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61.
By applying the Lefebvrian lens, this paper tries to understand why unlike previous similar cases, the latest removal of the Star Ferry and Queen’s Pier was so controversial. To Lefebvre, embedded in ‘spatial practices’ that ‘secrete’ a place are two contradicting spaces: ‘conceived spaces’ produced by planners to create exchange values and ‘lived spaces’ appropriated by citizens for use values. Applying Lefebvre’s framework to examine the ‘Piers saga’, it is found that the pre‐Second World War (WWII) piers were ‘conceived’ by spatial practices of a colonial and racially segregated trading enclave. The public space in the commercial heart that housed the previous generations of piers was not accessible to the Chinese community, thus denying them opportunities to appropriate them and turn them into ‘lived’ spaces. It was only after WWII when the Government carried out further reclamation to meet the needs of an industrializing economy that inclusive public spaces were conceived in the commercial heart, enabling the general public to ‘appropriate’ them as ‘lived’ space. When the Government planned to remove this very first ‘lived’ space in the political and economic heart of the city to conceive further reclamation for the restructuring economy, the more enlightened citizens were determined to defend it. 相似文献
62.
In this study, AOT [sodium bis(2-ethylhexyl) sulfosuccinate] combined with fluorinated cosurfactant or alcohol was used to form a water-in-CO2 (W/C) microemulsion. The amount of water uptake in the microemulsion was closely related to the PFPE-PO4/AOT (P/A) ratio. The stability of the microemulsion decreased with the amount of water. Lower temperature and higher pressure stabilize W/C microemulsions. The extraction efficiencies of metals (Cd, Co, Cu, Pb, Zn), when this W/C microemulsion method was used, exceeded 90% (AOT + octanol). The efficiencies for the extraction of Eu, La, and Sr could exceed 94% (AOT + PFPE-PO4) in sc-CO2. 相似文献
63.
Lukasz Pietrzak Przemyslaw Sowinski Joanna Bojda Ewa Piorkowska Andrzej Galeski 《应用聚合物科学杂志》2016,133(28)
We hypothesized that polymer crystal anisotropy is advantageous for toughening of polymer composites involving easy slip network of oriented crystalline layers around filler particles. To this end, composites of syndiotactic polypropylene (sPP) with high concentration of submicrometer calcium carbonate particles were prepared and examined because usual sPP crystals exhibit high packing anisotropy. The specific orientation of sPP lamellae around chalk grains was found, which is supposed to facilitate the plastic deformation of polymer matrices. The compression molded bars of the composite exhibited markedly higher Izod impact strength than those of neat sPP. Toughening was even enhanced in the injection molded composite, for which 4.5‐fold increase in the impact strength was achieved. Injection‐induced orientation of the disordered form I sPP crystals was enhanced in the composite. The injection molded tensile specimens exhibited also a good drawability. Debonding at chalk–sPP interface occurred both during the impact and tensile tests facilitating the plastic deformation of sPP matrix. Chalk did not have any significant influence on the thermal properties of the composites but it affected the rheological behavior, increasing the loss and storage moduli, and the viscosity. Highly filled sPP composite exhibited solid‐like behavior in a molten state with the storage modulus exceeding the loss modulus in the entire frequency range. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43651. 相似文献
64.
The influence of electron beam irradiation,plastic deformation,and re‐irradiation on crystallinity degree,mechanical and sclerometric properties of GUR 1050 used for arthroplasty
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Adrian Barylski Joanna Maszybrocka Marian Kupka Krzysztof Aniołek Łukasz Mieszczak 《应用聚合物科学杂志》2016,133(28)
The article describes the influence of an electron beam irradiation (I), plastic deformation (D), and re‐irradiation (R) on the properties of ultrahigh molecular weight polyethylene (GUR 1050). It was found that the modification through irradiation entailed a gradual increase in the degree of crystallinity (after irradiation–I). After plastic deformation and re‐irradiation (IDR) the degree of crystallinity decreases which had a direct influence on the mechanical properties. The polymer irradiation only (technique I) resulted in an increase in the maximum stress as compared with the material in the initial state. The application of deformation and re‐irradiation (technique IDR) allowed increasing the deformation resistance by more than 40%. Moreover, the irradiation with an electron beam resulted in the increase in hardness (H) and Young's modulus (E) proportionally to the applied irradiation dose and in the reduction of total indentation work (Wtot) and its components. After deformation and re‐irradiation the polyethylene hardness went down. The application of technique (I) caused an improvement to the material abrasion resistance (reduction of parameter PD–working scratch depth) with the increasing irradiation dose. The introduction of deformation and re‐irradiation did not have a material impact on parameter (PD) increasing at the same time elastic properties of UHMWPE (increase in parameter NPS–elastic recovery). Modification IDR has changed the wear mechanism (β) toward ploughing and has increased the abrasion‐resistance index (Wβ) and also significantly reduced the coefficient of friction (μ) of GUR 1050. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43683. 相似文献
65.
