A Convenient Synthesis of Some Coumarin Derivatives Using SnCl2 · 2H2O as Catalyst

Some substituted coumarins have been synthesized by von-Pechmann condensation using SnCl₂ · 2H₂O (10 mol %) as catalyst in ethanolic medium. The reactions are simple, easy in handling and environmentally benign.     

Refractories for handling steel outside a furnace

A range of refractories is presented for handling steel outside a furnace, which are produced by the Borovichi Refractories Corporation. The refractory characteristics and working features are given. Translated from Novye Ogneupory, No. 9, pp. 29–35, September, 2008.     

Factors of large graphite crucible life

Production methods used to prepare graphite crucibles with high operating properties are considered: use as a filler of good graphitizing acicular coke, vibration molding of the original coke mix, use of production cycles for impregnation with medium temperature coal-tar pitch — firing, firing of compacted billets in metal containers, graphitization of fired billets in graphite cylinders. The last two production methods make it possible to reduce the temperature drop throughout the volume of a billet during heat treatment, and as a consequence to reduce crack development to a minimum as a result of reducing thermal stresses. All of the production methods recommended may be entirely accomplished in existing electrode plants and may be used to increase markedly the quality crucible graphite. It is possible to achieve a quality for these materials at the best world level. Translated from Novye Ogneupory, No. 8, pp. 28–33, August 2008.     

A method of reducing the thermal stresses in the lining of the tuyere belt in a nonferrous metallurgy converter

Research results are given on magnesian box-type components in the tuyere belt of horizontal converters at Ufalei Nickel Corporation. The purpose has been to eliminate the zoning in them by impregnation with nickel or copper mattes to relieve thermal stresses during use. Components impregnated with matte show improved physicomechanical and thermophysical properties. A technology has been developed and tested for impregnating standard components under conditions found at Ufalei Nickel Corporation. Translated from Novye Ogneupory, No. 5, pp. 44–47, May, 2008.     

Highly resistant dispensing nozzles based on zirconium dioxide for profiled CBCM. Part 1. Structure and physicomechanical properties of materials based on zirconium dioxide for producing CBCM dispensing nozzles

Technology is developed for preparing refractory components made of partially stabilized zirconium dioxide using an isostatic compaction press. Technology is provided for manufacturing dispensing nozzles using combined and separately stabilized zirconium dioxide, and also indices of the refractories obtained and imported materials are compared. __________ Translated from Novye Ogneupory, No. 3, pp. 127–131, March 2008.     

A light refractory concrete for thermal insulation

Compositions have been developed for nonshrinking vibrocast thermally insulating light refractory concretes with densities of 1.0, 1.3, 1.5, and 1.8 g/cm³ for temperatures of use up to 1400°C. The structure and properties have been examined for the concrete of density 1.3 g/cm³. __________ Translated from Novye Ogneupory, No. 4, pp. 29–32, April, 2008.     

Secondary Aluminum Production Waste — A Raw Material for the Refractory Industry

Secondary aluminum waste products, and processes that occur during heating and mineral formation on introducing fine periclase powder into the composition of waste products are studied. It is demonstrated that secondary aluminum production waste may be used as a raw material for synthesizing aluminomagnesia spinels. Translated from Novye Ogneupory, No. 6, pp. 15–18, June 2008.     

Total and Fractional Performance of Granular Dust Traps in Refractory Production

Methods are proposed for designing interpolation models for the preliminary determination and subsequent forecasting of general and fractional breakthrough coefficients for dust used with granular filters, as employed in energy-saving and high-performance dust trapping from technological gases and ventilation discharges in refractory production. The models are supplied with nomograms, which makes them widely suitable for experts working in environmental protection at refractory-producing organizations. The main factors are identified that influence the performance. The results are of interest to experts in related areas of industry such as building materials and engineering ceramics and so on. Translated from Novye Ogneupory, No. 4, pp. 64–67, April, 2008.     

Influence of the preparation conditions on the size and morphology of nanocrystalline lanthanum orthoferrite

Nanocrystalline LaFeO₃ is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO₃ nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size.     

Generalized model of the formulation of the required composition of pitch-coke mixtures

Known methods of calculating the required compositions of pitch-coke mixtures in producing large graphitized electrodes are not widely used [1, 2]. This may be attributed to the multivariance of the problem, the probabilistic character of the technological operations, the lack of well-founded optimization criteria, and the sensitivity of the characteristics of the product to variation in the parameters of the initial materials and their ratios in the mixture. The only means of solving the problem is physical modeling, taking account of current computer capabilities.