Catching a molecule at the air-water interface: Dynamic pore array for molecular recognition

As a soft and flexible porous structure, a pore array of a steroid cyclophane SC(OH), which consists of the rigid 1,6,20,25-tetraaza[6.1.6.1]paracyclophane ring connected to four steroid moieties (cholic acid) through flexible L-lysine spacers, was prepared at the air-water interface. As confirmed by surface pressure (π)-molecular area (A) isotherms, transition between open conformation and cavity conformation of the SC(OH) molecule was reversibly induced upon repeated compression and expansion of its monolayer at pH 11 where amino groups of the lysine residues are not fully deprotonated. Capture and release of an aqueous fluorescent guest (TNS) by SC(OH) was observed upon dynamic cavity formation through surface fluorescence spectroscopy. At pH 12, dynamic cavity formation of SC(OH) was sufficiently suppressed, and the capture and release of an aqueous TNS by the monolayer was not virtually observed. Lessened electrostatic repulsion between the SC(OH) molecules due to conversion of ammonium to free amine may prevent the cavity from reopening. The importance of dynamic nature of cavity formation on the guest binding was also proved by control experiments using SC(H), which cannot form cavity conformation at any surface pressures at both pH 11 and 12.     

Formation of phase structure and crystallization behavior in blends containing polystyrene–polyethylene block copolymers

The microphase separation structure in the molten state and the structure formation in crystallization from such ordered melt were investigated for the blends of polystyrene–polyethylene block copolymers (SE) with polystyrene homopolymer (PS) and polyethylene homopolymer (PE) and for the blends consisting of two kinds of SE with different copolymer compositions from each other, using synchrotron small-angle X-ray scattering techniques (SAXS). The copolymer compositions of SE block copolymers employed were 0.34, 0.58 and 0.73 wt. fraction of PE, and their melt morphologies were cylindrical, lamellar and lamellar, respectively. Macrophase separation or the morphology change in the melt occurred depending on the molecular weight and the blend composition, as reported so far. In crystallization from such macrophase-separated and microphase-separated melts, the melt morphology was completely kept for all the blends. Crystallization behavior was also investigated for the blends. The crystallization within the spherical and cylindrical domains surrounded by glassy PS was not observed for SE/PS blends. In the crystallization from the macrophase-separated melt, two exothermal peaks were observed in the DSC measurements, while a single peak was observed for other blends. For the blends with PS, the degree of crystallinity was depressed and the apparent activation energy of crystallization was high, compared to those for the corresponding neat SE. For SE/PE and SE/SE blends, those were changed depending on the blend composition.     

Thermal deformation analysis of tabbed solar cells using solder alloy and conductive film

Finite element analysis (FEA) has been carried out with the aim of understanding the thermal deformation characteristics of two solar cell configurations. One of the solar cell models is tabbed by lead-free solder, the other model by Conductive film (CF). A high temperature soldering process could weaken the bond and reduce the reliability of the cells because of the residual stress caused by the different thermal expansion coefficients of the materials. Moreover, solar irradiation generates temperature distribution across the surface of the solar cell, and the development of solar cells made of thinner crystalline silicon wafers will lead to the reduction in manufacturing costs. In this study, Finite element analysis (FEA) of the manufacturing process has been carried out using both solder and CF bonding. Three temperature cycles were applied to analyze different environmental operating conditions and understand how thermal cycles affect the residual stress during actual service conditions. This investigation provides a comparison of thermal deformations between solder and CF bonded solar cells in order to understand which offers substantial reliability in the long term. Also this study explores the effects of various thicknesses of the silicon wafer on the residual stress and deformation of the solar cells.     

