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Karl Speer Peter Horstmann Elke Steeg Thomas Kühn und Alfred Montag 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1990,191(6):442-448
Zusammenfassung Die Bestimmung der ubiquitär verbreiteten Polycyclen bereitet oftmals in Gemüseproben Schwierigkeiten. Vorgestellt werden daher Verfahren, mit denen man eine Abtrennung der störenden Stoffe wie etherische Öle, Wachse, Carotinoide und Chlorophylle erreicht. Als besonders geeignet erweist sich dabei die Reinigung der Probenextrakte an Bio Beads S-X3 und mittels der halbpräparativen HPLC an Kieselgel Si60. Die Polycyclen werden durch CGC/MS bestimmt. Hierdurch ist es möglich, neben den zu bestimmenden Analyten auch die zugesetzten deuterierten Standardverbindungen störungsfrei zu erfassen. Die Resultate 32 verschiedener Gemüseproben werden diskutiert. Höhere Gehalte findet man in Grünkohl- und Petersilienproben.
PAH analysis in vegetable samples
Summary PAH analyses in vegetables are often difficult to carry out; therefore two different clean-up methods, which allow elimination of interfering matrix components such as essential oils, waxes, carotinoids and chlorophylls were developed. Clean-up of 32 different vegetables samples consisted of either Bio-Beads S-X3 chromatography or semi-preparative HPLC on silica gel Si-60. PAH were determined by capillary GC-MS, which allowed the application of deuterium-labelled internal standards. The results are presented; higher PAH contamination was detected in cale and parsley.相似文献
24.
Yong Hyun Kim Christoph Sachse Michael L. Machala Christian May Lars Müller‐Meskamp Karl Leo 《Advanced functional materials》2011,21(6):1009-1009
Highly conductive poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) films as stand‐alone electrodes for organic solar cells have been optimized using a solvent post‐treatment method. The treated PEDOT:PSS films show enhanced conductivities up to 1418 S cm?1, accompanied by structural and chemical changes. The effect of the solvent treatment on PEDOT:PSS has been investigated in detail and is shown to cause a reduction of insulating PSS in the conductive polymer layer. Using these optimized electrodes, ITO‐free, small molecule organic solar cells with a zinc phthalocyanine (ZnPc):fullerene C60 bulk heterojunction have been produced on glass and PET substrates. The system was further improved by pre‐heating the PEDOT:PSS electrodes, which enhanced the power conversion efficiency to the values obtained for solar cells on ITO electrodes. The results show that optimized PEDOT:PSS with solvent and thermal post‐treatment can be a very promising electrode material for highly efficient flexible ITO‐free organic solar cells. 相似文献
25.
A wavelet-based method for multiscale tomographic reconstruction 总被引:4,自引:0,他引:4
The authors represent the standard ramp filter operator of the filtered-back-projection (FBP) reconstruction in different bases composed of Haar and Daubechies compactly supported wavelets. The resulting multiscale representation of the ramp-filter matrix operator is approximately diagonal. The accuracy of this diagonal approximation becomes better as wavelets with larger numbers of vanishing moments are used. This wavelet-based representation enables the authors to formulate a multiscale tomographic reconstruction technique in which the object is reconstructed at multiple scales or resolutions. A complete reconstruction is obtained by combining the reconstructions at different scales. The authors' multiscale reconstruction technique has the same computational complexity as the FBP reconstruction method. It differs from other multiscale reconstruction techniques in that (1) the object is defined through a one-dimensional multiscale transformation of the projection domain, and (2) the authors explicitly account for noise in the projection data by calculating maximum a posteriori probability (MAP) multiscale reconstruction estimates based on a chosen fractal prior on the multiscale object coefficients. The computational complexity of this maximum a posteriori probability (MAP) solution is also the same as that of the FBP reconstruction. This result is in contrast to commonly used methods of statistical regularization, which result in computationally intensive optimization algorithms. 相似文献
26.
Non-linear autoregressive Markov regime-switching models are intuitive. Time-series approaches for the modelling of electricity spot prices are frequently proposed. In this paper, such models are compared with an ordinary linear autoregressive model with regard to their forecast performances. The study is carried out using German daily spot-prices from the European Energy Exchange in Leipzig. Four non-linear models are used for the forecast study. The results of the study suggest that Markov regime-switching models provide better forecasts than linear models. 相似文献
27.
