全文获取类型
收费全文 | 129787篇 |
免费 | 3345篇 |
国内免费 | 469篇 |
专业分类
电工技术 | 1105篇 |
综合类 | 2355篇 |
化学工业 | 21579篇 |
金属工艺 | 5646篇 |
机械仪表 | 3960篇 |
建筑科学 | 3558篇 |
矿业工程 | 655篇 |
能源动力 | 2372篇 |
轻工业 | 11565篇 |
水利工程 | 1657篇 |
石油天然气 | 555篇 |
武器工业 | 7篇 |
无线电 | 10954篇 |
一般工业技术 | 23266篇 |
冶金工业 | 12832篇 |
原子能技术 | 523篇 |
自动化技术 | 31012篇 |
出版年
2024年 | 92篇 |
2023年 | 389篇 |
2022年 | 835篇 |
2021年 | 1302篇 |
2020年 | 929篇 |
2019年 | 1112篇 |
2018年 | 15658篇 |
2017年 | 14586篇 |
2016年 | 11434篇 |
2015年 | 1938篇 |
2014年 | 1938篇 |
2013年 | 3603篇 |
2012年 | 5717篇 |
2011年 | 11990篇 |
2010年 | 10314篇 |
2009年 | 7536篇 |
2008年 | 8574篇 |
2007年 | 9329篇 |
2006年 | 1478篇 |
2005年 | 2395篇 |
2004年 | 2229篇 |
2003年 | 2141篇 |
2002年 | 1451篇 |
2001年 | 760篇 |
2000年 | 837篇 |
1999年 | 767篇 |
1998年 | 3235篇 |
1997年 | 2188篇 |
1996年 | 1477篇 |
1995年 | 847篇 |
1994年 | 698篇 |
1993年 | 773篇 |
1992年 | 290篇 |
1991年 | 307篇 |
1990年 | 205篇 |
1989年 | 227篇 |
1988年 | 229篇 |
1987年 | 200篇 |
1986年 | 165篇 |
1985年 | 215篇 |
1984年 | 168篇 |
1983年 | 131篇 |
1982年 | 163篇 |
1981年 | 178篇 |
1980年 | 191篇 |
1979年 | 97篇 |
1978年 | 97篇 |
1977年 | 350篇 |
1976年 | 744篇 |
1973年 | 84篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
991.
Summary The synthesis is reported of copolymers of styrene with methacrylic acid and of methyl methacrylate with methacrylic acid by radical copolymerization, of copolymers of methyl methacrylate with methacrylic acid by partial alkaline hydrolysis of poly(methyl methacrylate), and of block copolymers of styrene with methacrylic acid. Modified titration curves of all these copolymers were recorded in water and water-ethanol solutions. In a solution containing 50 mass.% ethanol, only small differences could be observed between the potentiometric behaviour of the individual copolymers and polymethacrylic acid. Also, there were no essential differences in any of the solvents used between the potentiometric behaviour of block copolymers of styrene with methacrylic acid, on the one hand, and polymethacrylic acid, on the other. On the contrary, maxima and minima were always observed on the modified titration curves of statistical copolymers with a higher content of the hydrophobic comonomer in solutions with a high water content. Thus, using the modified titration curves, it is possible to decide whether a given copolymer is of the block or statistical type. 相似文献
992.
The effects of air oxidation of three Spanish coals on the pressure exerted during carbonization have been studied. Coals were oxidized by air in an oven at 120 and 140 °C. The extent of oxidation was assessed by the Audibert-Arnu dilatometer test. Coal samples oxidized at different levels were subjected to the Koppers-lncar laboratory coking pressure test. The results obtained indicated that for coals classified as ‘dangerous’ the ‘danger’ increased and reached a maximum at a certain level of oxidation, after which it decreased sharply. This behaviour did not occur with coals classified as safe. 相似文献
993.
A series of new polyamides 3a–d containing aryl-azo, ether and sulfone groups in the main chain were synthesized from bis[4-(4-aminophenoxy)phenyl sulfone]
1 and several azo aromatic diacyl chlorides 2a–d by the low temperature solution polycondensation technique. FTIR spectroscopy, nuclear magnetic resonance (NMR) and elemental
analyses confirmed the structure of these polymers. Owing to the aryl and amide groups in the main chain, these polymers exhibit
photochromic properties as well as excellent thermal stabilities. The transition temperatures (T
g) are between 242 and 265 °C, and the char yields at 800 °C in nitrogen atmosphere were above 39%. Based on incorporation
of flexible ether linkages and polar sulfone groups, the polyamides show desirable solubility in organic solvents such as
DMAc, N,N-dimethylformamide (DMF), N-methyl-2-pyrroidinone (NMP) and dimethylsulfoxide (DMSO). And it is exemplified that
polyamide containing 2 and 2′ substitutes performed better solubility.
Funded by the National Natural Science Foundation of China (No. 50572081) 相似文献
994.
A micro-envioment for nerve cells and tissue growth were designed and constructed via surface modification of poly(L-lactide-co-glycolide)(PLGA)
with chitosan and hydroxyapatite(HA). The poly(L-lactide-co-glycolide)/chitosan/hydroxyapatite (PLGA/chitosan/HA) conduits
were manufactured by a combined solvent casting and particulate leaching technique. The conduits were highly porous with an
interconnected pore structure and 76.5% porosity. Micropores with 50–100 micrometer diameter were formed in the conduits.
In vivo application of PLGA/chitosan/HA conduits for reconstruction of 10 mm sciatic nerve defect was assessed by the walking
track analysis, the quantifying of the wet weight of tibialis anterior muscle and the histological assessment. The conduits
in host rats in vivo can not only be an effective in promoting regenerating of nerves but can also lead to favorable nerve
functional recovery.
