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61.
J. B. Sousa M. R. Chaves M. F. Pinheiro R. S. Pinto 《Journal of Low Temperature Physics》1975,18(1-2):125-137
Direct measurements of the temperature derivative of the electrical resistivity d/dT have been made on several ferromagnetic NiCu alloys with high Cu content (20, 30, 40, 50.4 at %). For Ni80Cu20 and Ni70Cu30 the results closely resemble the general pattern found in pure ferromagnets: d/dT - b – a ln ¦¦, for 10–3 ¦¦ 10–1, with a and b constants and = (T/T
c
)– 1. In Ni60Cu40 the rounding off of the magnetic transition is already so pronounced that a similar analysis is hardly significant. In the Ni49.6Cu50.4 sample negative values of d/dT were confirmed above ~165 K. The possible theoretical implications of the results are briefly discussed.Work supported by Instituto de Alta Cultura, Portugal (Project PF1). 相似文献
62.
The problem of base station antenna assignment (BSAA) with minimum mobile transmit power (MTP) is studied for CDMA networks with fixed overlapping sector antenna architecture (FOSAA) where more than one co-located antenna is used to cover any space in the network. It is first noted that the non-FOSAA has limitations in switching users between in-cell sectors and also out-of-cell sectors in moderately-loaded networks. It is then shown that by employing overlapping sectors in FOSAA, we can exploit the flexibility of assigning a user to one of possibly many potential antenna to effectively support the nonuniform azimuthal traffic. It is also shown that the BSAA problem with minimum MTP is a special case of a general problem that was solved by Hanly and Yates. The process of dynamic cell sectoring is differentiated twofold as cell-breathing (CB) and cell-slicing (CS) and the latter can be viewed as being azimuthal discrete counterpart of the former radial scheme. The hybrid scheme, CB+CS, offers better performance in terms of minimum total MTP in a FOSAA system. Simulation results demonstrate the flexibility and effectiveness of the FOSAA system in nonuniform angular traffic. 相似文献
63.
A reconfigurable high-frequency phase-locked loop 总被引:4,自引:0,他引:4
Reconfigurable phase-locked loops (PLLs) present the advantage of fast-frequency acquisition combined with narrow-noise bandwidth, since their parameters can be dynamically adjusted. High-frequency PLLs are generally implemented by means of analog circuits which are not easily reconfigured during operation. However, the five-port technique allows the discrimination of the phase difference between two microwave signals using a mixed circuit. In this paper the design of a PLL comprising a five-port based phase detector is presented. This system benefits from the phase-detector digital circuit to carry out the loop filtering. Simulation results for different conditions of noise and frequency acquisition are shown. We also present measurement results to confirm the simulations. 相似文献
64.
Gilles Celeux Author Vitae Author Vitae Jorge Marques Author Vitae 《Pattern recognition》2004,37(9):1841-1853
Many recent tracking algorithms rely on model learning methods. A promising approach consists of modeling the object motion with switching autoregressive models. This article is involved with parametric switching dynamical models governed by an hidden Markov Chain. The maximum likelihood estimation of the parameters of those models is described. The formulas of the EM algorithm are detailed. Moreover, the problem of choosing a good and parsimonious model with BIC criterion is considered. Emphasis is put on choosing a reasonable number of hidden states. Numerical experiments on both simulated and real data sets highlight the ability of this approach to describe properly object motions with sudden changes. The two applications on real data concern object and heart tracking. 相似文献
65.
Preparation of polypropylene‐based nanocomposites using nanosized MCM‐41 as support and in situ polymerization
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Darío M González Raúl Quijada Mehrdad Yazdani‐Pedram Joao Paulo Lourenço M Rosario Ribeiro 《Polymer International》2016,65(3):320-326
MCM‐41 nanoparticles were used for preparing nanocomposites through the in situ polymerization of propylene. The performance of the catalytic system and the final properties of the materials obtained are highly dependent on the methodology used for impregnation of the catalyst onto the support particles, and therefore an optimization study for the impregnation methodology of the catalyst (Me2Si(Ind)2ZrCl2) was carried out. Two different methodologies were used; the results in terms of catalytic activity and polymer molecular masses indicated that the most promising one involved the pre‐activation of the catalyst with the cocatalyst, methylaluminoxane, followed by impregnation onto the MCM‐41 nanoparticles. Thus, an optimized route for the preparation of polypropylene nanocomposites achieving significant improvements in catalyst activity was developed. The nanocomposite materials were characterized by GPC, TGA and DSC. The dispersion state and the size of the nanoparticles incorporated in the polypropylene matrix were investigated by transmission electron microcopy. Additionally, this methodology allows simultaneous control of the desired amount of support and the concentration of catalyst to be used in the in situ polymerization. © 2015 Society of Chemical Industry 相似文献
66.
