Evaporation of polymer-solvent mixtures

Summary The Stefan-Winkelmann diffusion technique has been used to determine vapor pressures of high boiling point compound-solvents mixtures. Data are reported at a temperature of 67°C for the mixtures polyphenyl ether (6 rings) — benzene and carbowax 1500 — benzene and at a temperature of 100°C for the mixtures polyphenyl ether (6 rings) — toluene and tricresylphosphate-toluene. The range of concentration is only limited by the appearance of a solid phase, and results are in good agreement with those determined by vapor pressure osmometry.Nomenclature A Vapour source - B Flowing gas phase - c Concentration, g-mol/cm³ - D_AB Molecular diffusion coefficient, cm₂/s - h_i Total interface depth, cm - K Parameter defined by equation (6), dimensionless - I Polymer or high boiling point compound - M_A Molecular weight - N_AZ Molar flux, g-mol/(cm₂) (s) - P_A Partial pressure at the interface, atm - P Total pressure, atm - R Gas constant, (atm) (cm₃) / (°K) (g-mol) - T Temperature, °K - t Time, s - Y_A Molar fraction at the interface, dimensionless - z_o Initial interface depth, cm - z_i Drop of the interface depth, cm - z Interface position Greek Letters _A Density of the liquid phase, g/cm³     

A computational fluid dynamic analysis of gas and particle flow in flame spraying

The flame spraying process, which is a common industrial thermal spraying application, has been analyzed by means of three-dimensional computational fluid dynamics (CFD) simulations. The process used at the Volvo Aero Corporation for the coating of fan and compressor housings has been modeled. The process uses the Metco 6P torch (Metco, Westbury, NY), which ejects a mixture of acetylene and oxygen at high speed through a ring of 16 orifices to form the flame. A stream of argon gas flowing through an orifice in the center of the ring carries a powder of nickel-covered bentonite through the flame to the spray substrate. The torch is cooled by a flow of air through an outer ring of 9 orifices. The simulation emulated reality closely by including the individual inlets for fuel, cooling air, and injected particles. The gas combustion was simulated as a turbulent, multicomponent chemically reacting flow. The standard, two-equation k-ε turbulence model was used. The chemical reaction rates appeared as source terms in the species transport equations. They were computed from the contributions of the Arrhenius rate expressions and the Magnussen and Hjertager eddy dissipation model. The first simulations included several intermediate chemical substances whose predicted concentration agreed favorably with measurements. Later, more simplified simulations incorporated only the global chemical reaction involving the initial and the final products, with corrections to the thermal properties being made to account for the missing intermediaries. The gas velocity and temperature fields predicted by the later simulations compared satisfactorily to those predicted by the earlier, more elaborate, ones. Therefore, the final simulations, which incorporated injected particles, were conducted employing the simplified model with only the global reaction. An in-house finite difference code was developed to calculate particle properties. Allowance was made for elliptical shapes, phase changes, and internal heat transfer with regard to the composite material. The particle velocities and temperatures predicted by the final simulations compared fairly well with experimental results obtained with the optical DPV2000 system.     

Influence of Reinforcement Content and Matrix Composition on the Oxidation Resistance of Aluminum-Matrix Composites (A3xx.x/SiCp)

A study was made on the influence of the SiCp proportion and the matrix concentration of four composites (A360/SiC/10p, A360/SiC/20p, A380/SiC/10p, A380/SiC/20p) on their oxidation behavior. Gravimetric tests were used in a kinetics study of the corrosion process at different temperatures (350, 400, 450, and 500°C). The influence of corrosion on mechanical properties was evaluated by hardness measurements. The nature of corrosion products and the influence of the microstructure on the morphology and growth of the oxidation layer were analyzed by SEM and low-angle XRD. The extent of the damage due to oxidation for Al/SiCp composites increases with the SiCp concentration due to the increase of nucleation sites. One of these nucleation sites is in the interface region between the matrix and the particles. Oxidation was influenced more by the percentage of alloy elements in the matrix than by the proportion of SiCp reinforcement. The presence of Cu and Ni in the matrix favors the oxidation process through the formation of different intermetallic compounds.     

A linear algebra approach to OLAP

Inspired by the relational algebra of data processing, this paper addresses the foundations of data analytical processing from a linear algebra perspective. The paper investigates, in particular, how aggregation operations such as cross tabulations and data cubes essential to quantitative analysis of data can be expressed solely in terms of matrix multiplication, transposition and the Khatri–Rao variant of the Kronecker product. The approach offers a basis for deriving an algebraic theory of data consolidation, handling the quantitative as well as qualitative sides of data science in a natural, elegant and typed way. It also shows potential for parallel analytical processing, as the parallelization theory of such matrix operations is well acknowledged.     

