Studies of the pH of the membrane surface in a laboratory chlor-alkali cell

The pH on the surface of an ion-exchange membrane was measured with a microprobe in a laboratory scale chlor-alkali cell to study the leakage of OH^– through the membrane. The solution pH in the vicinity of the membrane facing the anode was found to be considerably higher than that in the bulk solution because of penetration and leakage of OH^–. The pH varied with the membrane type. This explains why the carboxylate membrane is not protonated and can be used as a separator in chlor-alkali cells.Deceased.     

Size Distribution of Gold Nanoparticles Used by Small Angle X-ray Scattering

The size distribution of gold nanoparticles was estimated based on the scattering intensity data obtained from small angle X-ray scattering (SAXS) and compared with the result of micrographs by transmission electron microscopy. The slope of the Guinier plot was used to estimate the mean size assuming a narrow particle size distribution. When the size distribution is narrow, the mean size can be easily obtained from slope of a Guinier plot of scattering data within 10% error. Additionally, assuming a lognormal size distribution, the size distribution and the mean size can be calculated using the experimental SAXS data in the fitting analysis. The histogram method, which utilizes the coefficient matrix of scattering intensity, was also applied to the estimation of the size distribution, and this method could be useful for a rough estimate of the size distribution.     

Analysis of PD-generated SF/sub 6/ decomposition gases adsorbed on carbon nanotubes

Chemical byproducts analysis has been recognized as a powerful diagnosis method for SF₆ gas-insulated switchgear (GIS). The authors have previously demonstrated that a carbon nanotube (CNT) gas sensor could detect partial discharge (PD) generated in SF₆ gas. However, PD-generated decomposition gas species, which were responsible for the CNT gas sensor response, have not been identified yet. In this paper, two kinds of experiments were conducted in order to identify the responsible decomposition gas species. At first, the decomposition gas molecules adsorbed on CNTs were analyzed by Fourier transformation infrared (FTIR) spectroscopy. FTIR absorbance was observed around 735 cm^-1 after CNTs were exposed to PD generated in SF₆. In the second experiment, the CNT gas sensor responses to typical SF₆ decomposition products (HF and SF₄) were examined. The CNT gas sensor responded to these gases in the same way as to PD generated in SF₆. SF₄ response was larger than HF response. Based on these results, SF ₄ and SOF₂ emerged as candidates for the responsible decomposition gases. Electrochemical interactions between adsorbed gas molecules and CNT were discussed based on theoretical predictions of molecular orbital calculations. The calculation results suggested that both of SOF₂ and SF₄ could increase the CNT gas sensor conductance     

Impurity effect on Kramer-Pesch core shrinkage ins-wave vortex and chiralp-wave vortex

The low-temperature shrinking of the vortex core (Kramer-Pesch effect) is studied for an isolated single vortex for chiral p-wave and s-wave superconducting phases. The effect of nonmagnetic impurities on the vortex core radius is numerically investigated in the Born limit by means of a quasiclassical approach. It is shown that in the chiral p-wave phase the Kramer-Pesch effect displays a certain robustness against impurities owing to a specific quantum effect, while the s-wave phase reacts more sensitively to impurity scattering. This suggests chiral p-wave superconductors as promising candidates for the experimental observation of the Kramer-Pesch effect.     

HSPF Simulation of Runoff and Sediment Loads in the Upper Changjiang River Basin, China

To evaluate the performance of a computer model simulating runoff and sediment load in the upper region of the Changjiang (Yangtze River) basin over a relatively short time interval, including examining the applicability of the input precipitation data generated from global circulation models and satellite data, we used a spatially distributed model, HSPF with the International Satellite Land Surface Climatology Project (ISLSCP) precipitation data for 1987 and 1988 as input data. The Nash–Sutcliffe coefficient (R2) for 5-day average streamflow was 0.94 in the calibration period and 0.95 in the verification period for the whole upper region. Moreover, the model simulated the 5-day average streamflow well in each main tributary, as shown by R2 values of 0.46–0.96, except that it underestimated the peak flow rates during the flood season over 2 years by up to 71% in Tuojiang and 61% in Jialingjiang. The model simulated the 5-day concentrations of suspended solids (SS) fairly well in the headwaters and upper regions of the Jinshajiang, Yalongjiang, and Minjiang watersheds, as shown by R2 values of 0.31–0.65. In the other regions, however, the model underestimated the SS load by up to 72%, and rarely simulated the fluctuation of SS concentration in each river channel during the flood season. These errors led to the underestimation of sediment runoff volume from the whole upper region during the flood season, as shown by the ratio of the simulated sediment load to the observed data at Yichang: 0.69 in the calibration period and 0.68 in the verification period. The ISLSCP precipitation tended to be more frequent and less intense than the measured precipitation. This was probably the main reason why the HSPF did not perform well in all regions at all times.     

