

Application of ACO algorithm in protein structure prediction

The hydrophobic-polar (HP) lattice model is an important simplified model for studying protein folding. In this paper, we present an improved ACO algorithm for the protein structure prediction. In the algorithm, the "lone"ethod is applied to deal with the infeasible structures, and the "oint mutation and reconstruction"ethod is applied in local search phase. The empirical results show that the presented method is feasible and effective to solve the problem of protein structure prediction, and notable improvements in CPU time are obtained.     

基于改进型类间方差分割的红外目标提取算法

文章对最大类间方差法进行了改进,利用计算图像类间方差的约束条件,通过构造罚函数,把求最大类间方差问题转换为求带约束条件的函数最优解问题,再用迭代法对图像进行分割,从而有效地弥补了最大类间方差法对图像噪音和目标大小敏感不足。仿真实验结果表明,该方法效果良好。     

一种高效的电子政务系统的设计与应用

计算机网络技术的出现,全球信息化改变着人们的生活方式,世界各国高度重视发展电子政务,它是一个国家及城市竞争力水平的标志之一.在这样严峻的社会形势下,建立一个高效的电子政务系统是十分必要的.首先,分析了建立电子政务系统的必要性、特点、功能;然后,提出了电子政务系统的体系模型,设计出了功能结构图和网络结构图,详细地描述了方案思路;最后,把此模型应用到商洛市旅游行业中,经过调查数据研究分析,政务系统的出现给旅游业带来巨大的变化,整个城市的经济、影响力大幅度上升.     

利用C_5开发叔戊基甲醚

介绍了利用C_5生产汽油抗爆剂叔戊基甲醚的工艺进程。其中KOCH公司开发的催化蒸馏工艺是目前最先进的工艺。我国当前尚未有工业化生产叔戊基甲醚的装置。利用流化催化裂化C_5生产叔戊基甲醚是急待开发的课题。     

Mathematical model of shear rate of polymer melt dynamic extruding through capillary

With superimposing a sine vibration of displacement on the extruding direction of a polymer melt, the characterization formula of the shear rate of a polymer melt within a capillary was set up. By making use of the experimental equipment of a constant velocity type dynamic rheometer of capillary (CVDRC) designed by the authors, the calculating steps of the shear rate of the polymer melt at the wall of the capillary under a vibration force field were established. Through measuring and analyzing the instantaneous data of capillary entry pressure, capillary volume rate, and their phase‐difference under the superimposed vibration, the polymer melt's shear rate at the wall of the capillary can thus be calculated. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1056–1061, 2005     

FGTO — A fine structured GTO-thyristor with improved switching characteristics

Contents A fine structured GTO thyristor, abbreviated FGTO, has been developed to improve the switching characteristics. The new device has a cathode finger width of only 20 m and can be turned off without a negative gate bias at an anode current level of more than 200 A/cm². The turn-off time can be shortened down tot _off 500 ns by increasing the negative gate current. A snubber circuit is not necessary to turn off the FGTO's. The maximum rate of rise of anode voltage du/dl reaches more than 10 kV/s. Analytical models are developed to describe the turn-off transients of the FGTO's. Good agreement between the theoretical and experimental results could be achieved.

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FGTO — Ein feinstrukturierter GTO-Thyristor mit verbessertem Schaltverhalten

Übersicht Zur Verbesserung des Schaltverhaltens ist ein feinstrukturierter GTO-Thyristor, abgekürzt FGTO, entwickelt worden. Dieses neue Bauelement hat eine Kathoden-streifenbreite von nur 20 m und kann ohne negative Gatevorspannung bei einer Anodenstromdichte von mehr als 200 A/cm² abgeschaltet werden. Die Abschaltzeit läßt sich durch Erhöhung des negativen Gatestroms bis zut _off 500 ns verkürzen. Beim Abschalten von FGTOs ist keine RC-Beschaltung erforderlich. Der maximale du/dl-Wert erreicht mehr als 10 kV/s. Zur Beschreibung des Abschalt-verhaltens von FGTOs werden analytische Modelle entwickelt, die eine gute Übereinstimmung mit den Meßergebnissen liefern.

     

基于人体骨骼关键点的吸烟行为检测算法

针对公共场所的监控视频中烟头目标较小并且吸烟产生的烟雾易发散,仅依靠目标检测算法检测烟头或者烟雾来判定吸烟行为存在较大难度的问题,考虑到利用骨骼关键点来进行姿态估计的算法越来越成熟,提出一种利用人体骨骼关键点和吸烟行为之间的关系来进行吸烟行为检测的算法。该算法首先利用AlphaPose和RetinaFace分别检测出人体骨骼关键点和脸部关键点信息,根据手腕到两嘴角中点和手腕到同侧眼睛的距离之比,提出一种计算人体的吸烟动作比例（SAR）是否属于吸烟动作黄金比例（GRSA）的方法以区分吸烟与非吸烟行为;再利用YOLOv4检测视频中是否存在烟头;最后结合GRSA判定和YOLOv4的结果来确定视频中存在吸烟行为的可能性高低,作出是否有吸烟行为的判定。经过笔者录制的数据集测试,结果表明所提算法可以准确检测到吸烟行为,准确率达到92%。     

Effect of deposition time on microstructures and growth behavior of ZrC coatings prepared by low pressure chemical vapor deposition with the Br<Subscript>2</Subscript>-Zr-C<Subscript>3</Subscript>H<Subscript>6</Subscript>-H<Subscript>2</Subscript>-Ar System

ZrC coatings were deposited on graphite substrates by low pressure chemical vapor deposition (LPCVD) with the Br₂-Zr-C₃H₆-H₂-Ar system. The effects of deposition time on the microstructures and growth behavior of ZrC coatings were investigated. ZrC coating grew in an island-layer mode. The formation of coating was dominated by the nucleation of ZrC in the initial 20 minutes, and the rapid nucleation generated a fine-grained structure of ZrC coating. When the deposition time was over 30 min, the growth of coating was dominated by that of crystals, giving a column-arranged structure. Energy dispersive X-ray spectroscopy showed that the molar ratio of carbon to zirconium was near 1:1 in ZrC coating, and X-ray photoelectron spectroscopy showed that ZrC was the main phase in coatings, accompanied by about 2.5mol% ZrO₂ minor phase.