Funded by the National Natural Science Foundation of China(No.50774096) 相似文献
995.
郑立霞 《武汉理工大学学报(材料科学英文版)》2009,24(3):415-417
The deformation resistance effect of polyacrylonitrile (PAN)-based carbon fibers was investigated, and the variatipn law of
electrical resistivity under tensile stress was analyzed. The results show that the gauge factor (fractional change in resistance
per unit strain) of PAN-based carbon fibers is 1.38, which is lower than that of the commonly-used resistance strain gauge.
These may due to that the electrical resistivity of carbon fibers decreases under tensile stress. In addition when the carbon
fibers are stretched, the change of its resistance is caused by fiber physical dimension and the change of electric resistivity,
and mainly caused by the change of physical dimension. The mechanical properties of carbon fiber monofilament were also measured.
Funded by the National Natural Science Foundation of China (No. 10672128 and 50878170) 相似文献
996.
王智宇 《武汉理工大学学报(材料科学英文版)》2009,24(5):698-701
A simple sonochemical route for the surface coating of titanium dioxide on cadmium sulfide nanocrystal was reported. After
2 h ultrasonic irradiation treatment, the mixture of CdS nanocrystals and tetrabutyl titanate in an aqueous medium yielded
CdS/TiO2 nanocrystals composites with core/shell structure. The thickness of TiO2 layer with smooth interface could be easily controlled via changing the concentration of the precursors and the time of irradiation.
The core/shell nanocrysrals were characterized by X-ray diffraction, transmission electron microscope and UV-vis spectrometry
techniques. The prepared semiconductor composites with particular band structure present appealing properties especially in
photochemical activity. 相似文献
997.
何庆复 《武汉理工大学学报(材料科学英文版)》2009,24(3):428-431
Behaviour of hardening and serration yield of a Fe-Ni-Cr alloy under isothermal cycling (ISC) and out-phase TMF was studied
on the basis of varied hysteresis loops. Cycling hardening and serrated yielding for ISC depend on the temperature and the
total strain range, stronger hardening with serrated yielding at higher strain range under ISC at 600 °C, but no hardening
and serrated yielding occurred under ISC at 800 °C. Stronger hardening with stress serration occurred at the thermal path
going to the lowest temperature, no stress serration occurred at the highest temperature under the out-phase. The hardening
also depends on the total strain range, higher total strain range with lower cycling temperature resulted in a stronger hardening
and remarkable serration yielding behavior. Weaker hardening without serrated yielding occurred at near 800 °C may due to
an obvious cycling stress drop under out-phase TMF. Change in the shape of the hysteresis loops also expresses the degree
of the damage of the tested alloy under out-phase and ISC. 相似文献
998.
章桥新 《武汉理工大学学报(材料科学英文版)》2009,24(6):871-874
Silver powder was fabricated by spray pyrolysis, using 2%–20% AgNO3 solution, 336–500 mL/h flux of AgNO3 solution, 0.28–0.32 MPa flux of carrier gas and in the 620–820 °C temperature range. The effects of furnace set temperature,
concentration of AgNO3 aqueous solution, flux of AgNO3 aqueous solution as well as carrier gas on the morphology and particle size distribution of silver powder, were investigated.
The experimental results showed that with the high concentration of AgNO3 aqueous solution, the average grain size of silver decreased with the increasing of furnace set temperature. But the gain
size distribution was not homogenous, the discontinuous grain growth occurred. With the low concentration of AgNO3 aqueous solution, the higher furnace set temperature made the nano sliver grains sintered together to grow. Nano silver powder
about 100 nm was fabricated by spray pyrolysis, using 2wt% AgNO3 solutions, 336 mL/h flux of AgNO3 aqueous solution, 0.32 MPa flux of carrier gas at 720 °C furnace set temperature. 相似文献
999.
贺海燕 《武汉理工大学学报(材料科学英文版)》2009,24(3):359-362
Fatigue-free Bi3.2La0.8Ti3O12 ferroelectric thin films were successfully prepared on p-Si (100) substrates using metalorganic solution deposition process. The orientation and formation of 5-layers thin films
were studied under different processing conditions using XRD. Experimental results indicate that increase in annealing time
at 700 °C after preannealing for 10 min at 400 °C can remarkably increase (200)-orientation of the films derived from the
precursor solutions with two contents of citric acid. Meanwhile, high content of citric acid increases the film thickness
and is conducive to the a-orientation of the films with the preannealing, and low concentration of the solution is conducive to the c-orientation of
the films without the preannealing. 相似文献
1000.
A series of dimer acid-based polyamides were synthesized by melt-polycondensation of dimer acid and various aromatic diamines,
and were characterized by Fourier transform infrared spectrum (FT-IR) and nuclear magnetic resonance (1H NMR). The physical properties of the polyamides, such as glass transition temperature, melting temperature, decomposition
temperature and mechanical properties were also investigated. The polyamides’ intrinsic viscosity ranges from 1.8 dL·g−1 to 2.2 dL·g−1, and the melting temperature ranges from 140 °C to 181 °C. The glass transition temperatures, observed from dynamic mechanical
analysis, fall in the range of 34.8–48.2 °C. The physical and mechanical properties of the resultant polyamides are similar
to those of the PA1212. The heat resistance and mechanical properties of poly (4, 4′-diphenylsulfone dimeramide) (PSD) and
poly(4, 4′-diphenyl dimeramide) (PPDI) are comparable to those of PA1212. 相似文献