3D Micro-PIXE at atmospheric pressure: A new tool for the investigation of art and archaeological objects

The paper describes a novel experiment characterized by the development of a confocal geometry in an external Micro-PIXE set-up. The position of X-ray optics in front of the X-ray detector and its proper alignment with respect to the proton micro-beam focus provided the possibility of carrying out 3D Micro-PIXE analysis. As a first application, depth intensity profiles of the major elements that compose the patina layer of a quaternary bronze alloy were measured. A simulation approach of the 3D Micro-PIXE data deduced elemental concentration profiles in rather good agreement with corresponding results obtained by electron probe micro-analysis from a cross-sectioned patina sample. With its non-destructive and depth-resolving properties, as well as its feasibility in atmospheric pressure, 3D Micro-PIXE seems especially suited for investigations in the field of cultural heritage.     

Fugitive Diffusion Barrier for Integration of Sol-Gel-Derived Lead Titanate with Oxidized Silicon Substrates

The crystalline phase development and microstructural changes with heating of sol-gel-derived lead titanate (PT) particles and films on silica with and without a fugitive (or removable) diffusion barrier layer were investigated. Amorphous gel-derived PT particles were deposited on SiO₂-coated TEM grids with and without polyimide (PI) or carbon barrier layers between SiO₂ and PT. TEM analysis showed that PI or carbon barriers prevented reaction between the gel-derived PT particles and SiO₂. PT particles crystallize and then the PI or carbon film decomposes. Sol-gel-derived PT films were deposited on oxidized Si substrates (Si/SiO₂) with and without a PI barrier layer. Perovskite PT films were prepared on Si/SiO₂ substrates with a PI barrier; however, some porosity remained in the films. Identically prepared films without the PI barrier formed a mixture of pyrochlore and perovskite. X-ray photoelectron spectroscopy results indicate that the PI film pre- vents the diffusion of Si into the PT film.     

Failure mode analysis for a hazardous waste clean-up manipulator

This paper describes the application of Fault Tree Analysis to the design phase of a robot manipulator for hazardous waste retrieval. The robot is to be deployed in single-shell under-ground storage tanks at the US Department of Energy (DOE) site in Hanford, Washington. These tanks contain a variety of highly radioactive waste types, necessitating extremely safe and reliable manipulator operation. Based on preliminary design drawings of this long-reach manipulator, fault trees were constructed for several critical failure scenarios. Analysis of the trees revealed a number of ways to improve the safety and reliability of the manipulator design. This paper presents a summary of the fault tree analysis, with a discussion of the applicability of qualitative and quantitative fault tree methods to hazardous waste robotics.     

The effects of feedback on performance and retention of skill for a natural language interface

This study investigated the effectiveness of different types of on-line feedback following user errors for informing users of the information and functions available in a system with a natural language interface. Twenty-four individuals performed a task based on an industry cost savings program, in which they were given general goals to pursue with regard to the task. Three feedback levels which differed according to the type and amount of feedback provided, along with two levels of system complexity, were examined. In addition, subjects performed the task again after one week to determine the effects of feedback on retention. Results indicated that the subjects in the second level of feedback generally performed better with respect to accessing system functions and information than those in the first level. Although there was some performance improvement from the second to third level, it was not significant. However, the third level of feedback did significantly improve the efficiency with which subjects used information to complete the task during the return condition. Overall, feedback did not affect the errors made, though at certain more limited stages of the tasks this effect was observed.     

Constant boost control of the Z-source inverter to minimize current ripple and voltage stress

This paper proposes two constant boost-control methods for the Z-source inverter, which can obtain maximum voltage gain at any given modulation index without producing any low-frequency ripple that is related to the output frequency and minimize the voltage stress at the same time. Thus, the Z-network requirement will be independent of the output frequency and determined only by the switching frequency. The relationship of voltage gain to modulation index is analyzed in detail and verified by simulation and experiments.     

Silicon Valley Policy

Silicon Valley is hom e to the m ostdynam ic industries in the C aliforniaeconom y .These industries —— thehigh-tech sector—— are driven by in-novation,and each new wave of inno-vation is usually led by cre ativeentrepreneurs starting new firm s.D uri…     

Electrostatic Charging and Levitation of Helium II Drops

Liquid Helium II drops, of diameter 1 mm or less, are charged with positive helium ions and subsequently levitated by static electric fields. Stable levitation was achieved for drops of order 100–150 micrometers in diameter. The suspended drops could be translated to arbitrary positions within the levitator using additional superimposed DC electric fields, and also could be made to oscillate stably about their average positions by means of an applied time-varying electric field. A weak corona discharge was used to produce the necessary ions for levitation. A novel superfluid film flow device, developed for the controlled deployment of large charged drops, is described. Also discussed is an adjustable electric fountain that requires only a field emission tip operating at modest potentials, and works in both Helium I and Helium II.     

Recent advances in the stabilization of flexible and semirigid PVC

Both the European and USA markets for liquid mixed metal stabilizers have moved or are moving to cadmium-free products. Self-lubricating products now dominate demanding areas such as calendering and extrusion in the European marketplace while the USA market has produced higher efficiency products by other means. In both markets, the use of organic costabilizers has played a major role in the formulation of cadmium-free products. The merits of self-lubricating technology and a new class of patented pyrrolidines are discussed here.     

Ultrasonographically-guided fine-needle aspiration cytology in the diagnosis of colonic lesions

BACKGROUND: The use of fine-needle aspiration cytology (FNAC) in the diagnosis of colonic lesions was investigated. METHODS: Some 22 patients (median age 71 years) with a colonic lesion identified on abdominal ultrasonography underwent ultrasonographically-guided FNAC using a 21-G needle. The sample was checked immediately by a cytopathologist for adequacy. RESULTS: Eighteen patients had colonic carcinoma; aspiration cytology detected malignant epithelial cells consistent with colonic carcinoma in 17 patients and severely dysplastic cells in one patient. The sensitivity and specificity of ultrasonographically-guided FNAC in the diagnosis of colonic carcinoma was 94 and 100 per cent respectively. The remaining four patients had a diagnosis of ileocaecal tuberculosis, ileocaecal Crohn's disease, and metastatic adenocarcinoma in the liver with no identifiable primary (two patients). One demonstrated granulomata, grew acid-fast bacilli and the patient was treated for tuberculosis. One had inflammatory cells and the patient was found to have Crohn's disease on histology. The remaining two patients had confirmed metastatic adenocarcinoma in the liver on aspiration cytology but suspected colonic lesions were found to be benign on cytological examination and no primary lesion was subsequently demonstrated. There were no complications of FNAC and patients complained of minimal discomfort. There has been no evidence of tumour recurrence with a median follow-up of 12 (range 1-25) months. CONCLUSION: Ultrasonographically-guided FNAC is a valid method for the diagnosis of colonic tumours.