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41.
Yanhan Shen Rongrong Qi Qiaochu Liu Yanling Wang Yapeng Mao Juan Yu 《应用聚合物科学杂志》2008,110(4):2261-2266
The grafting of a polymer can lead to the improvement and modification of the polymer and thus expand its applications. Grafting methods include solution grafting in organic solvents, melt grafting at high temperatures, and light grafting with radioactive sources. These methods have their advantages and disadvantages. The disadvantages include waste treatment, consumption of energy, and so on. In this study, a hydrothermal process which is called the green approach, was developed to prepare graft copolymers. The effect of various factors on the grafting degree was investigated in detail. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
42.
43.
根据具体工程实例,介绍了在基坑开挖时采用土钉加锚杆的联合支护方式后在施工过程中出现坍塌裂缝的现象,针对这一现象,分析了施工条件与环境,得出了事故发生的原因,并结合实际情况提出了处理措施. 相似文献
44.
为了改善筛分机械的使用环境,降低筛分机械的噪声,从噪声源入手,从内因和外因两个方面分析了筛分机噪声的形成原因。论述了USL和USK系列振动筛在降低噪声方面所采取的先进技术措施。 相似文献
45.
The Humanitarian Engineering initiative, sponsored by the William and Flora Hewlett Foundation, at the Colorado School of Mines, is creating a program that will support engineering students in understanding their responsibility for solving community development problems that exist throughout the world. As part of this effort, data has been collected on faculty and student attitudes using the ‘Community Service Attitudes Scale,” developed and validated by Shiarella, McCarthy, and Tucker. During the fall 2004, 78 students and 34 faculty members responded to this instrument. Statistically significant differences were found between the attitudes of students and faculty, males and females, and among different age groupings with respect to service activities. A general finding was that faculty displayed better attitudes toward community service than the students. 相似文献
46.
José Luis Montañez-Soto Salvador Alegret Juan Alfredo Salazar-Montoya Emma Gloria Ramos-Ramírez 《European Food Research and Technology》2006,223(3):379-386
In this work a novel amperometric biosensor for fructose determination in solutions was developed. The device was constructed by the incorporation of a tetrathiofulvalene-tetracyanoquinodimethane organic conducting salt and fructose dehydrogenase enzyme, include in a polymeric matrix of epoxy resin and graphite powder. Because of the electrocatalytic function of the salt, the direct transfer of the electron between the reduced prosthetic group (PQQH2) of the enzyme and the transducing material, was verified at a low working potential (150 mV vs. Ag/AgCl), where the interfering reactions were minimized. The response time at 90% of the steady state value was less than 20 s. The current response was directly proportional to the D-fructose concentration from 0.01 to 0.3 mmol/l with a detection limit of 0.005 mmol/l (signal/noise of 3) and a sensitivity of 1.9985 μA/mmol. The biosensor sensitivity diminishes when its surface is not polished between successive determinations, and remains constant (rsd=1.85, n=10) when the surface is polished between determinations. The effects of temperature and pH on the biosensor response were studied and analyzed; also the properties of the enzyme (Km
ap, I
max, Q10) were determinate in this work. The biosensor was used to determine fructose in high fructose syrups and there were not significant differences between these results and those obtained by HPLC (p≤0.05). During 4 months, in intermittent determinations the biosensor kept 100% of its original sensitivity and after 18 months stored at 4°C, it only lost 32% of its sensitivity. The simplicity, low working potential, high stability and good performance of this biosensor shows a great potential for its use in the fructose determination. 相似文献
47.
The conversion of heavy paraffin and aromatics into a high-quality diesel fraction was performed in a microplant using a WNiPd/CeY-alumina catalyst. The effects of aromatics and naphtheno-aromatics on mild hydrocracking of hexadecane were studied at different concentrations. Two catalysts, with and without Pd and thermal treatment, were characterized by FTIR, XPS, and TPD of ammonia and ammonia plus naphthalene to complement previous study about the surface composition. The hydrocracking activity and selectivity were tested using different amounts and types of aromatics. This study demonstrated the presence of two acid strengths that contribute in different ways to paraffin and aromatics isomerization, ring opening, and cracking reactions. The product distribution obtained by mild hydrocracking of n-C16 is between amorphous (SiO2Al2O3) and Y-zeolite type of support. The aromatic adsorption on acid sites reduces the cracking rate and improves the survival of di- and tri-branched paraffin. A model for the path of reaction is discussed to explain the results. 相似文献
48.
Intelligent multisensor surveillance systems consist of several types of sensors, which are installed on fixed and mobile devices. These components provide a huge quantity of information that has to be contrasted, correlated and integrated in order to recognize and react on special situations. These systems work in highly dynamic environments, with severe security and robustness requirements. All these characteristics imply the need for distributed solutions. In these solutions, scattered components can decide and act with some degree of autonomy (for instance, if they become isolated), or cooperate and coordinate for a complete tracking of special situations. In order to cope with these requirements and to better structure the solution, we have decided to design surveillance system control as a multiagent system. This is done by applying an agent-orientated methodology, which is assessed with concrete scenarios. 相似文献
49.
Jesús Canales-Vázquez Juan Carlos Ruiz-Morales David Marrero-López Juan Peña-Martínez Pedro Núñez Pedro Gómez-Romero 《Journal of power sources》2007
In the work presented herein, the potential use of La4Sr8Ti12−xFexO38−δ (LSTF) materials as electrodes for a new concept of solid oxide fuel cells, symmetrical fuel cells (SFCs), is considered. Such fuel cells use simultaneously the same material as anode and cathode, which notably simplifies the assembly and further maintenance of the cells. Therefore, we search for materials showing high conductivity in a wide range of oxygen partial pressures in addition to certain degree of catalytic activity for the oxidation of the fuel and reduction of the oxidant, respectively. The preliminary electrochemical experiments performed reveal that the overall conductivity increases notably upon Fe substitution, being the main contribution electronic n-type. The fuel cell tests indicate that LSTF composites with YSZ and CeO2 perform reasonably well under H2 conditions, although the performance in methane is rather modest and require further optimisation. 相似文献
50.