Structure,texture and surface acidity studies of a series of mixed zinc–aluminum (60–90 molar % Al) phosphate catalysts

A series of mixed zinc–aluminum phosphate (ZnAlP) catalysts containing 40–90 aluminum molar % were synthesized by a coprecipitation method and characterized by nitrogen adsorption–desorption, X‐ray diffraction, FTIR spectroscopy, thermogravimetric analysis (TGA), differential thermal analysis (DTA), diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and temperature programmed desorption (TPD) of ammonia. The presence of aluminum greatly affected the surface properties of Zn₃(PO₄)₂ by delaying the crystallization process of Zn₃(PO₄)₂. All amorphous samples were shown to be mesoporous and they contained two types of aluminum surface hydroxyl groups and one type of phosphorus hydroxyl group, as shown by DRIFT spectra. The specific surface area and the acidity of ZnAlP increased on increasing the aluminum content. On the other hand, a great difference in the texture and the concentration of surface acid sites was found by changing the precipitating agent and calcination temperature. Thus these factors also play an important role in the final properties of these catalysts. © 2001 Society of Chemical Industry     

Intelligent Human-Machine Interaction Based on Dynamic Bayesian Networks Probabilistic Intention Recognition

In this article, a novel human–machine interaction based on the machine intention recognition of the human is presented. This work is motivated by the desire that intelligent machines as robots imitate human–human interaction, that is to minimize the need for classical direct human–machine interface and communication. A philosophical and technical background for intention recognition is discussed. Here, the intention–action–state scenario is modified and modeled by Dynamic Bayesian Networks to facilitate for probabilistic intention inference. The recognized intention, then, drives the interactive behavior of the machine such that it complies with the human intention in light of the real state of the world. An illustrative example of a human commanding a mobile robot remotely is given and discussed in details.     

Analysis of a dephased complex-coupled distributed-feedback laser by the power-series method

A novel power-series method to solve the coupled-wave equations is introduced. The method is used to calculate the threshold gain margins of a complex-coupled distributed-feedback laser as functions of the ratio of gain coupling to index coupling (|kappa(g)|/|kappa(n)|) and of the phase difference between the index and the gain gratings. For coupling coefficient |kappa|l < ., the laser shows a mode degeneracy at specific values of the ratio |kappa(g)|/|kappa(n)| for cleaved facets. At phase differences pi/2 and 3pi/2 between the gain and the index gratings, an antireflection-coated complex-coupled laser becomes multimode, and a different mode starts to lase. The effect of facet reflectivity (both magnitude and phase) on the gain margin of a complex-coupled DFB laser is also investigated. Although the gain margin varies slowly with the magnitude of the facet's reflectivity, it shows large variations as a function of the phase. Spatial hole burning was found to be minimum at phase difference npi, n =, ..., and maximum at phase differences pi/2 and 3pi/2.     

Threshold analysis of a chirped-grating distributed-feedback laser with the power series method

A new and efficient method for analyzing a chirped-grating distributed-feedback (DFB) laser is presented. We show that coupled-wave equations can be solved by use of the power series method. The single-mode gain margin of a linearly chirped-grating DFB laser is calculated for different chirping factors and coupling constants. We found that clearly optimum chirping exists for which the single-mode gain margin is maximum. The gain margins were also calculated for different positions of the cavity center. The effect of facet reflectivities and their phases on the gain margin was investigated. We found that the gain margin is maximum and the spatial hole burning is minimum for the cavity center at the middle of the laser cavity.     

Phase I/II study of the toxicity, pharmacokinetics, and activity of the HIV protease inhibitor SC-52151

A significant restriction was demonstrated in the ability of herpes simplex virus type 1 virion host shutoff (vhs) mutant viruses to invade the corneal epithelium. Viral replication and invasion was confined to the areas of the cornea which were scarified prior to infection. Differences between wild-type and vhs mutant replication in corneas in vivo were 100- to 1000-fold at all timepoints postinfection. Smaller but still significant growth restrictions were observed in cultured corneal cells. This difference between in vitro and in vivo is not likely to be due to differences in cell cycle status since vhs-induced RNA degradation can occur in both cycling and noncycling cells in vitro. The vhs function is therefore important for invasion of the cornea and secondarily the nervous system and is thereby required for efficient establishment of latency.     

Thermodynamic interpretation of solute–polymer interactions at infinite dilution

Heats of solution at infinite dilution of solutes in poly(ethyl methacrylate) were estimated using gas–liquid chromatography over a temperature range of 417.74 K–427.55 K. The heat of solution is related to solute polarizability and dipole moment. Contributions of specific interactions such as hydrogen bonding and charge-transfer complexing to the enthalpy of solution were also determined.     

Laminar-flow non-newtonian heat transfer in flattened tubes

It is shown experimentally that flattened tubes give higher laminar-flow heat transfer coefficients than tubes of circular cross-section. Part of the increase is due to an increase in the tube-wall shear rate; the magnitude of this effect is predicted and checked by reference to the behaviour of Newtonian liquids. The other part is due to secondary flow patterns which develop in viscoelastic liquids; this effect is at a maximum when the aspect ratio of the tube cross-section is of the order 1.5:1. The first effect may increase heat transfer coefficient by over 90% and the latter by over 45%.     

Marital status and schizophrenia: A study of incidence and outcome.

Investigated the relationships between marital status and the incidence and prognosis of schizophrenia, based on a considerably more representative sample (N = 213) than previously available. Results provide strong evidence that the rate differentials and differences in outcome so often observed for marital status categories do not derive from inadequate or inappropriate sampling or statistical manipulation. In additional analyses, controlling for differential social class and severity of pathology, however, the relationships with prognosis could no longer be observed. These latter findings suggest that a process of selection by marriage is the more tenable interpretation of the relationships under consideration. (15 ref.) (PsycINFO Database Record (c) 2010 APA, all rights reserved)