The effect of electron damage on silicon solar cells coated with diamond‐like carbon films

The unique properties of the diamond‐like carbon (a:DLC), such as high mechanical hardness and abrasive resistance, optical transparency in the visible and IR spectral regions and high thermal conductivity, provide this material with advantages over other types of protecting materials for solar cells. Furthermore, the a:DLC films are inert to corrosive gases and other corrosive agents. Resistance to radiation damage of the a:DLC films deposited on solar cells is very important for space application. In the study we investigate the effect of electron damage on silicon solar cells coated with a:DLC films. We measure the I – V characteristic and the spectral response and calculate the values of the seven parameters of the double exponential solar cell model (usually not investigated) as a function of electron fluence irradiation. In addition we obtain also the usual external parameters I_sc, V_oc, I_m, V_m, FF, and efficiency) of the solar cells. We investigate solar cells with and without anti‐reflecting coating coated with a:DLC films which were exposed to electron radiation. The main findings show that the solar cells with a:DLC films of thickness up to 500 nm degrade similarly to regular silicon cells exposed to electron irradiation. The degradation of the spectral response of the solar cell is mainly in the range of longer wavelengths and the irradiation affects the solar cell parameters (mainly the reverse saturation currents). Copyright © 2000 John Wiley & Sons, Ltd.     

Low-frequency noise in TaSiN/HfO/sub 2/ nMOSFETs and the effect of stress-relieved preoxide interfacial layer

Low-frequency noise characteristics are reported for TaSiN-gated n-channel MOSFETs with atomic-layer deposited HfO/sub 2/ on thermal SiO/sub 2/ with stress-relieved preoxide (SRPO) pretreatment. For comparison, control devices were also included with chemical SiO/sub 2/ resulting from standard Radio Corporation of America clean process. The normalized noise spectral density values for these devices are found to be lower when compared to reference poly Si gate stack with similar HfO/sub 2/ dielectric. Consequently, a lower oxide trap density of /spl sim/4/spl times/10/sup 17/ cm/sup -3/eV/sup -1/ is extracted compared to over 3/spl times/10/sup 18/ cm/sup -3/eV/sup -1/ values reported for poly Si devices indicating an improvement in the high-/spl kappa/ and interfacial layer quality. In fact, this represents the lowest trap density values reported to date on HfO/sub 2/ MOSFETs. The peak electron mobility measured on the SRPO devices is over 330 cm/sup 2//V/spl middot/s, much higher than those for equivalent poly Si or metal gate stacks. In addition, the devices with SRPO SiO/sub 2/ are found to exhibit at least /spl sim/10% higher effective mobility than RCA devices, notwithstanding the differences in the high-/spl kappa/ and interfacial layer thicknesses. The lower Coulomb scattering coefficient obtained from the noise data for the SRPO devices imply that channel carriers are better screened due to the presence of SRPO SiO/sub 2/, which, in part, contributes to the mobility improvement.     

Testing the Interactivity Principle: Effects of Mediation, Propinquity, and Verbal and Nonverbal Modalities in Interpersonal Interaction

Early channel reliance research compared different modes of communication to assess relationships among nonverbal and verbal cues. Emerging communication technologies represent a new venue for gaining insights into the same relationships. In this article, the authors advance a principle of interactivity as a framework for decomposing some of those relationships and report an experiment in which physical proximity—whether actors are in the same place ("co-located") or interacting at a distance ("distributed")—and the availability of other nonverbal environmental, auditory, and visual information in distributed modes is varied. Results indicate that both proximity and availability of nonverbal cues affect communication processes, social judgments participants make about each other, and task performance. The authors discuss implications about gains and losses due to presence of nonverbal features.     

A method for coordinating the distributed transmission of imagery.

Distributed imaging using sensor arrays is gaining popularity among various research and development communities. A common bottleneck within such an imaging sensor network is the large resulting data load. In applications for which transmission power and/or bandwidth are constrained, this can drastically decrease the sensor network lifetime. We present an algorithm that efficiently exploits inter- and intrasensor correlation for the purpose of power-constrained distributed transmission of sensor-network imagery. Gains in network lifetime up to 114% are obtained when using the suggested algorithm with lossless compression. Our results also demonstrate that when lossy compression is employed, much larger gains are achieved. For example, when a normalized root-mean-squared error of 0.78% can be tolerated in the received measurements, the network lifetime increases by a factor of 2.8, as compared to the (optimized) lossless case.     

Efficiency Enhancement in Organic Photovoltaic Cells: Consequences of Optimizing Series Resistance

Here, means to enhance power conversion efficiency (PCE or η) in bulk‐heterojunction (BHJ) organic photovoltaic (OPV) cells by optimizing the series resistance (R_s)—also known as the cell internal resistance—are studied. It is shown that current state‐of‐the‐art BHJ OPVs are approaching the limit for which efficiency can be improved via R_s reduction alone. This evaluation addresses OPVs based on a poly(3‐hexylthiophene):6,6‐phenyl C₆₁‐butyric acid methyl ester (P3HT:PCBM) active layer, as well as future high‐efficiency OPVs (η > 10%). A diode‐based modeling approach is used to assess changes in R_s. Given that typical published P3HT:PCBM test cells have relatively small areas (～0.1 cm²), the analysis is extended to consider efficiency losses for larger area cells and shows that the transparent anode conductivity is then the dominant materials parameter affecting R_s efficiency losses. A model is developed that uses cell sizes and anode conductivities to predict current–voltage response as a function of resistive losses. The results show that the losses due to R_s remain minimal until relatively large cell areas (>0.1 cm²) are employed. Finally, R_s effects on a projected high‐efficiency OPV scenario are assessed, based on the goal of cell efficiencies >10%. Here, R_s optimization effects remain modest; however, there are now more pronounced losses due to cell size, and it is shown how these losses can be mitigated by using higher conductivity anodes.     

