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In BCC crystals, such as Tungsten (W), slippage has been observed on the (1 1 0) and (1 1 2) planes. In this work, hydrogen diffusion paths from three different W surfaces ((1 0 0), (1 1 0) and (1 1 2)) have been calculated using first principles density functional theory. Equilibrium sites for H at the surfaces are identified. The energetics for H penetration from the surfaces to the solute site in the bulk is calculated. It is found that for our low surface coverage of H (3.4 × 1014 H/cm2), approximately 2 eV is required for an H atom to penetrate any of the W surfaces considered in this study. 相似文献
24.
Rathika G. Suba V. Lakshmi D. Shanthana Rani Roopala 《Journal of Inorganic and Organometallic Polymers and Materials》2022,32(8):3153-3169
Journal of Inorganic and Organometallic Polymers and Materials - In recent decades, the analysis of nanoparticles is of greater importance for their applications in various fields. This present... 相似文献
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Silicon - This paper presents the analytical approximation of device physics of heterojunction based double gate (DG) Tunnel field effect transistors (TFETs) in terms of potential distribution,... 相似文献
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Kiran Tiwari Rudramani Singh Vinai Kumar Singh Manoj Kumar Krishnamoorthi S. Kumar Krishna 《Iranian Polymer Journal》2020,29(7):615-623
Iranian Polymer Journal - In our recent work, we have reported on hydrogels devoid of cross-linkers. After observing the successful swelling and water retention properties, we have introduced... 相似文献
28.
Casein and soybean are superior quality proteins; however, these are known to inhibit mineral absorption. These investigations were aimed at enzymatic modification of these proteins and to study their effect on mineral bioaccessibility. Casein and soybean proteins were hydrolyzed with alcalase and trypsin individually under optimum conditions. The protein hydrolysates, prepared with different degrees of hydrolysis, were freeze dried, fortified with either iron or zinc and analyzed for bioaccessible minerals in vitro. Proteolytic hydrolysis enhanced the bioaccessibility of iron and zinc in proportion to the degree of hydrolysis. Tryptic hydrolysis enhanced the bioaccessible iron from 1–4% in casein and from 1.3–3.3% in soybean. Alcalase hydrolysis showed a comparatively higher enhancement with both the proteins. Tryptic hydrolysis enhanced zinc bioaccessibity by 3-fold in casein and alcalase hydrolysis enhanced by 2- to 2.5-fold. In soybean, dephytinization showed a synergistic effect. In conclusion, enzymatic hydrolysis of proteins looks promising for enhancing bioaccessibility of minerals in protein matrices. 相似文献
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Heavy metal accumulation in vegetables irrigated with water from different sources 总被引:12,自引:0,他引:12
Monu Arora Bala Kiran Shweta Rani Anchal Rani Barinder Kaur Neeraj Mittal 《Food chemistry》2008,111(4):811-815
The present study was carried out to assess levels of different heavy metals like iron, manganese, copper and zinc, in vegetables irrigated with water from different sources. The results indicated a substantial build-up of heavy metals in vegetables irrigated with wastewater. The range of various metals in wastewater-irrigated plants was 116–378, 12–69, 5.2–16.8 and 22–46 mg/kg for iron (Fe), manganese (Mn), copper (Cu) and zinc (Zn), respectively. The highest mean levels of Fe and Mn were detected in mint and spinach, whereas the levels of Cu and Zn were highest in carrot. The present study highlights that both adults and children consuming vegetables grown in wastewater-irrigated soils ingest significant amount of these metals. However, the values of these metals were below the recommended maximum tolerable levels proposed by the [Joint FAO/WHO Expert Committee on Food Additives (1999). Summary and conclusions. In 53rd Meeting, Rome, June 1–10, 1999]. However, the regular monitoring of levels of these metals from effluents and sewage, in vegetables and in other food materials is essential to prevent excessive build-up of these metals in the food chain. 相似文献
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Kiran K Suresh Kumar K Suvardhan K Janardhanam K Chiranjeevi P 《Journal of hazardous materials》2007,147(1-2):15-20
2-{[1-(2-Hydroxynaphthyl) methylidene] amino} benzoic acid (HNMABA) was synthesized for solid phase extraction (SPE) to the determination of Co, Cu, Ni, Zn and Cd in environmental and biological samples by flame atomic absorption spectrophotometry (FAAS). These metals were sorbed as HNMABA complexes on activated carbon (AC) at the pH range of 5.0+/-0.2 and eluted with 6 ml of 1M HNO3 in acetone. The effects of sample volume, eluent volume and recovery have been investigated to enhance the sensitivity and selectivity of proposed method. The effect of interferences on the sorption of metal ions was studied. The concentration of the metal ions detected after preconcentration was in agreement with the added amount. The detection limits for the metals studied were in the range of 0.75-3.82 microg ml(-1). The proposed system produced satisfactory results for the determination of Co, Cu, Ni, Zn and Cd metals in environmental and biological samples. 相似文献