Is time really important for research into contracting out public services in cities? Evidence for urban water management in Southern Spain

Local governments are responsible for the supply of important public services in cities. On many occasions the management of those services is externalized. There is extensive literature analyzing the explanations for the governance option taken by local governments, aiming to ascertain the reasons why the management of certain services is externalized. Recent research has highlighted the fact that time has not been contemplated by research dealing with explanatory factors in the decision to contract out municipal services. This is a key issue in order to identify the real reason behind policymakers’ decisions about the management of the services in cities. This paper tests the importance of taking into account time in the research into contracting out. This is undertaken by means of two methodological tests in the design of variables from a dataset containing 744 municipalities in Southern Spain. Using this empirical analysis as a basis, it is concluded that considering time contributes towards enhancing the specification of the model and that omitting this aspect could lead to misunderstanding the motivation behind such decisions.     

Efficiency convergence processes and effects of regulation in the nonspecialized retail sector in Spain

This work analyzes the effects of the regulation/deregulation processes carried out on the evolution of efficiency in Spanish retail-sector firms in the period 1996–2004. The results suggest that the regulation in this sector has had a considerable influence on firms’ efficiency, in particular, the legislation on the expansion of commercial opening hours after 2000. The results provide clear evidence of a convergence in firms’ efficiency from the initial year considered to superior levels. Moreover, the pattern of convergence differs in function of the region in which the firm operates. The evolution of efficiency given by the means of different groups of regulation intensity levels through the time seems to show clearly in the groups of high and low regulation. It is observed that the group of high regulation is the most efficient. The analysis of the firms as a whole confirms the convergence process. Considering the analysis for subperiods an improvement is observed for all regions in the period 2000 at 2004.     

The importance of access to information and knowledge coordination on quality and economic benefits obtained from Six Sigma

Wireless Networks - This paper presents a structural equation model that relates knowledge coordination with access to information in the process of implementing Six Sigma and their impact on the...     

Network‐layer security for the Internet of Things using TinyOS and BLIP

The design of standard communications and security mechanisms for resource‐constrained sensing applications and devices may provide an important contribution for its integration with the Internet and consequently towards the realization of what we nowadays identify as the Internet of Things. This vision will only be realizable if appropriate security mechanisms are available, and in this context we target the design and experimental evaluation of security mechanisms for communications at the network‐layer with sensing devices (smart objects) using the standard IPv6 protocol. Our work proposes and evaluates the usage of new compressed security headers for the network layer with smart objects. We implement and evaluate what is, as far as we know, the first proposal of security at the network layer experimentally evaluated using the TinyOS operating system and its networking stack. As we verify in the course of our evaluation study, various scenarios employing network‐layer secure communications involving smart objects are feasible, particularly when security mechanisms are designed to benefit from cross‐layer interactions that allow the optimization of expensive cryptographic operations. Copyright © 2012 John Wiley & Sons, Ltd.     

Vitamins as Active Agents for Highly Emissive and Stable Nanostructured Halide Perovskite Inks and 3D Composites Fabricated by Additive Manufacturing

The use of non-toxic and low-cost vitamins like α-tocopherol (α-TCP, vitamin E) to improve the photophysical properties and stability of perovskite nanocrystals (PNCs), through post-synthetic ligand surface passivation, is demonstrated for the first time. Especially interesting is its effect on CsPbI₃ the most unstable inorganic PNC. Adding α-TCP produces that the photoluminescence quantum yield (PLQY) of freshly prepared and aged PNCs achieves values of ≈98% and 100%, respectively. After storing 2 months under ambient air and 60% relative humidity, PLQY is maintained at 85% and 67%, respectively. α-TCP restores the PL features of aged CsPbI₃ PNCs, and mediates the radiative recombination channels by reducing surface defects. In addition, the combination of α-TCP and PNCs facilitates the chemical formulation to prepare PNCs-acrylic polymer composites processable by additive manufacturing. This enables the development of complex shaped parts with improved luminescent features and long-term stability for 4 months, which is not possible for non-modified PNCs. A PLQY ≈92% is reached in the 3D printed polymer/PNC composite, the highest value obtained for a red-emitting composite solid until now as far as it is known. The passivation shell provided by α-TCP makes that PNCs inks do not suffer any degradation process avoiding the contact with the environment and preserve their properties after reacting with polar monomers during composite polymerization.     

48 Gbit/s InP DHBT MS-DFF with very low time jitter

A master-slave D-type flip-flop (MS DFF) fabricated in a self-aligned InP DHBT technology is presented. The packaged circuit shows full-rate clock operation at 48 Gbit/s. Very low time jitter and good retiming capabilities are observed. Layout aspects, packaging and measurement issues are discussed in particular     

An efficiently implementable maximum likelihood decoding algorithm for tailbiting codes

Convolutional tailbiting codes are widely used in mobile systems to perform error-correcting strategies of data and control information. Unlike zero tail codes, tailbiting codes do not reset the encoder memory at the end of each data block, improving the code efficiency for short block lengths. The objective of this work is to propose a low-complexity maximum likelihood decoding algorithm for convolutional tailbiting codes based on the Viterbi algorithm. The performance of the proposed solution is compared to that of another maximum likelihood decoding strategy which is based on the A* algorithm. The computational load and the memory requirements of both algorithms are also analysed in order to perform a fair comparison between them. Numerical results considering realistic transmission conditions show the lower memory requirements of the proposed solution, which makes its implementation more suitable for devices with limited resources.     

