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41.
42.
Heikki Kallio Saska Tuomasjukka Anu Johansson Raija Tahvonen Niina Nieminen Olli Sjvall Juha‐Pekka Kurvinen Hanna Kivini 《European Journal of Lipid Science and Technology》2005,107(2):101-106
Currant oils have special health properties due to their moderate contents of α‐linolenic, γ‐linolenic and stearidonic acids. The distribution of fatty acids (FA) in the triacylglycerols (TAG) may affect the beneficial effects. Seed oils of wild northern red currant (NRC) (Ribes spicatum L.) from Northern Finland and of wild alpine currant (AC) (R. alpinum L.) from the South‐West coast of Finland were investigated. The purified TAG were analysed by tandem mass spectrometry by applying the ammonia negative ion chemical ionisation – collision‐induced dissociation method. Molecular weight fractions rich in C18:3 FA and C18:4 FA were investigated. Of the total oil, the molecular weight species 54:7 (ACN:DB), 54:8 and 54:9 were more abundant in NRC than in AC, being 21.0%, 15.8%, 7.4% and 16.2%, 11.2%, 4.8%, respectively (p <0.05). The species 52:6 was more abundant in AC (3.1%) than in NRC (2.6%) (p <0.05). The preferential order of FA to be in the sn‐2 position in both berries was typically C18:1 > C18:2 > C18:4 > C18:3. No difference was observed between relative locations of C16:0 FA and C18:3 FA in either of the oils. Within the TAG consisting of FA combinations C18:3/C18:3/C18:1 (54:7), C18:1 was more preferentially in the sn‐2 position (p <0.05) in AC (93.2%) than in NRC (74.6%), and in the case of C18:3, the preference was vice versa. Within the molecular weight species 54:9, FA combination C18:4/C18:3/C18:2, linoleic acid preferentially occupied the secondary position (p <0.005) in both berries, and the proportion of the TAG regioisomer pair sn‐C18:3‐C18:4‐C18:2 + sn‐C18:2‐C18:4‐C18:3 was more abundant (30.2%) in NRC than in AC (15.3%). Within the TAG species 52:6, proportions of all the existing combinations, C16:0/C18:3/C18:3, C16:0/C18:4/C18:2 and C16:1/C18:3/C18:2, varied between the two berry species (p <0.005). 相似文献
43.
Nicolai Czink Giovanni Del Galdo Xuefeng Yin Ernst Bonek Juha Ylitalo 《Wireless Personal Communications》2008,46(1):83-98
In this work we introduce a novel metric for characterizing the double-directional propagation environment and use this metric
to assess the performance of a SAGE parameter estimator for MIMO channels. Using the IlmProp, a geometry-based MIMO channel
modeling tool, we construct synthetic channels for three different scenarios showing: (i) well separated clusters containing
dense propagation paths, and single-bounce scattering; (ii) partly overlapping clusters containing widely spread propagation
paths, and single-bounce scattering; (iii) unclustered multipath components (“rich scattering”), and double-bounce-only scattering.
We model the scatterers and the receiver in the environment as fixed, but the transmitter as moving. The Initialization and
Search-Improved SAGE (ISIS) estimation tool is used to extract the propagation paths from the constructed channels. Both true
and estimated paths are fed to the new system-independent metric which genuinely reflects the structure of the channel and
the compactness of the propagation paths. We use this metric to decide on the accuracy of the channel estimator. The results
show a convincing agreement between true and estimated paths. 相似文献
44.
L. Juha B. Ehrenberg S. Couris E. Koudoumas V. Hamplov Z. Pokorn A. Mü llerov M. Pavel 《Fullerenes, Nanotubes and Carbon Nanostructures》2000,8(4):319-336
In this paper we describe the efficient and substantial decomposition of C60 in toluene solution, induced by moderate intensity (I = 20 - 55 MW cm-2) near infrared (γ = 1064 nm) laser radiation. This behavior is surprising since both uncharged fullerene and toluene do not have any absorption bands at this wavelength. The decomposition efficiency and products are investigated with UV-Vis absorption spectrophotometry and high-performance liquid-chromatography (HPLC). Possible mechanisms of the fullerene decomposition are discussed. 相似文献
45.
