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31.
The stereologic analysis of a solid grain has been applied for determination of its porosity. The investigations were carried out on a natural hematite grain reduced to magnetite at 723 K. Stereologic analysis enabled the porosity of this material to be determined on the basis of independently measured grain contours and volume fractions of grain components: hematite, magnetite and pores. A conformity criterion has been formulated, regarding determination of grain volume on the basis of known densities of components and their measured volume fractions in the grain, and on the basis of weight and apparent grain density measurements. The volume increase accompanying reduction of hematite to magnetite, determined from these independent measurements, was in the range 7–19%. By measuring Ferets diameter, the volume of the convex envelope of the grain increased as a result of phase transformation by about 11%. Simultaneously, the volume of the solid phase was found to decrease by 1.5%. The total porosity of the reduced grain, determined by stereologic analysis amounted to 17.5%; 7.7% of which was related to cracks and large pores, and 9.8% to small pores in the magnetite phase. The porosity value determined by the classical mercury method was approximately the same. 相似文献
32.
Katarzyna TyszczukAuthor Vitae 《Sensors and actuators. B, Chemical》2011,156(2):899-905
The properties of the lead film electrode designed for adsorptive stripping voltammetric measurements of organic compounds were examined by electrochemical and microscopic techniques. The effect of Pb(II) concentration, the influence of deposition potential and time of the lead film formation on the determination of bleomycin at an in situ lead-coated glassy carbon electrode have been studied. Atomic force microscopy (AFM) was used to characterize the Pb crystallite growth on the glassy carbon surface. The morphology of the deposits was evaluated and its influence on the bleomycin responses was discussed. 相似文献
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Tomasz Pdzinski Katarzyna Grzyb Konrad Skotnicki Piotr Filipiak Krzysztof Bobrowski Chryssostomos Chatgilialoglu Bronislaw Marciniak 《International journal of molecular sciences》2021,22(9)
Within the reactive oxygen species (ROS) generated by cellular metabolisms, hydroxyl radicals (HO•) play an important role, being the most aggressive towards biomolecules. The reactions of HO• with methionine residues (Met) in peptides and proteins have been intensively studied, but some fundamental aspects remain unsolved. In the present study we examined the biomimetic model made of Ac-Met-OMe, as the simplest model peptide backbone, and of HO• generated by ionizing radiation in aqueous solutions under anoxic conditions. We performed the identification and quantification of transient species by pulse radiolysis and of final products by LC-MS and high-resolution MS/MS after γ-radiolysis. By parallel photochemical experiments, using 3-carboxybenzophenone (CB) triplet with the model peptide, we compared the outcomes in terms of short-lived intermediates and stable product identification. The result is a detailed mechanistic scheme of Met oxidation by HO•, and by CB triplets allowed for assigning transient species to the pathways of products formation. 相似文献
37.
Emilia Szymańska Katarzyna Winnicka Piotr Wieczorek Pawe? Tomasz Sacha El?bieta Anna Tryniszewska 《International journal of molecular sciences》2014,15(10):17765-17777
The combination of an antifungal agent and drug carrier with adjunctive antimicrobial properties represents novel strategy of complex therapy in pharmaceutical technology. The goal of this study was to investigate the unmodified and ion cross-linked chitosan’s influence on anti-Candida activity of clotrimazole used as a model drug in hydrogels. It was particularly crucial to explore whether the chitosans’ structure modification by β-glycerophosphate altered its antifungal properties. Antifungal studies (performed by plate diffusion method according to CLSI reference protocol) revealed that hydrogels obtained with chitosan/β-glycerophosphate displayed lower anti-Candida effect, probably as a result of weakened polycationic properties of chitosan in the presence of ion cross-linker. Designed chitosan hydrogels with clotrimazole were found to be more efficient against tested Candida strains and showed more favorable drug release profile compared to commercially available product. These observations indicate that novel chitosan formulations may be considered as promising semi-solid delivery system of clotrimazole. 相似文献
38.
Katarzyna Matkiewicz Agnieszka Bukowska Wiktor Bukowski 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(2):332-341
Hydroxyl functionalized gel type resins derived from 2-hydroxyethyl, 2-hydroxypropyl and 2-hydroxy-3-phenoxypropyl methacrylates
were applied to covalent immobilization of Mn(salen) complexes via glutarate and carbonate linkers. The obtained catalysts
were characterized by FTIR and DR UV–Vis methods and elemental analysis. It was found that the activity of polymeric catalysts
obtained in this way depended on both the nature of the functional and cross-linking monomers and the degree of the cross-linking
of polymer matrices and the way of complex immobilization. The highest activity was observed for the complexes immobilized
on the HEMA resins cross-linked with 3%-mol of diethylene glycol dimethacrylate. For instance, in the presence of the catalysts
with (S,S)-salen ligand S-epoxystyrene and (1S, 2R)-epoxyindene could be obtained with 46% and 69% ee, respectively. Attempts
have also been made to recycle the selected catalyst. However, a rapid fall off in the activity was observed, although the
selectivity was similar in which three cycles. 相似文献
39.
Siet J. Sijtsema Katarzyna Jesionkowska Ronan Symoneaux Dorota Konopacka Harriëtte Snoek 《LWT》2012,49(2):275-281
Dried fruits consumption has not received much research attention, although these foods are associated with potential health benefits. Therefore, the aim of this study was to compare fresh fruits and dried fruits on measures of health, convenience and consumer feelings.An on-line questionnaire that measured consumers' perceptions of the health benefits and convenience characteristics and their feelings about the consumption of both fresh fruits (apples and plums) and dried fruits (e.g., raisins, dates, and apricots) was completed by 693 respondents (Polish, French, and Dutch).Generally, fresh fruits were perceived to be healthier and less convenient than dried fruits. Consumers also reported more positive feelings about the consumption of fresh fruits compared to dried fruits. The more that the respondents were willing to sacrifice for their health, the more positively they rated the health aspects of both fresh and dried fruits, as well as several perceptions of convenience of both fresh and dried fruits. Health preoccupation was unrelated to most of the convenience perceptions and was associated with lower scores on several perceptions of healthiness. Recommendations for the consumer-oriented development of dried fruits are also provided. 相似文献
40.
Kała Katarzyna Maślanka Anna Sułkowska-Ziaja Katarzyna Rojowski Jacek Opoka Włodzimierz Muszyńska Bożena 《Food science and biotechnology》2016,25(3):829-837
Food Science and Biotechnology - The objective of this study was to obtain the in vitro cultures of Boletus badius under controlled conditions and investigate the release of indole compounds and... 相似文献