全文获取类型
收费全文 | 4648篇 |
免费 | 332篇 |
国内免费 | 9篇 |
专业分类
电工技术 | 49篇 |
综合类 | 6篇 |
化学工业 | 1255篇 |
金属工艺 | 92篇 |
机械仪表 | 159篇 |
建筑科学 | 210篇 |
矿业工程 | 19篇 |
能源动力 | 157篇 |
轻工业 | 889篇 |
水利工程 | 42篇 |
石油天然气 | 23篇 |
无线电 | 250篇 |
一般工业技术 | 765篇 |
冶金工业 | 245篇 |
原子能技术 | 34篇 |
自动化技术 | 794篇 |
出版年
2024年 | 11篇 |
2023年 | 57篇 |
2022年 | 148篇 |
2021年 | 204篇 |
2020年 | 143篇 |
2019年 | 166篇 |
2018年 | 200篇 |
2017年 | 192篇 |
2016年 | 221篇 |
2015年 | 155篇 |
2014年 | 213篇 |
2013年 | 369篇 |
2012年 | 310篇 |
2011年 | 341篇 |
2010年 | 257篇 |
2009年 | 266篇 |
2008年 | 221篇 |
2007年 | 197篇 |
2006年 | 172篇 |
2005年 | 144篇 |
2004年 | 127篇 |
2003年 | 102篇 |
2002年 | 110篇 |
2001年 | 67篇 |
2000年 | 52篇 |
1999年 | 52篇 |
1998年 | 90篇 |
1997年 | 57篇 |
1996年 | 55篇 |
1995年 | 51篇 |
1994年 | 31篇 |
1993年 | 29篇 |
1992年 | 20篇 |
1991年 | 17篇 |
1990年 | 12篇 |
1989年 | 19篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1986年 | 13篇 |
1985年 | 13篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 8篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 9篇 |
1976年 | 7篇 |
1975年 | 5篇 |
排序方式: 共有4989条查询结果,搜索用时 15 毫秒
51.
Reactor blends of polyethylene/poly(ethylene-co-1-octene) resins with bimodal molecular weight and bimodal short chain branching distributions were synthesized in a two-step polymerization process. The compositions of these blends range from low molecular weight (LMW) homopolymer to high molecular weight (HMW) copolymer and vice versa HMW homopolymer to LMW copolymer. The shear flow characteristics of these polymers in the typical processing range mostly depend on the molecular weight and MWD of the polymer and are independent of the short chain branch content. From oscillatory shear measurements, it was observed that the viscosity of HMW polymers was reduced with the addition of LMW material. For the polymers produced with this two-step polymerization process, the LMW homopolymer and HMW copolymer blends and HMW homopolymer and LMW copolymer blends were melt miscible, despite the large viscosity differences of the pure components. 相似文献
52.
53.
Abdullahi Nuhu Jorge Soares Monica Gonzalez-Herrera Andrew Watts Ghulam Hussein Michael Bowker 《Topics in Catalysis》2007,44(1-2):293-297
We have investigated the adsorption and reaction of methanol with Au/TiO2 catalysts using a pulsed flow reactor, DRIFTS and TPD. The TiO2 (P25) surface adsorbed a full monolayer of methanol, much of it in a dissociative manner, forming methoxy groups associated
with the cationic sites, and hydroxyl groups at the anions. The methoxy is relatively stable until 250 °C, at which point
decomposition occurs, producing mainly dimethyl ether by a bimolecular surface reaction. As the concentration of methoxy on
the surface diminishes, so the mechanism reverts to a de-oxygenation pathway, producing mainly methane and water (at ~330 °C
in TPD), but also with some coincident CO and hydrogen. Au catalysts were prepared by the deposition-precipitation method
to give Au loadings between 0.5–3 wt %. The effect of low levels of Au on the reactivity is marked. The pathway which gives
methane, which is characteristic of titania, remains, but a new feature of the reaction is the evolution of CO2 and H2 at lower temperature (a peak is seen in TPD at 220 °C), and the elimination of the DME-producing state. Clearly this is associated
with the presence of Au and appears to be due to the production of a formate species on the surface of the Au component. This
formate species is mainly involved in the reaction of methanol with the Au/TiO2 catalysts which results in a combustion pathway being followed, with complete conversion occurring by ~130 °C. 相似文献
54.
Filiberto González Garcia Bluma G. Soares Victor J. R. R. Pita Rubén Sánchez Jacques Rieumont 《应用聚合物科学杂志》2007,106(3):2047-2055
The mechanical properties of epoxy networks based on diglycidyl ether of bisphenol A epoxy resin cured with various linear aliphatic amines, such as ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, and cyclic amines such as 1‐(2‐aminoethyl)piperazine and isophorone diamine, were studied. General characteristics such as Tg, density, and packing density, were determined and related to the structure and funcionality of the curing agent. Dynamic mechanical spectra were used to study both the α and β relaxations. Tensile and the flexural tests were used to determine the Young's and flexural modulus, and fracture strength all in the glassy state. Furthermore, linear elastic fracture mechanics was used to determine KIC. As a rule, isophorone diamine network presented the higher tensile and flexure modulus while 1‐(2‐aminoethyl)piperazine gave the highest toughness properties. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
55.
Eric Jorge Thierry Chartier Phillippe Boch 《Journal of the American Ceramic Society》1990,73(8):2552-2554
Ultrasonication is very effective in dispersing alumina and barium titanate slurries. When optimum conditions are used, very short durations (2 to 3 min) are enough to achieve well-dispersed, stable suspensions. 相似文献
56.