Inverted polymer solar cells with a solution-processed cesium halide interlayer

We demonstrate the utility of a low-cost cesium iodide interlayer spun from an aqueous or 2-ethoxyethanol solution on ITO in inverted polymer solar cells of the structure ITO/CsI/P3HT:PCBM/MoO₃/Al, where P3HT is poly(3-hexylthiophene) and PCBM is [6,6]-phenyl-C₆₀-butyric acid methyl ester. The power conversion efficiency (PCE) of optimized cells was ～3.4%, comparable to that we obtained for inverted cells with Cs carbonate. The thickness of the CsI film was adjusted by varying the solution concentration. The concentration affected the surface morphology of P3HT:PCBM and the density of fractal-like aggregates (possibly related to the presence of Cs and film fabrication conditions) formed near the anode, as revealed by scanning electron microscopy. Auger analysis indicated a P3HT-rich surface. Optimization of the cells was achieved also by varying the thickness of the MoO₃ and the drying/annealing conditions of the active layer, as was evident from the current–voltage characteristics, external quantum efficiency spectra, and PCE. The cells with the CsI interlayer were compared additionally to cells with CsCl or CsF interlayers (with a PCE of up to ～2.7%), which were inferior to the comparable cells with Cs₂CO₃ or CsI. The surface concentrations of Cs and the halide on ITO were monitored using X-ray photoelectron spectroscopy. The iodine level was low with the Cs:I ratio exceeding 8:1. In contrast, the Cs:Cl ratio was ～1.4:1 and the Cs:F ratio was ～1:1; the Cs₂CO₃ decomposed partially, as expected. Therefore, for CsI, as is the case for Cs₂CO₃ but not for CsF, Cs–O bonds are formed at the surface. Such bonds on ITO are important in modifying the ITO work function, improving the cell performance. The results indicate that spin coating solutions of the high polarity CsI is a promising and easy approach to introduce Cs–O on ITO in inverted structures for increased electron extraction from PCBM and possibly hole extraction from the P3HT-rich surface at the anode.     

Z-source inverter for motor drives

This paper presents a Z-source inverter system and control for general-purpose motor drives. The Z-source inverter system employs a unique LC network in the dc link and a small capacitor on the ac side of the diode front end. By controlling the shoot-through duty cycle, the Z-source can produce any desired output ac voltage, even greater than the line voltage. As a result, the new Z-source inverter system provides ride-through capability during voltage sags, reduces line harmonics, improves power factor and reliability, and extends output voltage range. Analysis, simulation, and experimental results will be presented to demonstrate these new features.     

Scaling and technological limitations of 1/f noise and oscillator phase noise in SiGe HBTs

This paper examines the impact of SiGe HBT scaling on 1/f noise and phase noise of oscillators and frequency synthesizers. The increase of transistor speed with scaling is shown to significantly increase the sensitivity of oscillation frequency to 1/f noise and, thus, degrade close-in phase noise, but decrease the sensitivity of oscillation frequency to base current shot noise and base resistance thermal noises. The results show that corner offset frequency defined by the intersect of the 1/f³ and 1/f² phase noise has little to do with the traditional 1/f corner frequency. The relative importance of individual noise sources in determining phase noise is examined as a function of technology scaling, device sizing, and oscillation frequency. The collector current shot noise and base resistance noise are shown to set the fundamental limits of phase noise reduction. A methodology to identify the maximum tolerable 1/f K factor is established and demonstrated for the HBTs used     

Single-Cell Microgels for Diagnostics and Therapeutics

Cell encapsulation within hydrogel droplets is transforming what is feasible in multiple fields of biomedical science such as tissue engineering and regenerative medicine, in vitro modeling, and cell-based therapies. Recent advances have allowed researchers to miniaturize material encapsulation complexes down to single-cell scales, where each complex, termed a single-cell microgel, contains only one cell surrounded by a hydrogel matrix while remaining <100 μm in size. With this achievement, studies requiring single-cell resolution are now possible, similar to those done using liquid droplet encapsulation. Of particular note, applications involving long-term in vitro cultures, modular bioinks, high-throughput screenings, and formation of 3D cellular microenvironments can be tuned independently to suit the needs of individual cells and experimental goals. In this progress report, an overview of established materials and techniques used to fabricate single-cell microgels, as well as insight into potential alternatives is provided. This focused review is concluded by discussing applications that have already benefited from single-cell microgel technologies, as well as prospective applications on the cusp of achieving important new capabilities.