Template‐Free Fabrication of Mesoporous Alumina Nanospheres Using Post‐Synthesis Water‐Ethanol Treatment of Monodispersed Aluminium Glycerate Nanospheres for Molybdenum Adsorption

This work reports the template‐free fabrication of mesoporous Al₂O₃ nanospheres with greatly enhanced textural characteristics through a newly developed post‐synthesis “water‐ethanol” treatment of aluminium glycerate nanospheres followed by high temperature calcination. The proposed “water‐ethanol” treatment is highly advantageous as the resulting mesoporous Al₂O₃ nanospheres exhibit 2–4 times higher surface area (up to 251 m² g^?1), narrower pore size distribution, and significantly lower crystallization temperature than those obtained without any post‐synthesis treatment. To demonstrate the generality of the proposed strategy, a nearly identical post‐synthesis “water treatment” method is successfully used to prepare mesoporous monometallic (e.g., manganese oxide (MnO₂)) and bimetallic oxide (e.g., CuCo₂O₄ and MnCo₂O₄) nanospheres assembled of nanosheets or nanoplates with highly enhanced textural characteristics from the corresponding monometallic and bimetallic glycerate nanospheres, respectively. When evaluated as molybdenum (Mo) adsorbents for potential use in molybdenum‐99/technetium‐99m (⁹⁹Mo/^99mTc) generators, the treated mesoporous Al₂O₃ nanospheres display higher molybdenum adsorption performance than non‐treated Al₂O₃ nanospheres and commercial Al₂O₃, thereby suggesting the effectiveness of the proposed strategy for improving the functional performance of oxide materials. It is expected that the proposed method can be utilized to prepare other mesoporous metal oxides with enhanced textural characteristics and functional performance.     

A cross-junction channel valveless-micropump with PZT actuation

A gas-jet micro pump with novel cross-junction channel has been designed and fabricated using a Si micromachining process. The valveless micro pump is composed of a piezoelectric lead zirconate titanate (PZT) diaphragm actuator and fluidic network. The design of the valveless pump focuses on a cross-junction formed by the neck of the pump chamber and one outlet and two opposite inlet channels. The structure of cross-junction allows differences in fluidic resistance and fluidic momentum inside the channels during each PZT diaphragm vibration cycle, which leads to the gas flow being rectified without valves. The flow channels were easily fabricated by using silicon etching process. To investigate the effects of the structure of the cross-junction on the gas flow rate, two types of pump with different cross-junction were studied. The design and simulation were done using ANSYS-Fluent software. The simulations and experimental data revealed that the step-nozzle structure is much more advantageous than the planar structure. A flow rate of 5.2 ml/min was obtained for the pump with step structure when the pump was driven at its resonant frequency of 7.9 kHz by a sinusoidal voltage of 50 V_p–p.     

View-based virtual learning and recognition of 3D object using view model obtained by motion-stereo

View-based approach for learning and recognition of 3D object and its pose detection was proved to be affective and efficient, except its high learning cost. In this research, we propose a virtual learning approach which generates learning samples of views of an object from its 3D view model obtained by motion-stereo method. From the generated learning sample views, features of high-order autocorrelation are extracted, and discriminant feature spaces for object recognition and pose detection are built. Recognition experiments on real objects are carried out to show the effectiveness of the proposed method. Caihua Wang, Ph.D.: He received his B.S. in mathematics and M.E. in electronic engineering from Renmin University of China, Beijing, China in 1983 and 1986, and his Ph. D. from Shizuoka University, Hamamatsu, Japan in 1996. He is a JST domestic fellow and is doing his post doctoral research at Electrotechnical Laboratory. His research interests are computer vision and image processing. He is a member of IEICE and IPSJ. Katsuhiko Sakaue, Ph.D.: He received the B.E., M.E., and Ph.D. degrees all in electronic engineering from University of Tokyo, in 1976, 1978 and 1981, respectively. In 1981, he joined the Electrotechnical Laboratory, Ministry of International Trade and Industry, and engaged in researches in image processing and computer vision. He received the Encouragement Prize in 1979 from IEICE, and the Paper Award in 1985 from Information.     