Wit Grzesik Krzysztof Żak Roman Chudy Mariusz Prażmowski Joanna Małecka 《CIRP Annals》2019,68(1):101-104
This paper presents the optimization procedure of a hybrid removal-forming type process based on the minimum energy consumption and demanded surface roughness which is supported by the analysis of transformation of the surface and sublayer properties termed as the technological heredity. The experimental investigation covers an alloy steel hardened to 35 HRC and 55 HRC which was initially turned using coated carbide and CBN tools and subsequently burnished to produce surfaces with Ra roughness parameter of about 0.15 μm. The modifications of the initial surface profiles, microstructure and microhardness of the sublayer were determined and relevant technological limits are selected. 相似文献
66.
67.
Joanna Dawczyk Ecaterina Ware Mahmoud Ardakani Joe Russo Hugh Spikes 《Tribology Letters》2018,66(4):155
Focussed ion beam milling (FIB) followed by TEM has been used to study ZDDP tribofilms on rubbed steel surfaces. It has been found that the impact of high energy platinum and gallium ions during FIB causes significant morphological and structural changes to the uppermost 30–50 nm of a ZDDP tribofilm. This can be prevented by the low energy deposition of a quite thick gold layer prior to installation of the sample in the FIB facility. This problem, and its solution, have been quite widely reported in the non-tribology literature but have not previously been highlighted in the application of FIB to study tribological surfaces. It has also been found, using this gold pre-deposition method, that the bulk of the ZDDP tribofilm studied has a polycrystalline structure. 相似文献
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69.
Celina Kruszniewska-Rajs Barbara Strzaka-Mrozik Magdalena Kimsa-Dudek Agnieszka Synowiec-Wojtarowicz Elwira Chrobak Ewa Bbenek Stanisaw Boryczka Stanisaw Guszek Joanna Magdalena Gola 《International journal of molecular sciences》2022,23(5)
Betulin and its derivatives, 28-propyne derivative EB5 and 29-diethyl phosphonate analog ECH147, are promising compounds in anti-tumor activity studies. However, their effect on kidney cells has not yet been studied. The study aimed to determine whether betulin and its derivatives—EB5 and ECH147—influence the viability and oxidative status of human renal proximal tubule epithelial cells (RPTECs). The total antioxidant capacity of cells (TEAC), lipid peroxidation product malondialdehyde (MDA) level, and activity of antioxidant enzymes (SOD, CAT, and GPX) were evaluated. Additionally, the mRNA level of genes encoding antioxidant enzymes was assessed. Cisplatin and 5-fluorouracil were used as reference substances. Betulin and its derivatives affected the viability and antioxidant systems of RPTECs. Betulin strongly reduced TEAC in a concentration-dependent manner. All tested compounds caused an increase in MDA levels. The activity of SOD, CAT, and GPX, and the mRNA profiles of genes encoding antioxidant enzymes depended on the tested compound and its concentration. Betulin showed an cisplatin-like effect, indicating its nephrotoxic potential. Betulin derivatives EB5 and ECH147 showed different impacts on the antioxidant system, which gives hope that these compounds will not cause severe consequences for the kidneys in vivo. 相似文献
70.
One of the strategies in the search for safe and effective analgesic drugs is the design of multitarget analgesics. Such compounds are intended to have high affinity and activity at more than one molecular target involved in pain modulation. In the present contribution we summarize the attempts in which fentanyl or its substructures were used as a μ-opioid receptor pharmacophoric fragment and a scaffold to which fragments related to non-opioid receptors were attached. The non-opioid ‘second’ targets included proteins as diverse as imidazoline I2 binding sites, CB1 cannabinoid receptor, NK1 tachykinin receptor, D2 dopamine receptor, cyclooxygenases, fatty acid amide hydrolase and monoacylglycerol lipase and σ1 receptor. Reviewing the individual attempts, we outline the chemistry, the obtained pharmacological properties and structure-activity relationships. Finally, we discuss the possible directions for future work. 相似文献