Experimental validation of the discrete-time MCS adaptive strategy

This paper is concerned with the implementation and experimental validation of a discrete-time model reference adaptive control strategy, known as Minimal Control Synthesis (MCS) algorithm. After discussing the proof of stability of the algorithm when applied to discretized models of continuous-time plants, the problem of controlling a highly nonlinear electro-mechanical device is taken as a representative case of study. It is shown that the discrete-time MCS is an effective strategy to solve the problem while guaranteeing robustness to unmodeled nonlinear dynamics over a wide range of test manoeuvres.     

Leaf and stand-level carbon uptake of a Mediterranean forest estimated using the satellite-derived reflectance indices EVI and PRI

Various aspects of global environmental change affect plant photosynthesis, the primary carbon input in ecosystems. Thus, accurate methods of measuring plant photosynthesis are important. Remotely sensed spectral indices can monitor in detail the green biomass of ecosystems, which provides a measure of potential photosynthetic capacity. In evergreen vegetation types, however, such as Mediterranean forests, the amount of green biomass changes little during the growing season and, therefore, changes in green biomass are not responsible for changes in photosynthetic rates in those forests. This study examined the net photosynthetic rates and the diametric increment of stems in a Mediterranean forest dominated by Quercus ilex using three spectral indices (normalized difference vegetation index (NDVI), enhanced vegetation index (EVI), and photochemical reflectance index (PRI)) derived from Moderate Resolution Imaging Spectroradiometer (MODIS) sensors. Average annual EVI accounted for 83% of the variability of the diametric increment of Q. ilex stems over a 10 year period. NDVI was marginally correlated with the diametric increment of stems. This study was the first to identify a significant correlation between net photosynthetic rates and radiation use efficiency at the leaf level using PRI derived from satellite data analysed at the ecosystem level. These results suggest that each spectral index provided different and complementary information about ecosystem carbon uptake in a Mediterranean Q. ilex forest.     

Winter and spring surface velocity fields in the Cape Blanc region as deduced with the maximum cross-correlation technique

The ocean surface velocity field in the Cape Blanc region, off Northwest Africa, is investigated with the maximum cross-correlation (MCC) method applied to channel-4 Advanced Very High Resolution Radiometer satellite images. An initial sensitivity analysis allows us to select the four parameters that provide maximum area coverage and the best velocity resolution, while limiting the standard deviation for each velocity component within reasonable values. These are (m, n, MV, CT)?=?(22, 32, 50, 0.6), where m and n are the number of pixels of the search window (SW) and reference window (RW), respectively, MV is the maximum possible velocity (in cm s^?1), and CT is a correlation threshold for a feature to be tracked. A total of 489 images, for years 2005 and 2006, are analysed, and 106 velocity maps are generated with good coverage of the coastal transition zone (CTZ), most of them for the winter (34) and spring (59) seasons. We remove spurious data using the method's own filters (MV, CT, and a neighbour-vector comparison), requesting the velocity components to have Gaussian distributions and smoothing the resulting velocity fields with a median-vector filter. The instantaneous velocity maps illustrate the response of the alongshore coastal jet north of Cape Blanc (and its extension along the Cape Verde frontal region) to wind forcing, as well as the presence of numerous mesoscalar features (100–300 km wide) superposed on a westward offshore transport south of Cape Blanc. We also produce mean and standard deviation winter and spring velocity maps, which are compared with the corresponding mean sea surface temperature fields. The along-shore and offshore flow is better defined and is more intense in spring than in winter, in concordance with cross-slope sharper temperature gradients during this season, and brings about a cooling of the whole region. We identify five different ubiquitous currents: a southwestward jet north of Cape Blanc, a northwestward jet off Banc d'Argin, an offshore convergent jet, a spring jet-like feature at 18° N, and a southward flow in the southwestern CTZ.     

Decentralized active control of a class of uncertain cable-stayed flexible structures

This paper addresses the problem of designing robust stabilizing controllers for a class of cable-stayed flexible structures. The dynamic behaviour of the structure is characterized by a beam decomposed into a finite number of concentrated masses. The mathematical model exhibits uncertainties in parameters, stay cable geometry and couplings, as well as in the unknown environmental excitation. The controller design is made based on the principle of sliding mode to reduce the magnitude of the transverse vibrations of the structure induced by the environmental excitation. A numerical simulation example is presented to illustrate the effectiveness of the proposed control scheme.     

Lateral Magnetically Modulated Multilayers by Combining Ion Implantation and Lithography

The combination of lithography and ion implantation is demonstrated to be a suitable method to prepare lateral multilayers. A laterally, compositionally, and magnetically modulated microscale pattern consisting of alternating Co (1.6 µm wide) and Co‐CoO (2.4 µm wide) lines has been obtained by oxygen ion implantation into a lithographically masked Au‐sandwiched Co thin film. Magnetoresistance along the lines (i.e., current and applied magnetic field are parallel to the lines) reveals an effective positive giant magnetoresistance (GMR) behavior at room temperature. Conversely, anisotropic magnetoresistance and GMR contributions are distinguished at low temperature (i.e., 10 K) since the O‐implanted areas become exchange coupled. This planar GMR is principally ascribed to the spatial modulation of coercivity in a spring‐magnet‐type configuration, which results in 180° Néel extrinsic domain walls at the Co/Co‐CoO interfaces. The versatility, in terms of pattern size, morphology, and composition adjustment, of this method offers a unique route to fabricate planar systems for, among others, spintronic research and applications.     