Juha Nikkola Riitta Mahlberg Juha Mannila Saila Jämsä 《Journal of Coatings Technology and Research》2010,7(4):441-448
Recently, inorganic–organic hybrid coatings produced by the sol–gel route have proven to be a potential protective treatment
for wooden surfaces. In this study, the effect of curing process on simulated antisoiling properties of sol–gel coating was
investigated. The sol–gel coating was spray-coated on pine sapwood and cured with different temperature and time combinations.
The antisoiling properties were studied by measuring the water contact angle of the coating after different curing processes.
In addition, abrasion resistance and contact angle of oleic acid were measured. An optical profilometer was used to investigate
surface roughness of the coating. Sufficient hydro- and oleophobicity were obtained with all of the curing parameters. The
comparison between curing parameters showed that lower temperature and 1–3 h curing time leads to significant improvement
in the durability of the water and oil repellent properties of the coating. 相似文献
46.
Solution state 1H NMR is employed to study the mode and strength of chloroform adsorption on conjugated acid–base pairs of cation-exchanged Y-zeolites. 1H NMR results indicate that two different surface bonding orientations may exist. An acidic hydrogen site of zeolite favours orientation where the chloroform hydrogen points towards the zeolite cage centre. An exchanged electropositive cation increases the basicity of framework oxygens of zeolite and directs the chloroform to adsorb on framework oxygens with a hydrogen bond. In this adsorption site the chemical shift of the chloroform hydrogen has a linear dependence on the electronegativity of the cation. 相似文献
47.
Workflow Concurrency Control 总被引:5,自引:0,他引:5
48.
Abstract We discuss the role of Bose enhancement of the dipole matrix element in photoassociation, using stimulated Raman adiabatic passage as an example. In a non-degenerate gas the time scale for coherent optical transients tends to infinity in the thermodynamic limit, whereas Bose enhancement keeps this time scale finite in a condensate. Coherent transients are therefore absent in photoassociation of a thermal non-degenerate gas, but are feasible if the gas is a condensate. 相似文献
49.
Gravure offset printing of polymer inks for conductors 总被引:2,自引:0,他引:2
A gravure offset printing process has been developed for Ag-filled polymer conductor ink. Pad printing and roller type printing have been used. Curing and electrical properties have been studied. A roller type of gravure offset printing has been used to evaluate the printing process and pad printing to print on the non-planar substrates. Based on differential scanning calorimetry (DSC) and resistivity measurements during ink curing, it was found that the ink had an optimum curing temperature of 140 °C. Square resistance of 300 and 150 μm wide lines can be as low as 20 and 28 mΩ/sq., respectively, for 7–8.5 μm thick line. The minimum line width was 70 μm. This minimum line width can be reduced with different ink solvents, but in this case the line thickness suffers and the square resistance increases, respectively. 相似文献
50.
The integration of different energy systems, e.g., industrial and municipal, is potentially important for the efficient utilization of energy. It is important that the tools for analysing this type of integration can handle the energy systems on different levels, e.g., regional, site, plant and process levels. In this work, a framework for investigating the cost-efficient integration of large-scale energy systems is presented and tested at the UPM-Kymmene Kaukas pulp and paper plant and in the municipality of Lappeenranta, Finland. In addition to the different levels, the framework also aims to take into account several sub-problems, e.g., fuel logistic, optimal heat exchanger network and overall efficiency versus flexibility. The case in question shows that the presented framework can be used as a systematic tool for analysing the potential of integrating large energy systems and that it is able to handle both the synthesis of flexible heat exchanger networks and analyse the cost-efficiency of changes to the existing systems. 相似文献