Characterization of substituted phenol–formaldehyde resins using solid-state carbon-13 NMR

Crosslinked substituted phenol–formaldehyde resins were synthesized from cashew nut shell liquid, 3-n-pentadecylphenol and phenol with formaldehyde. The resulting resins were crosslinked and investigated using carbon-13 NMR in the solid state using cross-polarization, magic angle spinning, and dipolar decoupling. Comparisons were made between the spectra of pure phenol–formaldehyde resins and it was shown possible to distinguish between the resins. It was also shown that the proton-dephased spectrum gave better spectral resolution for the substituted compounds. In addition, the solids carbon-13 technique verified that the degradation of the substituted phenolic resins occurs first with the degradation of the side chain in agreement with suggestions from earlier work.     

Estimation of energy balance at the individual and herd level using blood and milk traits in high-yielding dairy cows

This study aimed to estimate individual and herd-level energy balance (EB) using blood and milk traits in 90 multiparous high-yielding Holstein cows, held on a research farm, from wk 1 to 10 postpartum (p.p.) and to investigate the precision of prediction with successively decreased data sets simulating smaller herd sizes and with pooled samples. Dry matter intake, milk yield, and BW were measured daily from parturition through wk 10 p.p. Milk composition was determined 4 times per week, and milk acetone was measured weekly. Blood samples for the determination of metabolites, hormones, electrolytes, and enzyme activities were taken weekly from wk 1 to 10 p.p. between 0730 and 0900. Body condition scores and ultrasonic measurements of backfat thickness and fat depth in the pelvic area were evaluated in wk 1, 4, and 8 p.p. Concentrations of glucose, cholesterol, urea, insulin, insulin-like growth factor-1, triiodothyronine, and thyroxine (T4) in blood plasma and of lactose and urea in milk were positively correlated with EB, whereas concentrations of nonesterified fatty acids (NEFA), creatinine, albumin, beta-hydroxybutyrate, and growth hormone and enzyme activities in blood, and concentrations of fat, protein, fat:lactose ratio, and acetone in milk were negatively correlated with EB. Leptin concentration was not correlated to EB over the first 10 wk p.p. To estimate EB linear mixed-effects, models were developed by backward selection procedures. The most informative traits for estimation of EB were the fat:lactose ratio in milk and NEFA and T4 concentrations in blood. The precision of estimation of EB in individual cows was low. Using blood in addition to milk traits did not result in higher precision of estimation of herd-level EB, and decreasing sample sizes considerably lowered the precision of EB prediction. Estimation of overall mean herd-level EB over the first 10 wk p.p. using pooled samples was precise even with small sample sizes, but does not consider the level of EB in particular weeks. In conclusion, estimation of herd-level EB at individual weeks using milk traits only has practical implication with herd sizes of > or = 100 cows if calving is highly seasonal and of or = 400 cows if calving is uniformly distributed. Using blood in addition to milk traits does not improve precision of estimation of herd-level EB, regardless of sample size.     

A focused two-dimensional air-coupled ultrasonic array for non-contact generation

Air-coupled ultrasonic sources are relatively inefficient because the high impedance mismatch at the air/solid boundary means that most of the input energy (in air) is reflected at this boundary. The objective of this research is to increase efficiency—specifically an increase in ultrasonic signal amplitude—by designing and building a focused, 2D-array of electrostatic transducers (individual diameters of 38 mm). The operating frequency of this array is in the range of 50–100 kHz; this range is selected for civil infrastructure applications. Numerical simulations are used to design an array by modeling the pressure field in air, and then optimizing an array consisting of 20 transducers to create a line-source. An array is then built (following this design) and the emitted pressure field (in air) of the as built array is measured with a microphone and compared to the pressure field predicted by the numerical model. Finally, the as built focused array is used as an ultrasonic source, and its robustness is verified by comparing the numerical simulation of a transient line-load on an elastic half-space with (completely non-contact) experimentally measured values. There is excellent agreement between these two representations, which confirms the possibility of developing a completely non-contact, scanning ultrasonic system in the 50–100 kHz range.     

Sustainable Syngas Production by High-Temperature Co-electrolysis

High-temperature co-electrolysis shows comparable performance to steam electrolysis. Current densities above 1 A cm⁻² can be reached between 700 °C and 800 °C. Tailor-made syngas is produced, mainly determined by the reactant ratio. The experimental results are supported by modeling. Durability tests with cathode-supported cells show increased voltage degradation rates during electrolysis compared to fuel cell operation. Nickel depletion is found to be the main cause.     

Rate dependent constitutive relations based on Anand model for92.5Pb5Sn2.5Ag solder

A rate dependent constitutive model, the Anand model, was applied to represent the inelastic deformation behavior for a Pb-rich solder 92.5Pb5Sn2.5Ag used in electronic packaging and surface mount technology. This rate dependent model is a unified viscoplastic constitutive model using an internal state variable, the deformation resistance, to describe the averaged isotropic resistance to macroscopic plastic flow. In order to obtain the acquired data for the fitting of the material parameters of this unified model for 92.5Pb5Sn2.5Ag solder, a series of experiments of constant strain rate test and constant load creep test were conducted under isothermal conditions at different temperatures ranged from -65°C to 250°C. A procedure for the determination of material parameters was proposed in this paper. Model simulations and verifications revealed that there are good agreements between model predictions and experimental data. Moreover, some discussions on using this rate dependent model in the finite element simulation of stress/strain responses of solder joints under thermal fatigue loading were presented     

Grain subdivision and recrystallization in oligocrystalline tantalum during cold swaging and subsequent annealing

A coarse-grained ingot of high-purity tantalum was deformed by swaging at room temperature to a strain of 1.28. During annealing at 900°C for 30 min two neighboring grains were observed to behave quite differently. Electron backscattering diffraction (EBSD) results show noticeable differences in terms of the misorientations developed in both grains. The grain developing larger misorientations recrystallized much more readily than the other. The result is interpreted in terms of the differences in grain subdivision into strongly misoriented regions.     

B-mode ultrasonography of mammary glands of cows, goats and sheep during alpha- and beta-adrenergic agonist and oxytocin administration.

Teat and gland cistern of the mammary glands of five dairy cows, five goats and five sheep were scanned in a water bath during alpha- and beta-adrenergic agonist and oxytocin administration. A 5 MHz linear array scanner was used to create vertical cut pictures with the scan plane longitudinally through the teat channel. The i.v. injection of the alpha-adrenergic agonist phenylephrine (30 micrograms/kg) induced diminution of the section area through teat and gland cistern by 38 +/- 17% on average within 1 min in all three species. In contrast, the i.v. injection of the beta-adrenergic agonist isoproterenol (1 microgram/kg) did not change the cisternal areas. The i.v. injection of oxytocin (2.0 x 10(-3) i.u./kg) elicited an enlargement of teat and gland cistern area by 48 +/- 12% on average. Ultrasonography proved to be a valuable system for visualizing changes of the cisternal volume. Smooth muscle contractions in response to phenylephrine administration are thought to cause area reduction, whereas an expected smooth muscle relaxation after injection of isoproterenol could not be observed by ultrasonography. Milk ejection as induced by oxytocin administration caused dramatic enlargement of the cistern area in all three species.