Zhi Chen Karl Hess Jinju Lee Lyding J.W. Rosenbaum E. Kizilyalli I. Chetlur S. Huang R. 《Electron Device Letters, IEEE》2000,21(1):24-26
The classical concept and theory suggest that the degradation of MOS transistors is caused by interface trap generation resulting from “hot carrier injection.” We report three new experiments that use the deuterium isotope effect to probe the mechanism for interface trap generation in n-MOS transistors in the presence of hot hole and electron injection. These experiments show clearly that hot carrier injection into the gate oxide exhibits essentially no isotope effect, whereas channel hot electrons at the interface exhibit a large isotope effect. This leads to the conclusion that channel hot electrons, not carriers injected into the gate oxide, are primarily responsible for interface trap generation for standard hot carrier stressing 相似文献
28.
Joshua D. Caldwell Kendrick X. Liu Marko J. Tadjer Orest J. Glembocki Robert E. Stahlbush Karl D. Hobart Fritz Kub 《Journal of Electronic Materials》2007,36(4):318-323
Stacking faults within 4H-SiC PiN diodes are known to be detrimental to device operation. Here, we present electroluminescence
(EL) images of 4H-SiC PiN diodes providing evidence that electrically and optically stimulated Shockley stacking fault (SSF)
propagation is a reversible process at temperatures as low as 210°C. Optical beam induced current (OBIC) images taken following
complete optical stressing of a PiN diode and that lead to a small number of completely propagated SSFs provide evidence that
such defects propagate across the n–/p+ interface and continue to grow throughout the p+ layer. These observations bring about
questions regarding the validity of the currently accepted driving force mechanism for SSF propagation. 相似文献
29.
当今,从事OC-48、OC-192技术的设计师在设计基于因特网协议(IP协议)的下一代系统时,因系统含有诸如ASIC、网络处理器(NP)、高速跟踪器等元件,以及分组SONET物理层(PoS-PHY)接口规范等的演变,而一直面临挑战。抖动和扭斜失真等现象的存在给诸如系统分组接口第4层(SPI-4)和通用交换接口(CSIX)等总线结构本已拥挤的时序容限,以及四元数据率静态RAM传送表访问时间带来极大混乱。再加上诸如低压差分信号(LVDS)、高速收发逻辑和短线串行终端逻辑等超低电压峰-峰信号技术的引入,使数据出错的可能性变得异常之高。而利用仿真技… 相似文献
30.
Sorantin E Halmai C Erdöhelyi B Palágyi K Nyúl LG Ollé K Geiger B Lindbichler F Friedrich G Kiesler K 《IEEE transactions on medical imaging》2002,21(3):263-273
PURPOSE: Demonstration of a technique for three-dimensional (3-D) assessment of tracheal-stenoses, regarding site, length and degree, based on spiral computed tomography (S-CT). PATIENTS AND METHODS: S-CT scanning and automated segmentation of the laryngo-tracheal tract (LTT) was followed by the extraction of the LTT medial axis using a skeletonization algorithm. Orthogonal to the medial axis the LTT 3-D cross-sectional profile was computed and presented as line charts, where degree and length was obtained. Values for both parameters were compared between 36 patients and 18 normal controls separately. Accuracy and precision was derived from 17 phantom studies. RESULTS: Average degree and length of tracheal stenoses was found to be 60.5% and 4.32 cm in patients compared with minor caliber changes of 8.8% and 2.31 cm in normal controls (p < 0.0001). For the phantoms an excellent correlation between the true and computed 3-D cross-sectional profile was found (p < 0.005) and an accuracy for length and degree measurements of 2.14 mm and 2.53% respectively could be determined. The corresponding figures for the precision were found to be 0.92 mm and 2.56%. CONCLUSION: LTT 3-D cross-sectional profiles permit objective, accurate and precise assessment of LTT caliber changes. Minor LTT caliber changes can be observed even in normals and, in case of an otherwise normal S-CT study, can be regarded as artifacts. 相似文献