Molecularly imprinted Au nanoparticles composites on Au surfaces for the surface plasmon resonance detection of pentaerythritol tetranitrate, nitroglycerin, and ethylene glycol dinitrate

Molecularly imprinted Au nanoparticles (NPs) composites are generated on Au-coated glass surfaces. The imprinting process involves the electropolymerization of thioaniline-functionalized Au NPs (3.5 nm) on a thioaniline monolayer-modified Au surface in the presence of a carboxylic acid, acting as a template analogue for the respective explosive. The exclusion of the imprinting template from the Au NPs matrix yields the respective imprinted composites. The binding of the analyte explosives to the Au NPs matrixes is probed by surface plasmon resonance spectroscopy, SPR, where the electronic coupling between the localized plasmon of the Au NPs and the surface plasmon wave leads to the amplification of the SPR responses originating from the dielectric changes of the matrixes upon binding of the different explosive materials. The resulting imprinted matrixes reveal high affinities and selectivity toward the imprinted explosives. Using citric acid as an imprinting template, Au NPs matrixes for the specific analysis of pentaerythritol tetranitrate (PETN) or of nitroglycerin (NG) were prepared, leading to detection limits of 200 fM and 20 pM, respectively. Similarly, using maleic acid or fumaric acid as imprinting templates, high-affinity sensing composites for ethylene glycol dinitrate (EGDN) were synthesized, leading to a detection limit of 400 fM for both matrixes.     

High-precision measurement of variations in calcium isotope ratios in urine by multiple collector inductively coupled plasma mass spectrometry

We describe a new chemical separation method to isolate Ca from other matrix elements in biological samples, developed with the long-term goal of making high-precision measurement of natural stable Ca isotope variations a clinically applicable tool to assess bone mineral balance. A new two-column procedure utilizing HBr achieves the purity required to accurately and precisely measure two Ca isotope ratios ((44)Ca/(42)Ca and (44)Ca/(43)Ca) on a Neptune multiple collector inductively coupled plasma mass spectrometer (MC-ICPMS) in urine. Purification requirements for Sr, Ti, and K (Ca/Sr > 10?000; Ca/Ti > 10?000?000; and Ca/K > 10) were determined by addition of these elements to Ca standards of known isotopic composition. Accuracy was determined by (1) comparing Ca isotope results for samples and standards to published data obtained using thermal ionization mass spectrometry (TIMS), (2) adding a Ca standard of known isotopic composition to a urine sample purified of Ca, and (3) analyzing mixtures of urine samples and standards in varying proportions. The accuracy and precision of δ(44/42)Ca measurements of purified samples containing 25 μg of Ca can be determined with typical errors less than ±0.2‰ (2σ).     

Measuring the optical properties of astrophysical dust analogues: instrumentation and methods

Dust is found throughout the universe and plays an important role for a wide range of astrophysical phenomena. In recent years, new IR facilities have provided powerful new data for understanding these phenomena. However, interpretation of these data is often complicated by a lack of complementary information about the optical properties of astronomically relevant materials. The Optical Properties of Astronomical Silicates with Infrared Techniques (OPASI-T) program at NASA's Goddard Space Flight Center is designed to provide new high-quality laboratory data from which we can derive the optical properties of astrophysical dust analogues. This program makes use of multiple instruments, including new equipment designed and built specifically for this purpose. The suite of instruments allows us to derive optical properties over a wide wavelength range, from the near-IR through the millimeter, also providing the capability for exploring how these properties depend upon the temperature of the sample. In this paper, we discuss the overall structure of the research program, describe the new instruments that have been developed to meet the science goals, and demonstrate the efficacy of these tools.     

Microcamera aperture scale in monocentric gigapixel cameras

Multiscale cameras achieve wide-angle, high-resolution imaging by combining coarse image formation by a simplified wide-field objective with localized aberration correction in an array of narrow field microcameras. Microcamera aperture size is a critical parameter in multiscale design; a larger aperture has greater capacity to correct aberration but requires a more complex microcamera optic. A smaller aperture requires integration of more microcameras to cover the field. This paper analyzes multiscale system performance as a function of microcamera aperture for 2 and 40 gigapixel monocentric objective lenses. We find that microcamera aperture diameters of 3 to 12 mm paired with complementary metal oxide semiconductor sensors in the 1 to 15 megapixel range are most attractive for gigapixel-scale cameras.     

MHz-rate nitric oxide planar laser-induced fluorescence imaging in a Mach 10 hypersonic wind tunnel

Nitric oxide planar laser-induced fluorescence (NO PLIF) imaging at repetition rates as high as 1 MHz is demonstrated in the NASA Langley 31 in. Mach 10 hypersonic wind tunnel. Approximately 200 time-correlated image sequences of between 10 and 20 individual frames were obtained over eight days of wind tunnel testing spanning two entries in March and September of 2009. The image sequences presented were obtained from the boundary layer of a 20° flat plate model, in which transition was induced using a variety of different shaped protuberances, including a cylinder and a triangle. The high-speed image sequences captured a variety of laminar and transitional flow phenomena, ranging from mostly laminar flow, typically at a lower Reynolds number and/or in the near wall region of the model, to highly transitional flow in which the temporal evolution and progression of characteristic streak instabilities and/or corkscrew-shaped vortices could be clearly identified.     

