Web‐Like Interconnected Carbon Networks from NaCl‐Assisted Pyrolysis of ZIF‐8 for Highly Efficient Oxygen Reduction Catalysis

The oxygen reduction reaction (ORR) is under intense research due to its significance in energy storage and conversion processes. Recent studies show that interconnected and hierarchically porous structures can further enhance ORR kinetics as well as catalyst durability, but their preparation can be quite time and/or chemical consuming. Here, a simple approach is reported to prepare such complex structures by pyrolyzing composites containing NaCl and ZIF‐8. The templating effect of molten NaCl connects ZIF‐8 particles into web‐like carbon networks. During ORR activity measurements, it achieves a 0.964 V onset potential and a 38 mV dec^?1 Tafel slope, which are comparable to those of the benchmark Pt/C (0.979 V and 40 mV dec^?1). Due to the metal‐free feature, this catalyst exhibits a 16 mV shift in half‐wave potential after a 10 000‐cycle durability test, which is only 60% of that of Pt/C. The catalyst is also tested in Zn–air batteries and the assemblies are able to work at above 1.2 V for 140 h, which triples the life held by those with Pt/C. This study demonstrates a facile strategy to prepare metal‐free ORR catalysts with interconnectivity and hierarchical porosity, and proves their great potentials in ORR catalysis and Zn–air batteries.     

Vacuum metrology and its impact on research and industry

To mark our anniversary, we are presenting articles that have been particularly appreciated by readers of our online edition once again in print. Here: By accurate vacuum measurement, it is possible to control processes in industry, to ensure the necessary environmental conditions for many experiments in science and research and to support the commercial relationship between manufacturers and users of vacuum equipment. The main task of vacuum metrology, the science of vacuum measurement, is to provide traceability of vacuum measurements to the SI. In recent years, also the characterization of vacuum by partial pressure analysis and outgassing rate measurement, and the dynamics of vacuum measurement became an issue for vacuum metrology.     

A wavelet-based method for multiscale tomographic reconstruction

The authors represent the standard ramp filter operator of the filtered-back-projection (FBP) reconstruction in different bases composed of Haar and Daubechies compactly supported wavelets. The resulting multiscale representation of the ramp-filter matrix operator is approximately diagonal. The accuracy of this diagonal approximation becomes better as wavelets with larger numbers of vanishing moments are used. This wavelet-based representation enables the authors to formulate a multiscale tomographic reconstruction technique in which the object is reconstructed at multiple scales or resolutions. A complete reconstruction is obtained by combining the reconstructions at different scales. The authors' multiscale reconstruction technique has the same computational complexity as the FBP reconstruction method. It differs from other multiscale reconstruction techniques in that (1) the object is defined through a one-dimensional multiscale transformation of the projection domain, and (2) the authors explicitly account for noise in the projection data by calculating maximum a posteriori probability (MAP) multiscale reconstruction estimates based on a chosen fractal prior on the multiscale object coefficients. The computational complexity of this maximum a posteriori probability (MAP) solution is also the same as that of the FBP reconstruction. This result is in contrast to commonly used methods of statistical regularization, which result in computationally intensive optimization algorithms.     

Integrating intelligent job-scheduling into a real-world production-scheduling system

The paper addresses the problem of scheduling production orders (jobs). First, an approach based on simulated annealing and Hopfield nets is described. Since performance was unsatisfactory for real-world applications, we changed the problem representation and tuned the scheduling method, dropping features of the Hopfield net and retaining simulated annealing. Both computing time and solution quality were significantly improved. The scheduling method was then integrated into a software system for short-term production planning and control (electronic leitstand). The paper describes how real-world requirements are met, and how the scheduling method interacts with the leitstand's database and graphical representation of schedules.     

Constrained Analytical Trajectory Filter for stabilizing humanoid robot motions

Mimicking human motion with a humanoid robot is essential for allowing humanoid robots to be used in service applications. Simply creating motions without considerations for balance and stability or directly copying motion from a human using motion capture and implementing it on a humanoid robot may not be successful because of the difference in physical properties between the human and the humanoid robot, which may cause instability and make it fall. Using the Zero Moment Point as the stability criteria, this work proposes a Constrained Analytical Trajectory Filter as part of an Analytical Motion Filter, which stabilizes a reference motion that can come from human motion capture data, kinematic synthesis, or animation software. The resulting solutions used in the Constrained Analytical Trajectory Filter provide insight into the complex interactions of motion and stability. The solutions were verified in simulation and with hardware, showing that the analytical filter can be successfully applied for stabilizing reference motions for humanoid robots which may be unstable otherwise.     

Stability analysis for multi-agent systems using the incidence matrix: Quantized communication and formation control

The spectral properties of the incidence matrix of the communication graph are exploited to provide solutions to two multi-agent control problems. In particular, we consider the problem of state agreement with quantized communication and the problem of distance-based formation control. In both cases, stabilizing control laws are provided when the communication graph is a tree. It is shown how the relation between tree graphs and the null space of the corresponding incidence matrix encode fundamental properties for these two multi-agent control problems.     

Heuristics for the multi-period orienteering problem with multiple time windows

We present the multi-period orienteering problem with multiple time windows (MuPOPTW), a new routing problem combining objective and constraints of the orienteering problem (OP) and team orienteering problem (TOP), constraints from standard vehicle routing problems, and original constraints from a real-world application. The problem itself comes from a real industrial case. Specific route duration constraints result in a route feasibility subproblem. We propose an exact algorithm for this subproblem, and we embed it in a variable neighborhood search method to solve the whole routing problem. We then provide experimental results for this method. We compare them to a commercial solver. We also adapt our method to standard benchmark OP and TOP instances, and provide comparative tables with state-of-the-art algorithms.