Kinetics, acid sites and deactivation of H-mordenite during the SCR of NOx with CH4

H-mordenites are active for the SCR reaction but they suffer irreversible partial deactivation after being on stream for one hour at 650°C. The reaction orders and activation energies are not significantly affected by deactivation. This indicates that deactivation originates in a decrease in the number of active sites due to dealumination and possible pore blockage. The NO disappearance rate correlates with TPD NH₃ between 300 and 700°C; FTIR confirms these results. ¹²⁹Xe NMR of adsorbed xenon shows that pore blockage occurs and is due to the presence of aluminum species in the main zeolite channels. The overall deactivation process and the role of acid sites is discussed in terms of the current literature. This revised version was published online in July 2006 with corrections to the Cover Date.     

Correction to Lombardo and Foschi (2003).

Reports an error in the original article by G. P. Lombardo and R. Foschi (History of Psychology, 2003, 2, 123-142). In the reference list, several works by Pierre Janet were identified as being Paul Janet. The correct references are provided, where Paul Janet is identified by the initial P. and Pierre Janet is identified by the initials P. M. F.. (The following abstract of this article originally appeared in record 2003-03729-003.) Since the 1920s, the road to the acknowledgment of personality psychology as a field of scientific psychology that has individuality as its object began with the founding of the discipline by Gordon W. Allport. Historians of psychology have made serious attempts to reconstruct the cultural, political, institutional, and chronological beginnings of this field in America in the 20th century. In this literature, however, an important European tradition of psychological studies of personality that developed in France in the 2nd half of the 19th century has been overlooked. The aim of this article is to cast some light on this unexplored tradition of psychological personality studies and to discuss its influence on the development of the scientific study of personality in the United States. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Molecular Epidemiology of Mitochondrial Cardiomyopathy: A Search Among Mitochondrial and Nuclear Genes

Mitochondrial Cardiomyopathy (MCM) is a common manifestation of multi-organ Mitochondrial Diseases (MDs), occasionally present in non-syndromic cases. Diagnosis of MCM is complex because of wide clinical and genetic heterogeneity and requires medical, laboratory, and neuroimaging investigations. Currently, the molecular screening for MCM is fundamental part of MDs management and allows achieving the definitive diagnosis. In this article, we review the current genetic knowledge associated with MDs, focusing on diagnosis of MCM and MDs showing cardiac involvement. We searched for publications on mitochondrial and nuclear genes involved in MCM, mainly focusing on genetic screening based on targeted gene panels for the molecular diagnosis of the MCM, by using Next Generation Sequencing. Here we report twelve case reports, four case-control studies, eleven retrospective studies, and two prospective studies, for a total of twenty-nine papers concerning the evaluation of cardiac manifestations in mitochondrial diseases. From the analysis of published causal mutations, we identified 130 genes to be associated with mitochondrial heart diseases. A large proportion of these genes (34.3%) encode for key proteins involved in the oxidative phosphorylation system (OXPHOS), either as directly OXPHOS subunits (22.8%), and as OXPHOS assembly factors (11.5%). Mutations in several mitochondrial tRNA genes have been also reported in multi-organ or isolated MCM (15.3%). This review highlights the main disease-genes, identified by extensive genetic analysis, which could be included as target genes in next generation panels for the molecular diagnosis of patients with clinical suspect of mitochondrial cardiomyopathies.     

Peculiar aspects of nanocrystal memory cells: data and extrapolations

Nanocrystal memory cell are a promising candidate for the scaling of nonvolatile memories in which the conventional floating gate is replaced by an array of nanocrystals. The aim of this paper is to present the results of a thorough investigation of the possibilities and the limitations of such new memory cell. In particular, we focus on devices characterized by a very thin tunnel oxide layer and by silicon nanocrystals formed by chemical vapor deposition. The direct tunneling of the electrons through the tunnel oxide, their storage into the silicon nanocrystals, and furthermore, retention, endurance, and drain turn-on effects, well-known issues for nonvolatile memories, are all investigated. The cell can be also programmed by channel hot electron injection, allowing the possibility to multibit storage. The suppression of the drain turn-on and the possibility of using this cell for multibit storage give us a clear evidence of the distributed nature of the charge storage.     