Modeling the performance of residential building envelope: The role of sustainable energy performance indicators

The success of modeling the sustainable performance of the residential building envelope will be to a great extent associated to the sustainable energy performance indicators used. The sustainable energy performance indicators that these building assessment models are developed around should be chosen by taking into account the targeted objectives. However, it is very common to find building performance assessment models that do not take into account these considerations and therefore have a limited capability and scope. This leads to inadequate aggregate indicators for the actual assessment of the sustainable performance of the building envelope for a sustainable energy efficient building. The focus of this paper is to investigate the principal sustainable energy performance indicators for modeling the sustainable performance of the residential building envelope and develop an approach for determining the most appropriate sustainable energy performance indicators. In doing that, this paper provides an overview of previous research on sustainable energy performance indicators and discusses conceptual framework for developing sustainable energy performance indicators. In order to identify these indicators that influence the capability of building performance assessment models, a comprehensive survey of construction industry professionals was conducted using questionnaire survey technique while the data was analyzed using correlation analysis techniques.     

Spatial mismatch and the affordability of public transport for the poor in Singapore’s new towns

Singapore has redeveloped its Central Area into business districts and relocated the affected population to new towns. Unfortunately, this strong center policy has hindered the development of employment sub-centers. Most jobs are located in the Central Area, resulting in a spatial mismatch that the government is attempting to address by building a world-class public transport system. However, the poor not only face affordability problems and long travel times for employment, but they are also experiencing a shrinking supply of employment due to economic restructuring. Route tests were conducted, and the results indicate that the poor, who generally choose to travel by bus, have to spend up to 9.8% of their household income per month and 70 min per trip from their neighborhoods to the city center. Those who take the hub-and-spoke network have to spend 13.2% of household income and take 60 min for similar trips. To increase the job-seeking range of these people, they should be offered concessions to encourage use of the hub-and-spoke network. The government should also build a light-rail transit line to pass through the Central Catchment Nature Reserve to connect employment sub-centers.     

Heat and cold stresses in different climate zones across China: A comparison between the 20th and 21st centuries

Summer and winter discomfort in terms of heat and cold stresses in the nine major architectural climate zones and sub-zones across China in the 21st century were investigated using predictions from general circulation models for the low and medium emissions scenarios. For the six severe cold and cold climate zones in the north, reductions in cumulative cold stress outweighed the increase in cumulative heat stress resulting in an overall decreasing trend in the annual cumulative stress, and vice versa for the other three warmer climate zones in the south. Compared with the 20th century, significant reduction in the cumulative cold stress was observed across the six zones in severe cold and cold climates, ranging from 15.8 in cold-III to 42.3 in severe cold-II. There were modest increases in the cumulative heat stress from 0.3 in cold-II to 12.3 in cold-III. For the warmer climates in the south, reduction in cumulative cold stress ranged from 7.6 in hot summer and warm winter (HSWW) to 10.3 in hot summer and cold winter, while cumulative heat stress increased from 9.9 in the mild zone to 30.6 in HSWW. A reduction in cold stress would result in less winter heating and an increase in heat stress more cooling requirement.     

Reliability analysis of roof sheathing panels exposed to a hurricane wind

Light-frame wood roofs are frequently used in the US for residential and commercial construction. High wind events, such as hurricanes, may cause severe damage to these structures by breaking the roof envelope and allowing penetration of wind-driven rain. Most previous wood panel reliability studies have used static, uniform wind pressure load models and code-specified load distribution rules for analysis. This study re-estimates the reliability of roof sheathing panels exposed to a specific hurricane event using actual wind pressure data and a more refined structural analysis model. The objective is to examine the adequacy of the simplified wind load and structural analysis models used for roof panel reliability analysis. In the procedure here, panel failure behavior is modeled by individual fastener extraction from the panel as dynamic wind pressure is increased. For reliability analysis, the limit state is based on panel pull-off. The results show that the use of a refined model provides some significant differences in panel reliability found from simplified techniques.     

Enhanced Electron Mobility Due to Dopant‐Defect Pairing in Conductive ZnMgO

The increase of the band gap in Zn_1‐xMg_xO alloys with added Mg facilitates tunable control of the conduction band alignment and the Fermi‐level position in oxide‐heterostructures. However, the maximal conductivity achievable by doping decreases considerably at higher Mg compositions, which limits practical application as a wide‐gap transparent conductive oxide. In this work, first‐principles calculations and material synthesis and characterization are combined to show that the leading cause of the conductivity decrease is the increased formation of acceptor‐like compensating intrinsic defects, such as zinc vacancies (V_Zn), which reduce the free electron concentration and decrease the mobility through ionized impurity scattering. Following the expectation that non‐equilibrium deposition techniques should create a more random distribution of oppositely charged dopants and defects compared to the thermodynamic limit, the paring between dopant Ga_Zn and intrinsic defects V_Zn is studied as a means to reduce the ionized impurity scattering. Indeed, the post‐deposition annealing of Ga‐doped Zn_0.7Mg_0.3O films grown by pulsed laser deposition increases the mobility by 50% resulting in a conductivity as high as σ = 475 S cm^‐1.