Curing of mixtures of epoxy resins and 4‐methyl‐1,3‐dioxolan‐2‐one with several initiators

Diglycidyl ether of bisphenol A or 3,4‐epoxycyclohexylmethyl 3,4‐epoxycyclohexane carboxylate were mixed with different proportions of 4‐methyl‐1,3‐dioxolan‐2‐one and cured using lanthanide triflates as initiators. In order to compare the materials obtained, conventional initiators such as boron trifluoride complexes and N,N‐dimethylaminopyridine were also tested. The curing process was followed by differential scanning calorimetry (DSC) and Fourier transform IR in attenuated total reflectance mode. This technique proved that the carbonate accelerates the curing process because it helps to form the active initiating species, although it was not chemically incorporated into the network and remained entrapped in the material. The DSC kinetic study was also reported. © 2006 Wiley Periodicals Inc. J Appl Polym Sci 102: 2086–2093, 2006     

Self-adaptive utility-based web session management

In the Internet, where millions of users are a click away from your site, being able to dynamically classify the workload in real time, and predict its short term behavior, is crucial for proper self-management and business efficiency. As workloads vary significantly according to current time of day, season, promotions and linking, it becomes impractical for some ecommerce sites to keep over-dimensioned infrastructures to accommodate the whole load. When server resources are exceeded, session-based admission control systems allow maintaining a high throughput in terms of properly finished sessions and QoS for a limited number of sessions; however, by denying access to excess users, the website looses potential customers.In the present study we describe the architecture of AUGURES, a system that learns to predict Web user’s intentions for visiting the site as well its resource usage. Predictions are made from information known at the time of their first request and later from navigational clicks. For this purpose we use machine learning techniques and Markov-chain models. The system uses these predictions to automatically shape QoS for the most profitable sessions, predict short-term resource needs, and dynamically provision servers according to the expected revenue and the cost to serve it. We test the AUGURES prototype on access logs from a high-traffic, online travel agency, obtaining promising results.     

New thermosets obtained by cationic copolymerization of DGEBA with γ‐caprolactone with improvement in the shrinkage. II. Time–temperature–transformation (TTT) cure diagram

Mixtures of diglycidylether of bisphenol A (DGEBA) with different proportions of γ‐caprolactone (γ‐CL) were cured with ytterbium triflate as initiator. The curing was studied with differential scanning calorimetry (DSC) and thermo mechanical analysis (TMA). The results are presented in the form of a time–temperature–transformation diagram. The kinetic analysis was performed by means of the isoconversional integral procedure and the kinetic model was also determined using the Coats–Redfern method. Gelation was determined by means of combined experiences of DSC and TMA. The relationship between the glass transition temperature (T_g) and the degree of conversion α was determined by DSC. Using the isoconversional lines and the T_g‐α relationship, the vitrificacion curve was obtained. The methodology developed makes it possible to obtain the TTT diagram using only no‐isothermal experiments with equivalent results to those using classical isothermal procedures. The addition of γ‐CL accelerates the curing and reduces the shrinkage after gelation and consequently the internal stresses in the material. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Velocity‐based formulations for standard and quasi‐incompressible hypoelastic‐plastic solids

We present three velocity‐based updated Lagrangian formulations for standard and quasi‐incompressible hypoelastic‐plastic solids. Three low‐order finite elements are derived and tested for non‐linear solid mechanics problems. The so‐called V‐element is based on a standard velocity approach, while a mixed velocity–pressure formulation is used for the VP and the VPS elements. The two‐field problem is solved via a two‐step Gauss–Seidel partitioned iterative scheme. First, the momentum equations are solved in terms of velocity increments, as for the V‐element. Then, the constitutive relation for the pressure is solved using the updated velocities obtained at the previous step. For the VPS‐element, the formulation is stabilized using the finite calculus method in order to solve problems involving quasi‐incompressible materials. All the solid elements are validated by solving two‐dimensional and three‐dimensional benchmark problems in statics as in dynamics. Copyright © 2016 John Wiley & Sons, Ltd.     

Bioavailability Studies and in vitro Profiling of the Selective Excitatory Amino Acid Transporter Subtype 1 (EAAT1) Inhibitor UCPH‐102

Although the selective excitatory amino acid transporter subtype 1 (EAAT1) inhibitor UCPH‐101 has become a standard pharmacological tool compound for in vitro and ex vivo studies in the EAAT research field, its inability to penetrate the blood–brain barrier makes it unsuitable for in vivo studies. In the present study, per os (p.o.) administration (40 mg kg^?1) of the closely related analogue UCPH‐102 in rats yielded respective plasma and brain concentrations of 10.5 and 6.67 μm after 1 h. Three analogue series were designed and synthesized to improve the bioavailability profile of UCPH‐102, but none displayed substantially improved properties in this respect. In vitro profiling of UCPH‐102 (10 μm ) at 51 central nervous system targets in radioligand binding assays strongly suggests that the compound is completely selective for EAAT1. Finally, in a rodent locomotor model, p.o. administration of UCPH‐102 (20 mg kg^?1) did not induce acute effects or any visible changes in behavior.