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21.
Rönnholm Mats R. Hernández Carucci José R. Arve Kalle Eränen Kari Salmi Tapio 《Topics in Catalysis》2007,42(1-4):195-198
A silver/alumina catalyst was tested for its NO
x
reduction activity during oxygen-rich conditions and during variation in the input parameters (nitric oxide, octane and oxygen).
The experimental data using the microreactor was investigated by means of artificial neural networks (ANN). 相似文献
22.
Heikki Kallio Saska Tuomasjukka Anu Johansson Raija Tahvonen Niina Nieminen Olli Sjvall Juha‐Pekka Kurvinen Hanna Kivini 《European Journal of Lipid Science and Technology》2005,107(2):101-106
Currant oils have special health properties due to their moderate contents of α‐linolenic, γ‐linolenic and stearidonic acids. The distribution of fatty acids (FA) in the triacylglycerols (TAG) may affect the beneficial effects. Seed oils of wild northern red currant (NRC) (Ribes spicatum L.) from Northern Finland and of wild alpine currant (AC) (R. alpinum L.) from the South‐West coast of Finland were investigated. The purified TAG were analysed by tandem mass spectrometry by applying the ammonia negative ion chemical ionisation – collision‐induced dissociation method. Molecular weight fractions rich in C18:3 FA and C18:4 FA were investigated. Of the total oil, the molecular weight species 54:7 (ACN:DB), 54:8 and 54:9 were more abundant in NRC than in AC, being 21.0%, 15.8%, 7.4% and 16.2%, 11.2%, 4.8%, respectively (p <0.05). The species 52:6 was more abundant in AC (3.1%) than in NRC (2.6%) (p <0.05). The preferential order of FA to be in the sn‐2 position in both berries was typically C18:1 > C18:2 > C18:4 > C18:3. No difference was observed between relative locations of C16:0 FA and C18:3 FA in either of the oils. Within the TAG consisting of FA combinations C18:3/C18:3/C18:1 (54:7), C18:1 was more preferentially in the sn‐2 position (p <0.05) in AC (93.2%) than in NRC (74.6%), and in the case of C18:3, the preference was vice versa. Within the molecular weight species 54:9, FA combination C18:4/C18:3/C18:2, linoleic acid preferentially occupied the secondary position (p <0.005) in both berries, and the proportion of the TAG regioisomer pair sn‐C18:3‐C18:4‐C18:2 + sn‐C18:2‐C18:4‐C18:3 was more abundant (30.2%) in NRC than in AC (15.3%). Within the TAG species 52:6, proportions of all the existing combinations, C16:0/C18:3/C18:3, C16:0/C18:4/C18:2 and C16:1/C18:3/C18:2, varied between the two berry species (p <0.005). 相似文献
23.
Thomas Garoff Laura Mannonen Marjo Väänänen Virgine Eriksson Kalle Kallio Päivi Waldvogel 《应用聚合物科学杂志》2010,115(2):826-836
The characteristic features of LLDPE polymerization with ZN catalyst are the time drift effect during polymerization and the bending effect when trying to decrease density of the copolymer by adding more comonomer to the polymerization. The time drift in LLDPE polymerization is revealed by a constant decrease of comonomer incorporation during polymerization time. The bending is revealed by difficulties in lowering the density of LLDPE material below the density of 920 kg/m3. With increasing comonomer content during polymerization, the density does not decrease, but the soluble fraction increases. To try to observe if these phenomena are connected, two types of catalysts, SiO2 supported and precipitated MgCl2 ZN catalysts, were studied. A short time (10 min) and an extended time (60 min) copolymerization test series where the polymerizations were performed in the presence of a gradually increasing comonomer amount. Both catalysts show a strong bending when density is presented as a function of 1‐hexene both in 10‐ and 60‐min polymerization, indicating no connection between time drift and bending. The density, melting point, and crystallinity results all indicate that both catalysts are making similar copolymer material with identical chemical composition distribution. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
24.
Rapeseed oil was oxidized chemically and thermally to produce two distinct oxidized oils. These oils, along with unoxidized
oils, were subjected to an artificial digestion model to simulate the digestive processes in humans. Lipid digestion involves
lipases that break down the intact triacylglycerol (TAG) molecules first to diacylglycerols, and eventually to sn-2-monoacylglycerols (MAG) and free fatty acids. A high performance liquid chromatography-evaporative light scattering detector-electrospray
ionization-mass spectrometric (HPLC–ELSD–ESI–MS) method was developed to monitor the lipolysis and the presence of oxidized
lipids. The HPLC–ELSD–ESI–MS analysis enabled the separation and detection of nearly all the lipid species present in the
sample after TAG hydrolysis. The HPLC–MS analyses of digestion products revealed that oxidized triacylglycerols are hydrolyzed
by the digestive enzymes in a manner similar to that of native, unoxidized molecules. Significant amounts of sn-1(3)-MAG were found in all the samples after lipolysis, however, more of these were found in unoxidized rapeseed oil samples
than in the oxidized oils. Several oxidized molecules were identified with the aid of synthesized oxylipids. This novel method
is scalable to small-scale preparative fractionation of oxidized lipid molecules from a complex digestion sample. Also, the
fingerprint-like, diagnostic, MS profiles of oxidized oils, reference compounds, and digestion products may be a great aid
in comprehensive analysis of lipid oxidation and lipolysis. 相似文献
25.