Teacher ratings of attention deficit hyperactivity disorder symptoms: Factor structure and normative data.

Behavior rating scales are a primary method for screening and identifying children with attention deficit hyperactivity disorder (ADHD). The factorial structure and normative data of a teacher rating scale containing the 18 symptoms of ADHD were examined in this study. Factor analyses and assessment of differences in ADHD ratings across sex, age, and ethnic group were conducted with 4,009 children and adolescents who attended kindergarten through 12th grade in 31 U.S. school districts. Two factors (inattention and hyperactivity-impulsivity) were derived, and normative data for a nationally representative sample were presented. Boys, younger children, and African Americans received higher ratings of ADHD symptoms. Limitations of this investigation and potential uses of this scale in clinical practice and research are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The effect of preparation methods and activation strategies upon the catalytic behavior of the vanadium-phosphorus oxides

The Catalyst precursors for the oxidation of n-butane to maleic anhydride were prepared using vanadium pentoxide and orthophosphoric acid. The former was reduced using different agents (HC1 and benzyl alcohol) and solvents (water, isobutyl and Isopropyl alcohols). The precursors were activated applying different strategies which were selected and adapted from the literature. The changes occurring in the solid were followed using XRD, XPS and ³¹P MAS NMR techniques. The Catalytic performance was evaluated using a flow reactor system. The equilibrated Catalysts obtained after 100–400 hours on stream contained vanadyl pyrophosphate as the only crystalline phase (XRD). The XPS data showed significant phosphorus surface enrichment and the existence of only V(iv) on the surface. The solvent used and the activation strategy strongly influenced the Catalytic performance which could be traced through ³¹P NMR to the presence of small amounts of V(v) containing phases. The results are discussed in terms of the current literature.     

Exploring the Substrate Specificity and Enantioselectivity of a Baeyer–Villiger Monooxygenase from Dietzia sp. D5: Oxidation of Sulfides and Aldehydes

Baeyer–Villiger monooxygenases (BVMOs) are valuable enzymes for specific oxyfunctionalization chemistry. They catalyze the oxidation of ketones to esters, but are also capable of oxidizing other chemical functions, namely aldehydes and heteroatoms such as sulfur, nitrogen, selenium and boron. The oxidation specificity and enantioselectivity of a newly characterized BVMO (BVMO4) from a strain of Dietzia towards sulfide- and aldehyde substrates have been studied. BVMO4 could react with sulfides containing an aromatic group. The presence of a substituent on the aromatic group was tolerated when they were in the meta- and para position and the oxidations yielded predominantly the (R)-sulfoxides. Similarly, BVMO4 displayed a higher activity for aldehydes containing a phenyl group, but long aliphatic aldehydes, namely octanal and decanal, were also accepted as substrate by this enzyme. The major oxidation products of the aldehyde substrates were the respective carboxylic acids in contrast to formate ester that was obtained in most of the previous reports. The Baeyer–Villiger oxidation of the substrate 2-phenylpropionaldehyde was studied in further detail and the corresponding acid product was obtained with good regio- and enantioselectivity. This is a unique feature for BVMO4 and is of great interest for further exploration of an alternative biocatalytic process.     

The role of calcium in blended fly ash geopolymers

In this research effort, the role of calcium in geopolymers was investigated through a series of syntheses where a high-calcium fly ash was blended with a low-calcium fly ash. Increased calcium content led to accelerated set-up times, increased compressive strength, and increased product formation. Powder X-ray diffraction results showed the majority of that product to be geopolymer framework with only minor contributions from calcium silicate phases. Thermal analysis confirmed the absence of a calcium silicate hydrate phase. Analysis of fly ash dissolution showed that calcium aided in aluminosilicate dissolution and therefore the geopolymerization reaction. While aiding in this reaction, calcium became incorporated into the pore structure of the geopolymer as a counter-balancing cation, according to ion exchange experiments. Thus, geopolymer synthesis with increased calcium content through the use of a high-calcium fly ash under these experimental conditions produced a quick-setting, strong, calcium incorporated geopolymer material.