全文获取类型
收费全文 | 113876篇 |
免费 | 19317篇 |
国内免费 | 4090篇 |
专业分类
电工技术 | 5079篇 |
技术理论 | 1篇 |
综合类 | 4960篇 |
化学工业 | 29023篇 |
金属工艺 | 4852篇 |
机械仪表 | 5793篇 |
建筑科学 | 6449篇 |
矿业工程 | 1911篇 |
能源动力 | 2987篇 |
轻工业 | 14191篇 |
水利工程 | 1745篇 |
石油天然气 | 3008篇 |
武器工业 | 577篇 |
无线电 | 15582篇 |
一般工业技术 | 20771篇 |
冶金工业 | 4231篇 |
原子能技术 | 841篇 |
自动化技术 | 15282篇 |
出版年
2024年 | 392篇 |
2023年 | 1352篇 |
2022年 | 2479篇 |
2021年 | 3567篇 |
2020年 | 3792篇 |
2019年 | 5020篇 |
2018年 | 5340篇 |
2017年 | 5732篇 |
2016年 | 6144篇 |
2015年 | 6903篇 |
2014年 | 7626篇 |
2013年 | 9705篇 |
2012年 | 8118篇 |
2011年 | 8564篇 |
2010年 | 7997篇 |
2009年 | 7748篇 |
2008年 | 6997篇 |
2007年 | 6435篇 |
2006年 | 5832篇 |
2005年 | 4844篇 |
2004年 | 3916篇 |
2003年 | 3421篇 |
2002年 | 3219篇 |
2001年 | 2742篇 |
2000年 | 2440篇 |
1999年 | 1635篇 |
1998年 | 1083篇 |
1997年 | 821篇 |
1996年 | 699篇 |
1995年 | 520篇 |
1994年 | 457篇 |
1993年 | 340篇 |
1992年 | 261篇 |
1991年 | 199篇 |
1990年 | 163篇 |
1989年 | 139篇 |
1988年 | 98篇 |
1987年 | 83篇 |
1986年 | 80篇 |
1985年 | 44篇 |
1984年 | 39篇 |
1983年 | 34篇 |
1982年 | 29篇 |
1981年 | 24篇 |
1980年 | 25篇 |
1979年 | 22篇 |
1978年 | 19篇 |
1977年 | 24篇 |
1976年 | 32篇 |
1975年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
941.
The melt polycondensation reaction of N‐protected trans‐4‐hydroxy‐L ‐proline (N‐Z‐Hpr) and ?‐caprolactone (?‐CL) over a wide range of molar fractions in the feed produced new and degradable poly(N‐Z‐Hpr‐co‐?‐CL)s with stannous octoate as a catalyst. The optimal reaction conditions for the synthesis of the copolymers were obtained with 1.5 wt % stannous octoate at 140°C for 24 h. The synthesized copolymers were characterized by IR spectrophotometry, 1H NMR, differential scanning calorimetry, and Ubbelohde viscometry. The values of the inherent viscosity (ηinh) and glass‐transition temperature (Tg) of the copolymers depended on the molar fractions of N‐Z‐Hpr. With an increase in the trans‐4‐hydroxy‐N‐benzyloxycarbonyl‐L ‐proline (N‐CBz‐Hpr) feed from 10 to 90 mol %, a decrease in ηinh from 2.47 to 1.05 dL/g, and an increase in Tg from ?48 to 49°C were observed. The in vitro degradation of these poly(N‐CBz‐Hpr‐co‐?‐CL)s was evaluated from weight‐loss measurements. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 3176–3182, 2003 相似文献
942.
Fluidized bed combustion of high ash anthracite (HAA) was experimentally studied. The combustor consists of 0.25 m ID bed,
and auxiliary equipments for coal feeding, ash removal, lemperature control, etc. Experimental results elucidate main cause
of fuel loss to be elutriation of fines (i.e., flyash) containing unburned carbon. However, detailed balances of particle
size distribution show majority of carbon in flyash comes from fines contained in the feed instead of attrition of coarse
particles. The latter is the main source of flyash for conventional coal. The difference is due to much smaller attrition
rate of HAA; feed HAA particles do not shrink much in size by combustion and attrition. 相似文献
943.