Volatile compounds of Baltic herring analysed by dynamic headspace sampling–gas chromatography–mass spectrometry 总被引:1,自引:1,他引:1
Aro Tarja Tahvonen Raija Koskinen Lotta Kallio Heikki 《European Food Research and Technology》2003,216(6):483-488
European Food Research and Technology - The effect of storage time at 6&;nbsp;°C on the volatile compounds of Baltic herring was studied using the dynamic headspace–gas... 相似文献
26.
27.
The separation of γ- and α-linolenic acid containing triacylglycerols with an identical acyl carbon number and degree of unsaturation
was obtained on capillary supercritical fluid chromatography using a 25% cyanopropyl−75% methylpolysiloxane stationary phase.
The resolution of 1,3-dioleoyl-2-γ-linolenoyl-sn-glycerol and 1,3-dioleoyl-2α-linolenoyl-sn-glycerol was 1.35 on a 10 m×50 μm i.d. column, whereas the resolution was enhanced to 1.66 by combining two 10-meter columns
in series. The difference in the position of double bonds in one linolenic acid residue of triacylglycerols resulted in two
series of peaks in the separation of alpine currant (Ribes alpinum) and black currant (R. nigrum) seed oils. The use of the 10-meter column was found to be appropriate for the screening of the triacylglycerol profile in
both seed oils studied. 相似文献
28.
Magnus Oskarsson Kalle Åström Niels Chr. Overgaard 《Journal of Mathematical Imaging and Vision》2006,26(3):327-343
In this paper we investigate the structure and motion problem for calibrated one-dimensional projections of a two-dimensional environment. The theory of one-dimensional cameras are useful in several areas, e.g. within robotics, autonomous guided vehicles, projection of lines in ordinary vision and vision of vehicles undergoing so called planar motion. In a previous paper the structure and motion problem for all cases with non-missing data was classified and solved. Our aim is here to classify all structure and motion problems, even those with missing data, and to solve them. In the classification we introduce the notion of a prime problem. A prime problem is a minimal problem that does not contain a minimal problem as a sub-problem. We further show that there are infinitely many such prime problems. We give solutions to four prime problems, and using the duality of Carlsson these can be extended to solutions of seven prime problems. Finally we give some experimental results based on synthetic data. 相似文献
29.
We have investigated the evolution of chronic glomerular changes in the absence of the recurrence of original disease in an experimental rat model of chronic renal allograft rejection. Using serial graft needle biopsies and serum creatinine levels, we were able to focus on early glomerular changes that are associated with good graft function. The recipient rats were divided into 5 groups, 2 with allogeneic (DA to WF) transplants and 3 with syngeneic (DA to DA) transplants. In the first 2 allogeneic groups, one group received cyclosporine (CsA) for 2 weeks (n = 7) and the other received CsA for 12 weeks (n = 5). In the 2-week treatment group, all allografts developed chronic rejection, compared with none in the 12-week group. Syngeneic controls received CsA for 2 (n = 3) and 12 weeks (n = 3), or no immunosuppression (n = 2) in order to exclude the effects of CsA. The first detectable ultrastructural event was slight deposition of electron lucent material in the glomerular basement membrane. Contrary to previous morphological studies, the initial deposition was not subendothelial, but was within the lamina densa itself. Examination of allogeneic grafts with good graft function and syngeneic grafts showed glomerular alterations that were similar to the early changes preceding chronic rejection. The intensity of changes in optimally immunosuppressed allografts was mild, and they were arrested early in the evolving stage of glomerular basement membrane changes. In the suboptimally immunosuppressed allografts with chronic rejection, the glomerular basement membrane changes became more pronounced and extensive in subsequent biopsies. Thus, all recipients in different groups showed similar glomerular alterations, but to different intensities. These results suggest a common pathogenetic mechanism which might be endothelial damage. In chronic rejection, the endothelial damage might be immunologically mediated by rejection episodes and progressive, whereas in syngeneic grafts and in allografts without chronic rejection, perioperative trauma, ischemia, and graft reperfusion may be responsible for the self-limiting glomerular changes. 相似文献