Coupled simulation of BES-CFD and performance assessment of energy recovery ventilation system for office model

Thermal comfort and indoor air quality as well as the energy efficiency have been recognized as essential parts of sustainable building assessment. This work aims to analyze the energy conservation of the heat recovery ventilator and to investigate the effect of the air supply arrangement. Three types of mixing ventilation are chosen for the analysis of coupling ANSYS/FLUENT (a computational fluid dynamics (CFD) program) with TRNSYS (a building energy simulation (BES) software). The adoption of mutual complementary boundary conditions for CFD and BES provides more accurate and complete information of indoor air distribution and thermal performance in buildings. A typical office-space situated in a middle storey is chosen for the analysis. The office-space is equipped with air-conditioners on the ceiling. A heat recovery ventilation system directly supplies fresh air to the office space. Its thermal performance and indoor air distribution predicted by the coupled method are compared under three types of ventilation system. When the supply and return openings for ventilation are arranged on the ceiling, there is no critical difference between the predictions of the coupled method and BES on the energy consumption of HVAC because PID control is adopted for the supply air temperature of the occupied zone. On the other hand, approximately 21% discrepancy for the heat recovery estimation in the maximum between the simulated results of coupled method and BES-only can be obviously found in the floor air supply ventilation case. The discrepancy emphasizes the necessity of coupling CFD with BES when vertical air temperature gradient exists. Our future target is to estimate the optimum design of heat recovery ventilation system to control CO₂ concentration by adjusting flow rate of fresh air.     

Calculation of the uniform breakdown field strength of SF6 gas

We calculated the uniform dielectric breakdown field strength of SF₆ gas over the temperature range of 300 to 3000 K. The local thermal equilibrium (ITE) composition of the dissociated gas is connected to the electron impact collision cross sections of the species SF₆, F₂, F and S. The critical reduced electric field strength of the composition is determined by a balancing electron generation and loss modeled by chemical reactions evaluated by the electron energy distribution function (EEDF) derived from the Boltzmann transport equation. At room temperature, pure SF₆ has a critical reduced electric field strength of 362 Td. With increasing temperature and decreasing density we found a small decrease of this value, whereas at temperatures higher than 1500 K, dissociation starts to decrease the dielectric strength of the composition. Furthermore, we found that generation of electrons by (associative) detachment from F ^- starts to play an important role at temperatures >2500 K, where the critical field strength still has a value of 118 Td. This value is found to decrease rapidly afterwards with increasing temperature to the value of 38 Td at 3000 K. The calculated results agree very well with independently predicted values and measured data     

220 kV金属氧化物避雷器故障类型分析与处理

对近年上海220 kV金属氧化物避雷器故障进行分析,介绍了避雷器在线监测仪指针卡涩引起示数偏大、避雷器表面脏污或内部受潮等引起发热的问题,针对不同故障现象列举了带电检测和停电试验等故障诊断方法,并总结了故障诊断过程中的注意事项,以保证人身及设备安全.     

Expression of fibrogenic cytokines in desmoplastic malignant melanoma

OBJECTIVE: Research has confirmed substantial links between OCD and AN. Not only are there psychopathological similarities between the two syndromes, but a marked neurochemical correspondence. Extensive exercising is a common feature of AN and also has relevance in its links with OCD. There is evidence from the exercise-induced weight-loss syndrome in animals that exercise and caloric restriction, in combination, tend to increase serotonergic activity in a synergistic manner. This syndrome has been proposed as a valid model of OCD as well as for AN. To date, little research has directly tested this theory in the human condition. METHOD: Fifty-three AN patients were categorized as high-level exercisers (N = 22) or moderate/nonexercisers (N = 31) based on the frequency of their physical activity over the year before assessment. RESULTS: Exercisers scored significantly higher on a measure of OC personality characteristics, OC symptomatology, and perfectionism--a personality factor associated with the development of Obsessive-Compulsive Personality Disorder. On the other hand, there were no group differences on other salient eating disorder characteristics such as body esteem, self-esteem, or weight preoccupation. There were also no differences in degree of emaciation as indicated by Body Mass Index. CONCLUSIONS: Findings suggest that among AN patients obsessional personality characteristics are linked to high-level exercising, and that exercising is associated with a greater degree of OC symptomatology. Results are discussed in the context of current theories of AN, OCD, and some biological mechanisms.     

单目视觉人工路标辅助INS的组合导航定位方法

提出一种单目视觉人工路标辅助惯性导航系统(Inertial Navigation System,INS)的定位方法。首先设计人工路标,并用相机拍摄各预先设置的人工路标,记录拍摄每个路标时相机位置和姿态,建立视觉路标库。在利用惯性导航系统定位过程中,对单目相机采集到的图像进行路标提取、与路标库中相应路标进行匹配,估计当前相机位置和姿态,然后利用卡尔曼滤波将视觉匹配估计的位置信息和INS有效地融合。实验结果表明:传统航位推算方法的平均误差为0.715 m,本文组合导航方法的平均误差为0.154 m,该方法有效地提高了惯性导航定位的精度。