Marcia C. Delpech Ivana L. Mello Fernanda C. S. Delgado Jurandir M. Sousa 《应用聚合物科学杂志》2012,125(5):4074-4081
The extender oil usually employed in compositions of rubbers based on styrene and butadiene (SBR) 1712 is the distilled aromatic extract (DAE). In this work, this oil was substituted by oils with low levels of polycyclic aromatic hydrocarbons (PAHs): treated residual aromatic extract (TRAE) and two naphthenic oils from different suppliers (HN1 and HN2). This substitution was performed in response to REACH Regulation (EC No. 1907/2006 European Parliament and the Council of December 18, 2006, Annex XVII), which state that the sum of individual PAHs should be below 10 mg/kg and the levels of benzo (a) pyrene (BaP) should not exceed 1 mg/kg. Infrared spectroscopy was employed to characterize the structure of crude oils and respective SBR compositions. Thermal properties of the materials were evaluated by thermogravimetry and differential scanning calorimetry. Mechanical properties as tension tests, hardness, abrasion resistance, and resilience were also determined. The final results showed that it is possible to replace the extender oil DAE for any of the oils tested, specially the naphthenic HN1, without any loss of the properties evaluated in this study for the SBR compositions. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
67.
Liliana Martelo Alfonso Jiménez Artur JM Valente Hugh D Burrows Ana T Marques Michael Forster Ullrich Scherf Mercedes Peltzer Sofia M Fonseca 《Polymer International》2012,61(6):1023-1030
Films of neat and plasticized biodegradable poly(lactic acid) (PLA) matrices containing anionic conjugated polyelectrolytes, poly[9,9‐bis(4‐phenoxybutylsulfonate)]fluorene‐2,7‐diyl‐alt‐arylenes, with 1,4‐phenylene and 4,4″‐p‐terphenylene, respectively, as arylene groups or a neutral poly(9,9‐dialkylfluorene) for comparison were prepared by solution casting. These films were characterized using differential scanning calorimetry, thermogravimetry, scanning electron microscopy and fluorescence spectroscopy. In addition, the effects of plasticizer on the thermal properties and the oxygen permeability of the PLA films were measured through the oxygen transmission rate. Results show that it is possible to obtain thin, optically transparent and luminescent films with potential in oxygen sensing, exhibiting good thermal and photochemical stability. At high polyelectrolyte content, evidence is found for phase separation and aggregate formation and it is no longer possible to obtain completely homogeneous films. The possibility of incorporating the cationic metal complex tris(2,2′‐bipyridyl)ruthenium(II) into plasticized PLA films containing conjugated polyelectrolytes for dual‐wavelength ratiometric luminescence sensing is also discussed. Copyright © 2012 Society of Chemical Industry 相似文献
68.
69.
Nair do Amaral Sampaio Neta José Cleiton Sousa dos Santos Soraya de Oliveira Sancho Sueli Rodrigues Luciana Rocha Barros Gonçalves Ligia R. Rodrigues José A. Teixeira 《Food Hydrocolloids》2012
Sugar esters are compounds with surfactant properties (biosurfactants), i.e., capable of reducing the surface tension and promote the emulsification of immiscible liquids. On the other hand, as with all emulsions, coconut milk is not physically stable and is prone to phase separation. Therefore, the aim of this work was to evaluate the synthesis of fructose, sucrose and lactose esters from the corresponding sugars using Candida antarctica type B lipase immobilized in two different supports, namely acrylic resin and chitosan, and evaluate its application in the stabilization of coconut milk emulsions. The enzyme immobilized on chitosan showed the highest yield of lactose ester production (84.1%). Additionally, the production of fructose ester was found to be higher for the enzyme immobilized on the acrylic resin support (74.3%) as compared with the one immobilized on chitosan (70.1%). The same trend was observed for the sucrose ester, although with lower percentage yields. Sugar esters were then added to samples of fresh coconut milk and characterized according to their surface tension, emulsification index and particle size distribution. Although the microscopic analysis showed similar results for all sugar esters, results indicated lactose ester as the best biosurfactant, with a surface tension of 38.0 N/m and an emulsification index of 54.1%, when used in a ratio of 1:10 (biosurfactant:coconut milk, v/v) for 48 h experiments. 相似文献
70.
Using the flexibility of Wireless Mesh Networks (WMNs) and network virtualization, we define a novel architecture that provides personalized access for users by splitting a WMN into several adaptable Virtual Networks (VNs). Each VN is configured to meet specific levels of user context demands (context can span from security, mobility or service requirements). Users are grouped according to similarity of their context, and associated to VNs matching their context. To break the traditional centralized solutions for WMN and virtualization control, this paper defines an overall framework to distribute the control responsibilities along the architectural entities, which can then cooperate to autonomously discover, select, create, extend or remove VNs on-demand according to user and WMN dynamics. We also propose an analytical model to evaluate several performance aspects of the distributed VN control when compared to centralized or decentralized solutions, validating the model against a simulation study. 相似文献