An organic‐solvent‐soluble disperse dye was introduced into an aqueous phase by a reaction with a self‐emulsified, aqueous‐based polyurethane (PU), and this resulted in the formation of a homogeneous, aqueous polymeric dye dispersion. This aqueous polymeric dye was stable in a water phase with excellent color extension upon application. It was formulated with a latent curing agent, polyaziridine (e.g., TMPTA‐AZ), as a single‐component, self‐curable, aqueous polymeric dye. The curing reaction took place between PU carboxylic acid and the latent curing agent upon drying. A self‐cured polymeric dye was obtained with excellent color extension and fastness and resistance to organic solvents and water after drying. This single‐component, self‐curable, aqueous‐based PU system containing a dye has potential for printing, writing, and dyeing applications. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 2006 © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3741–3747, 2006 相似文献
944.
Hyun Min Shim Joon Soo Lee Hong Yue Wang Seung Hak Choi Jeong Hoon Kim Hyung Taek Kim 《Korean Journal of Chemical Engineering》2007,24(3):537-541
The main purpose of the study was to develop a model using ASPEN and Excel simulation method to establish optimum CO2 separation process utilizing hollow fiber membrane modules to treat exhaust gas from LNG combustion. During the simulation,
optimum conditions of each CO2 separation scenario were determined while operating parameters of CO2 separation process were varied. The characteristics of hollow fibers membrane were assigned as 60 GPU of permeability and
25 of selectivity for the simulation. The simulation results illustrated that 4 stage connection of membrane module is required
in order to achieve over 99% of CO2 purity and 90% of recovery rate. The resulted optimum design and operation parameters throughout the simulation were also
correlated with the experimental data from the actual CO2 separation facility which has a capacity of 1,000 Nm3/day located in the Korea Research Institute of Chemical Technology. Throughout the simulation, the operating parameters of
minimum energy consumption were evaluated. Economic analysis of pilot scale of CO2 separation plant was done with the comparison of energy cost of CO2 recovery and equipment cost of the plant based on the simulation model.
This work was presented at the 6
th
Korea-China Workshop on Clean Energy Technology held at Busan, Korea, July 4–7, 2006. 相似文献
945.
Yong Min Lee 《Electrochimica acta》2006,52(4):1582-1587
Highly ion-conductive solid polymer electrolyte (SPE) based on polyethylene (PE) non-woven matrix is prepared by filling poly(ethylene glycol) (PEG)-based crosslinked electrolyte inside the pores of the non-woven matrix. The PE non-woven matrix not only shows good mechanical strength for SPE to be a free-standing film, but also has very porous structure for high ion conductivity. The ion conductivity of SPE based on PE non-woven matrix can be enhanced by adding sufficient non-volatile plasticizer such as poly(ethylene glycol) dimethyl ether (PEGDME) into ion conduction phase without sacrificing mechanical strength. SPE with 20 wt.% crosslinking agent and 80 wt.% non-volatile plasticizer shows 3.1 × 10−4 S cm−1 at room temperature (20 °C), to our knowledge, which is the highest level for SPEs. It is also electrochemically stable up to 5.2 V and has high transference number about 0.52 due to the introduction of anion receptor as an additive. The interfacial resistance between Li electrode and SPE is low enough to perform charge/discharge test of unit cell consisting of LiCoO2/SPE/Li at room temperature. The discharge capacity of the unit cell shows 87% of theoretical value with 86% Coulombic efficiency. 相似文献
946.