Jorge Garcia-Cañadas Jon Kapla Germà Garcia-Belmonte Marten O.M. Edwards 《Electrochimica acta》2004,49(5):745-752
The dynamic response of viologen-activated nanostructured titanium dioxide has been studied by means of electrical and electro-optical measurements. We show that the state of charge of the semiconductor network is the key factor mediating between the electrode potential and colouration of viologen. Theoretically, we relate the electrode potential to the statistics of occupancy of both TiO2 nanoparticles and oxidized viologen molecules attached to the surface, on the assumption of quasi-equilibrium of Fermi levels in these contacting phases. Experimentally, we determine the statistical function from steady-state measurements (electrochemical impedance spectroscopy) of the capacitance of the semiconductor film. From this understanding we explain the main features that correlate the simultaneous voltammetry and transmittance responses. Finally, the redox process of viologen is resolved separately from the TiO2 response by means of transmittance data. 相似文献
57.
Reactor blends of polyethylene/poly(ethylene-co-1-octene) resins with bimodal molecular weight and bimodal short chain branching distributions were synthesized in a two-step polymerization process. The compositions of these blends range from low molecular weight (LMW) homopolymer to high molecular weight (HMW) copolymer and, vice versa, HMW homopolymer to LMW copolymer. The physical properties of the blends were found to be consistent with the nature of the individual components. For the tensile properties, the stiffness decreases with increasing the fraction of the copolymer, regardless of the molecular weight of the homopolymer fraction. For these blends with bimodal microstructures, it was confirmed that the degree of crystallinity governs the stiffness of the polymer. However, the energy dampening properties of the polymers benefit from the presence of the copolymer. A balance of stiffness and toughness can be obtained by altering the composition of the blends. For some blends, the presence of HMW homopolymer can dominate the tensile properties, showing little variation in the stiffness with increased addition of copolymer. It was also demonstrated that the testing conditions and thermal treatment of the polymer greatly influence the resulting elastic and energy dampening properties. Depending on the desired application, annealing these polymers (especially very low density copolymers) not only increases the crystallinity and stiffness, but also changes the frequency response of the dynamic mechanical properties. 相似文献
58.
Rama Subba Reddy Gorla Jorge E. Gatica Bahman Ghorashi Pijarn Ineure Larry W. Byrd 《Chemical Engineering Communications》2004,191(5):718-731
Heat transfer enhancement in an evaporating thin liquid film utilizing a electric field under isothermal interfacial condition is presented. A new mathematical model subjected to van der Waals attractive forces, capillary pressure, and an electric field is developed to describe the heat transfer enhancement in the evaporating thin liquid film. The effect of the electrostatic field on the curvature of the thin film, evaporative flux, pressure gradient distribution, heat flux, and heat transfer coefficient in the thin film is presented. The results show that applying an electric field can enhance heat transfer in a thin liquid film significantly. In addition, utilizing electric fields on the evaporating film will be a way to expand the extended meniscus region to attain high heat transfer coefficients and high rates of heat flux. 相似文献
59.
The alignment of information systems with the business goals of an organisation, although a topic of great importance, is not always properly valued or taken into consideration. In general, managers have different opinions to chief information officers (CIOs) in relation to IS, especially with regard to their importance and value to the business and also in terms of investment needs. Here, we discuss and study new approaches to methods and tools for assessing the relative importance of each information system to business, focusing on the financial sector including banks and insurance companies. We suggest the introduction of new key indicators for better decision support and to identify investment priorities, and present results regarding the relative importance of each process to support the business strategy. The primary goal for the inherent research project is to analyse the main problems and difficulties encountered by IS and IT managers, featuring different players and how they relate. The main contributions of this work are the CRUDi framework as a tool to improve alignment between business and IS strategies and the CRUDi survey and its results qualifying the financial sector's opinion regarding the relative importance of processes and investments. 相似文献
60.
Vanesa Losada Jorge Barros‐Velzquez Jos M. Gallardo Santiago P. Aubourg 《European Journal of Lipid Science and Technology》2004,106(12):844-850
Slurry ice is a biphasic system consisting of small spherical ice crystals surrounded by seawater at subzero temperature. Its effect on lipid damage (hydrolysis and oxidation) was evaluated during the chilled storage of a fatty fish species, sardine (Sardina pilchardus). Slurry ice treatment was checked alone and in combination with ozone and compared to traditional flake icing during a 22‐day storage. Different lipid damage indices (free fatty acids, FFA; peroxide value, PV; thiobarbituric acid index, TBA‐i; fluorescent compounds, FR) were checked and compared to sensory assessment and nucleotide degradation (K value). According to lipid hydrolysis (FFA) and oxidation (PV and FR) developments, slurry ice showed an inhibitory effect (p <0.05) on lipid damage during storage, as well as an inhibition of nucleotide autolytic degradation. Ozonised slurry ice did not provide differences (p >0.05) from slurry ice alone when considering lipid hydrolysis, nucleotide degradation and some lipid oxidation indices (PV and FR), although a higher (p <0.05) TBA‐i was observed at day 22 of storage when compared to flake ice and slurry ice treatments. However, a lower (p <0.05) fluorescence development was observed for fish treated under ozonised slurry ice when compared to traditionally iced fish. Sensory assessment showed a higher shelf life for fish samples treated under ozonised slurry ice than for their counterparts under slurry ice (15 d versus 12 d), while flake icing led to a far shorter shelf life (5 d). According to sensory and biochemical (lipid matter and nucleotide) analysis, slurry ice has proved to be a promising technology for damage inhibition and quality retention in a fatty fish species such as sardine. Ozonised slurry ice was also shown to be useful, since a longer shelf life was obtained in the present experiment and a pro‐oxidant effect of ozone on sardine lipids was not proved. 相似文献