Photoacoustic technique for simultaneous measurements of thermal effusivity and absorptivity of pigments in liquid solution

A photoacoustic (PA) methodology, in the transmission configuration, for simultaneous measurements of thermal effusivity and molar absorption coefficient (absorptivity) for pigments in liquid solution is introduced. The analytical treatment involves a self-normalization procedure for the PA signal, as a function of the modulation frequency, for a strong absorbing material in the thermally thin regime, when the light travels across the sample under study. Two fitted parameters are obtained from the analysis of the self-normalized PA amplitude and phase, one of them proportional to the sample's optical absorption coefficient and from which, taking it for a series of samples at different concentrations, the pigment's absorptivity in liquid solution can be measured, the other one yields the sample's thermal effusivity. Methylene blue's absorptivity in distilled water was measured with this methodology at 658 nm, finding good agreement with the corresponding one reported in the literature.     

Note: The intermodulation lockin analyzer

Nonlinear systems can be probed by driving them with two or more pure tones while measuring the intermodulation products of the drive tones in the response. We describe a digital lockin analyzer which is designed explicitly for this purpose. The analyzer is implemented on a field-programmable gate array, providing speed in analysis, real-time feedback, and stability in operation. The use of the analyzer is demonstrated for intermodulation atomic force microscopy. A generalization of the intermodulation spectral technique to arbitrary drive waveforms is discussed.     

Distributed Latency-Energy Minimization and interference avoidance in TDMA Wireless Sensor Networks

This paper presents Latency-Energy Minimization Medium Access (LEMMA), a new TDMA-based MAC protocol for Wireless Sensor Networks (WSNs), specially suited to extend the lifetime of networks supporting alarm-driven, delay-sensitive applications characterized by convergecast traffic patterns and sporadic traffic generation. Its cascading time-slot assignment scheme conciliates low end-to-end latency with a low duty-cycle, while supporting multi-sink WSN topologies. Unlike most of the current solutions, LEMMA’s time-slot allocation protocol makes decisions based on the interference actually experienced by the nodes, instead of following the simple but potentially ineffective n-hop approach. Simulation results are presented to demonstrate the ineffectiveness of the n-hop time-slot allocation in comparison with LEMMA, as well as to evaluate the performance of LEMMA against L-MAC, T-MAC and Low Power Listening. The results show that under the target scenario conditions, LEMMA presents lower interference between assigned time-slots and lower end-to-end latency, while matching its best contender in terms of energy-efficiency.     

On a novel interpretation of PVC antiplasticization based on some local chain conformations

Summary The transition of a poly(vinyl chloride) after either nucleophilic substitution to various extents or plasticization with distinct amounts of diocytl phthalate has been measured by Dynamical Mechanical Thermal Analysis. Both sets of experiments are shown to result in similar loss of transition. The results are argued in the light of prior work on the substitution mechanism determining role of the mmr chain segments at the end of isotactic sequences. They strongly suggest the mmr structures to interact specifically with plasticizer thereby becoming stiffer (antiplasticization).     

Analysis of the inappropriate utilization of the emergency service of a third-level hospital

OBJECTIVE: a) To find the reasons for inadequate use of Hospital Casualty Departments (HCDs); b) to discover the general population's levels of information concerning non-hospital Emergency Services (NESs); c) to analyse the relationship between the type of Primary Care Centre (PCC), i.e. whether reformed or not, and inadequate use of HCDs. DESIGN: A crossover study. SETTING: The Germans Trias i Pujol Hospital Casualty Department, Badalona. PATIENTS: A random sample of 321 patients over 14 years old, who were attended for pathologies considered emergencies not requiring hospital treatment. MEASUREMENTS AND MAIN RESULTS: The variables gathered were: age, gender, where the patient came from, reason for hospital use, knowledge of NESs and subsequent referral. 83.2% of patients attended on their own initiative. The main reasons given were "advantages of a hospital" and "the persistence of symptoms." 49% of the patients stated they knew of the NESs. 80% of the patients proceeded from PCCs which had not been reformed. There were no statistically significant differences (p > 0.05) when the variables "reason for use" and "knowledge of NESs" were compared in relation to where the patient came from (i.e. reformed or non-reformed PCC). CONCLUSIONS: General practitioners in reformed PCCs are less likely to refer to HCDs. Knowledge and use of NESs should be actively supported.