Xiao Tang Min Gao Haosu Luo Jiefang Li Dwight D. Viehland 《Journal of the American Ceramic Society》2020,103(6):3726-3731
Epitaxial CoFe2O4 (CFO) and SrRuO3 (SRO) nanopillar heterostructures were deposited on Pb(Mg1/3Nb2/3)0.70Ti0.30O3 (PMN-30PT) single crystal substrates by switch pulsed laser deposition (SPLD). Since the CFO nanopillars are insulating, and the SRO matrix conductive, this self-assembled nanopillar heterostructure served as a patterned electrode on PMN-PT, which then enhances the dielectric and piezoelectric constant of the substrate. Cross-sectional electron microscopy images revealed the formation of a nanopillar heterostructure layer with CFO nanopillars within a SRO matrix. AFM and XRD revealed good topography and epitaxy, indicating a high quality SRO-CFO self-assembled nanopillar structure. Using a SRO-CFO thin film patterned electrode, PMN-PT was found to have a notably higher (30%) dielectric constant with increasing electric field and enhanced transverse broadening in reciprocal spacing mapping (RSM) scans. 相似文献
947.
Ayman M. Atta Manar E. Abdel‐Raouf Shimaa M. Elsaeed Abdel‐Azim A. Abdel‐Azim 《应用聚合物科学杂志》2007,103(5):3175-3182
Unsaturated polyester resin (UP) was prepared from glycolyzed oligomer of poly(ethylene terephthalate) (PET) waste based on diethylene glycol (DEG). New diacrylate and dimethacrylate vinyl ester resins prepared from glycolysis of PET with tetraethylene glycol were blended with UP to study the mechanical characteristics of the cured UP. The vinyl ester resins were used as crosslinking agents for unsaturated polyester resin diluted with styrene, using free‐radical initiator and accelerator. The mechanical properties of the cured UP resins were evaluated. The compressive properties of the cured UP/styrene resins in the presence of different vinyl ester concentrations were evaluated. Increasing the vinyl ester content led to a pronounced improvement in the compression strength. The chemical resistances of the cured resins were evaluated through hot water, solvents, acid, and alkali resistance measurements. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3175–3182, 2007 相似文献
948.
Polymer blends of poly(propylene) (PP) and polyacetal (polyoxymethylene, POM) with ethylene vinyl alcohol (EVOH) copolymers were investigated by differential scanning calorimetry (DSC), rheological, tensile, and impact measurements, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The PP–POM–EVOH blends were extruded with a co‐rotating twin‐screw extruder. The ethylene group in the EVOH is partially miscible with PP, whereas the hydroxyl group in the EVOH can form hydrogen bonding with POM. The EVOH tends to reside along the interface, acting as a surfactant to reduce the interfacial tension and to increase the interfacial adhesion between the blends. Results from SEM and mechanical tests indicate that a small quantity of the EVOH copolymer or a smaller vinyl alcohol content in the EVOH copolymer results in a better compatibilized blend in terms of finer phase domains and better mechanical properties. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1471–1477, 2003 相似文献
949.
A series of nanocomposite hydrogels were prepared from various ratios of N‐isopropylacrylamide (NIPAAm) and organic montmorillonite (MMT). The influence of the extent of MMT in the NIPAAm/MMT nanocomposite hydrogels on the physical properties and drug‐release behavior was the main purpose of this study. The microstructure and morphology were identified by X‐ray diffraction (XRD) and scanning electronic microscopy (SEM). The results showed that the swelling ratios for these nanocomposite hydrogels decreased with increase in the content of MMT. The gel strength and Young's modulus of the gels also increased with increase in the content of MMT. XRD results indicated that the exfoliation of MMT was achieved in the swollen state. Finally, the drug‐release behavior for the gels was also assessed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3652–3660, 2003 相似文献
950.
Min Luo Ji-Qiang Gao Jian-Feng Yang Jun-Zhuo Fang Zheng Wang 《Journal of the American Ceramic Society》2007,90(12):4036-4039
Biomorphic silicon nitride (Si3 N4 ) ceramics with fibrous morphology were fabricated by combining sol–gel infiltration with carbothermal reduction nitridation from wood precursor. Y2 O3 -incorporated silica sol was used as the infiltrated solution to promote the formation of fibrous Si3 N4 grain at 1600°C under high nitrogen pressure (0.6 MPa). The influence of sintering conditions (additive and temperature) on the phase composition and microstructure of sintering bodies was analyzed, and the reaction mechanism is discussed. 相似文献