The Priming Effects of Virtual Environments on Interpersonal Perceptions and Behaviors

This study investigated how virtual environments prime subsequent interpersonal relations among unacquainted individuals. Participants met in a virtual library or a café. Individuals in the virtual library perceived greater self and partner formality compared to those in the café. In addition, more self‐disclosure correlated with less formality only in the library, showing how revealing more about oneself goes against library norms. In contrast, perceived warmth and word counts were at the center of the effects found in the virtual café. Partner warmth and word counts also mediated the effect of the environments on formality. Overall, this article advances priming research in stimuli‐rich virtual settings by showing how environmental salience and activation of contextual norms affected interpersonal perceptions among unacquainted partners.     

Water activity,water glass dynamics,and the control of microbiological growth in foods

Water is probably the single most important factor governing microbial spoilage in foods, and the concept of water activity (a_w) has been very valuable because measured values generally correlate well with the potential for growth and metabolic activity. Despite some drawbacks (e.g., solute effect), the concept of a_w has assisted food scientists in their effort to predict the onset of food spoilage as well as to control food‐borne disease hazards in food products. In the last decade the concept of a_w has been challenged. It has been suggested that reduced‐moisture food products (e.g., low and intermediate) may be nonequilibrium systems and that most of them are in the amorphous metastable state, which is very sensitive to changes in moisture content and temperature. It has been proposed that the glass transition temperature T_g (temperature at which the glass‐rubber transition occurs), is a parameter that can determine many product properties, the safety of foods among them. The concept of water dynamics, originating in a food polymer science approach, has been suggested instead of a_w to better predict the microbial stability of intermediate‐moisture foods. The usage of a_w to predict microbial safety of foods has been discouraged on the basis that (1) in intermediate‐moisture foods the measured water vapor pressure is not an equilibrium one, and because a_w is a thermodynamic concept, it refers only to equilibrium; and (2) the microbial response may differ at a particular a_w when the latter is obtained with different solutes.

This review analyzes these suggestions on the basis of abundant experimental evidence found in the literature. It is concluded that nonequilibrium effects (e.g., inability of water to diffuse in a semimoist food) appear to be in many cases slow within the time frame (food's shelf life) of the experiments and/or so small that they do not affect seriously the application of the a_w concept as a predictor of microbial stability in foods.

The claims that a food science polymer approach to understanding the behavior of aqueous sugar glasses and concentrated solutions may be used to predict the microbial stability of food systems is not substantiated by experimental evidence. This approach does not offer, at the present time, a better alternative to the concept of a_w as a predictor of microbial growth in foods.

It is also recognized that a_w has several limitations and should be always used carefully, and this must include precautions regarding the possible influences of nonequilibrium situations. This aspect may be summarized by simply saying that anyone who is going to employ the term water activity must be aware of the implications of its definition.     

Hybrid Organic/Inorganic Nanostructures for Highly Sensitive Photoelectrochemical Detection of Dissolved Oxygen in Aqueous Media

Precise, reliable, and remote measurement of dissolved oxygen in aqueous media is of great importance for many industrial, environmental, and biological applications. In particular, photoelectrochemical sensors working in differential mode have recently demonstrated promising properties, in terms of stability, sensitivity, and application potential. Here, a new approach is presented, combining visible light sensitivity, efficient photocurrent generation, and solution‐processed fabrication methods of conjugated polymers, with charge carriers selectivity, energetic alignment favorable to efficient interfacial charge transfer and high surface area achievable by using metal oxide nanostructures. Extensive characterization and optimization of the hybrid organic/inorganic system are carried out, leading to the realization of an oxygen sensor device, based on nanostructured palladium oxide/poly[(9,9‐dioctylfluorenyl‐2,7‐diyl)‐alt‐5,5‐(4′,7′‐di‐2‐thienyl‐2′,1′,3′‐benzothiadiazole]/[6,6]phenyl‐C61‐butyric acid methyl ester (PdO/APFO‐3:PCBM) as materials of choice. State‐of‐the‐art sensitivity, amounting at ?5.87 μA cm^?2 ppm^?1, low background signal, in the order of ?4.85 μA cm^?2, good electrochemical stability for more than 2 h of continuous functioning and high reproducibility of the signal over the pH 1 to 10 range, are reported, making the hybrid device suitable for several practical uses. The results fully validate the mixed organic/inorganic approach for photoelectrochemical applications, and pave the way for its further exploitation in fields like waste water treatment, environmental monitoring, and water splitting.