Influences of iron, manganese, and dissolved organic carbon on the hypolimnetic cycling of amended mercury

The biogeochemical cycling of iron, manganese, sulfide, and dissolved organic carbon were investigated to provide information on the transport and removal processes that control the bioavailability of isotopic mercury amended to a lake. Lake profiles showed a similar trend of hypolimnetic enrichment of Fe, Mn, DOC, sulfide, and the lake spike ((202)Hg, purity 90.8%) and ambient of pools of total mercury (HgT) and methylmercury (MeHg). Hypolimnetic enrichment of Fe and Mn indicated that reductive mobilization occurred primarily at the sediment-water interface and that Fe and Mn oxides were abundant within the sediments prior to the onset of anoxia. A strong relationship (r(2)=0.986, n=15, p<0.001) between filterable Fe and Mn indicated that reduction of Fe and Mn hydrous oxides in the sediments is a common in-lake source of Fe(II) and Mn(II) to the hypolimnion and that a consistent Mn:Fe mass ratio of 0.05 exists in the lake. A strong linear relationship of both the filterable [Fe] (r(2)=0.966, n=15, p<0.001) and [Mn] (r(2)=0.964, n=15, p<0.001) to [DOC] indicated a close linkage of the cycles of Fe and Mn to DOC. Persistence of iron oxides in anoxic environments suggested that DOC was being co-precipitated with Fe oxide and released into solution by the reductive dissolution of the oxide. The relationship between ambient and lake spike HgT (r(2)=0.920, n=27, p<0.001) and MeHg (r(2)=0.967, n=23, p<0.001) indicated that similar biogeochemical processes control the temporal and spatial distribution in the water column. The larger fraction of MeHg in the lake spike compared to the ambient pool in the hypolimnion suggests that lake spike may be more available for methylation. A linear relationship of DOC to both filterable ambient HgT (r(2)=0.406, n=27, p<0.001) and lake spike HgT (r(2)=0.314, n=15, p=0.002) suggest a role of organic matter in Hg transport and cycling. However, a weak relationship between the ambient and lake spike pools of MeHg to DOC indicated that other processes have a major role in controlling the abundance and distribution of MeHg. Our results suggest that Fe and Mn play important roles in the transport and cycling of ambient and spike HgT and MeHg in the hypolimnion, in part through processes linked to the formation and dissolution of organic matter-containing Fe and Mn hydrous oxides particles.     

Feature analysis of women's wedding dresses in new,style weddings in the Wu culture region in modern times北大核心CSCD

To further clarify the features of wedding dresses in new, style weddings in cities and towns of the Wu culture region, the author sorted out and made a statistical analysis of modern journals and periodicals as well as conducted a comparison in combination with diaries of celebrities and novels in modern times to collect 368 wedding photos in total in the Wu culture region. The analysis results indicate that wedding dresses in the Wu culture region were mainly of modified styles from 1859 to 1949, the development of wedding dresses went through the stages of unitary styles, mixed styles and diversified styles, in each of which there were also representative regular ways of matching. In general, wedding dresses were in simple, elegant and delicate styles, and the silhouettes kept up with popular western styles, showing a high level of acceptance of foreign cultures. The colors of wedding dresses tended to combinations of light colors, while traditional colors were gradually reduced. Besides, patterns of flowers and plants with thin stems and leaves were mainly used to decorate wedding dresses, showing the distribution features of scattering and covering. © 2018 China Silk Association. All rights reserved.     

Boosting the electrochemical performance of Li-garnet based all-solid-state batteries with Li<Subscript>4</Subscript>Ti<Subscript>5</Subscript>O<Subscript>12</Subscript> electrode: Routes to cheap and large scale ceramic processing

All-solid-state batteries based on fast Li⁺ conducting solid electrolytes such as Li₇La₃Zr₂O₁₂ (LLZO) give perspective on safe, non-inflammable, and temperature tolerant energy storage. Despite the promise, ceramic processing of whole battery assemblies reaching close to theoretical capacities and finding optimal strategies to process large-scale and low cost battery cells remains a challenge. Here, we tackle these issues and report on a solid-state battery cell composed of Li₄Ti₅O₁₂ / c-Li_6.25Al_0.25La₃Zr₂O₁₂ / metallic Li delivering capacities around 70–75 Ah/kg with reversible cycling at a rate of 8 A/kg (for 2.5–1.0 V, 95 °C). A key aspect towards the increase in capacity and Li⁺ transfer at the solid electrolyte-electrode interface is found to be the intimate embedding of grains and their connectivity, which can be implemented by the isostatic pressing of cells during their preparation. We suggest that simple adaption of ceramic processing, such as the applied pressure during processing, strongly alters the electrochemical performance by assuring good grain contacts at the electrolyte-electrode interface. Among the garnet-type all-solid-state ceramic battery assemblies in the field, considerably improved capacities and cycling properties are demonstrated for Li₄Ti₅O₁₂ / c-Li_6.25Al_0.25La₃Zr₂O₁₂ / metallic Li pressed cells, giving new perspectives on cheap ceramic processing and up-scalable garnet-based all-solid-state batteries.     

Estimation of the error and interference immunity of the analog-to-digital conversion path in automatic control systems

A technique has been devised for determination of the error and interference immunity of the analog- to-digital conversion path in automatic control systems using moving digital averaging. The estimates of the errors and interference immunity of the analog-to-digital conversion path under the moving averaging have been analyzed and compared with the corresponding estimates obtained under averaging within the time-sampling interval and in the absence of averaging. Effective analytical expressions have been obtained to analyze the estimates of the errors and interference immunity of the analog-to-digital conversion of stationary random signals and additive interference. The calculated errors for various differentiable and nondifferentiable random signals given by autocorrelation functions have been analyzed. The influence of the number of the averaged readouts of the random signal and the time-sampling interval on the estimates of the errors and interference immunity have been investigated. The advantage of the moving averaging over the averaging within the time-sampling interval has been demonstrated. The calculated ratios allow, with the known signal and interference models and preset permissible-error estimate, selecting the parameters of the conversion path, i.e., the time-sampling interval, the number of the readouts of the converted sum of the random signal and interference under the averaging, and the effective number of bits of the analog-to-digital converter, under the conditions when the lag error cannot be excluded and the latter is excluded. The equations that allow the evaluation of the interference immunity of the conversion path are provided.     

特大城市地区如何引领实现百年目标

正吴唯佳(中国城市规划学会常务理事,清华大学建筑学院教授,本学术对话主持人):在2020年全面建成小康社会、实现第一个百年目标后,我国将为2049年实现第二个百年目标,建设现代化强国而奋斗。北京、天津、武汉等城市此前已开始加强2049战略研究。特大城市地区是以特大城市为核心,大中小城市相结合的城市密集地区,是我国现代化、城市化的战略引领地区。如何肩负使命,总结经验,认识规律,引领实现     

Spatial model selection strategies in a SUR framework. The case of regional productivity in EU

The purpose of the paper was to compare two well-known model selection strategies, the so-called Specific-to-General, Stge, and General-to-Specific, Gets, in a context of spatial SUR models. The two strategies use a battery of misspecification tests obtained in a maximum likelihood framework. The robust tests to local misspecification errors in the alternative hypothesis and the common factor test have been developed with this purpose. The paper includes a Monte Carlo experiment to compare their performance in a situation of small sample sizes. The results are mixed: Both alternatives work well under ideal conditions, but their efficiency deteriorates for different departures such as non-normality or endogeneity. All in all, Stge appears to be slightly preferable although our impression is that the two are complementary and can be used in common. The paper finishes with an application to the case of productivity for a large set of European regions.