Interactive learning and management of visual information via human-like software robot

To achieve smooth real-world interaction between people and computers, we developed a system that displays a three-dimensional computer-graphic human-like image from the waist up (anthropomorphic software robot: hereinafter “robot”) on the display, that interactively sees and hears, and that has fine and detailed control functions such as facial expressions, line of sight, and pointing at targets with its finger. The robot visually searches and identifies persons and objects in real space that it has learned in advance (registered space, which was our office in this case), manages the history information of the places and times it found objects and/or persons, and tells the user, indicating their three-dimensional positions with line of sight and its finger. It interactively learns new objects and persons with line of with their names and owners. By using this function, the robot can engage in simple dialogue (do a task) with the user. Osamu Hasegawa, Ph.D.: He received the B.E. and M.E. degrees from the Science University of Tokyo, in 1988, 1990 respectively. He received Ph.D. degree from the University of Tokyo, in 1993. Currently, he is a senior research scientist at the Electrotechnical Laboratory (ETL), Tsukuba, Japan. His research interests include Computer Vision and Multi-modal Human Interface. Dr. Hasegawa is a member of the AAAI, the Institute of Electronics, Information and Communication Engineers, Japan (IEICE), Information Processing Society of Japan and others. Katsuhiko Sakaue, Ph.D.: He received the B.E., M.E., and Ph.D. degrees all in electronic engineering from the University of Tokyo, in 1976, 1978 and 1981, respectively. In 1981, he joined the Electrotechnical Laboratory, Ministry of International Trade and Industry, and engaged in researches in image processing and computer vision. He received the Encouragement Prize in 1979 from IEICE, and the Paper Award in 1985 from Information Processing Society of Japan. He is a member of IEICE, IEEE, IPSJ, ITE. Satoru Hayamizu, Ph.D.: He is a leader of Interactive Intermodal Integration Lab. at Electrotechnical Laboratory. He received the B.E., M.E., Ph.D. degrees from Tokyo University. Since 1981, he has been working on speech recognition, spoken dialogue, and communication with artifacts. From 1989 to 1990, he was a visiting scholar in Carnegie Mellon University and in 1994 a visiting scientist in LIMSI/CNRS.     

Magnetic collective excitations in the B phase of superfluid He-3

The dynamical susceptibility of the B phase of superfluid He-3 in the presence of dipolar coupling is calculated in the collisionless regime. Two poles of the susceptibility that correspond to the spin wave and the mode with energy gap (2/5)^1/2 2 are found. The result agrees with that of Tewordt and Einzel qualitatively and contradicts the recent work by Maki. The residue of the high-frequency mode becomes remarkable near the transition temperature. The dispersion relations of these modes atT=0 K and near the transition temperature are given in the most general form.     

Shear viscosity of the B phase of superfluid3He

The shear viscosity (T) in the Balian-Werthamer (BW) state of superfluid ³ He is calculated variationally throughout the region 0t 1(t=T/T _c) from the transport equation for Bogoliubov quasiparticles. Coherence factors are treated exactly in the calculation of the collision integral. The numerical result for =_s= _s(T)/_n(T_c) agree very well with experiment in the range 0.8t1.0. Analytic expressions = 0.577 (1–1.0008t) and =1–(23/64) [=(T)/k _B T] are obtained in the low-temperature region and in the vicinity ofT _c, respectively. From the numerical analysis it is shown that the latter equation is valid only in the temperature range 0.9997t1.0.Supported by the Research Institute for Fundamental Physics, Kyoto University.     

Stress-corrosion cracking of aged AlCuMg alloys in NaCl solution

Pitting potentials and stress corrosion life-times of AlCuMg alloys (mainly 2024 alloy) with various ageing structures have been measured in a de-aerated 1M NaCl solution under conditions of controlled potential. The aged alloy, which has the higher susceptibility to stress-corrosion cracking, showed two pitting potentials corresponding to pitting at the grain boundaries and within the grains. The susceptibility of the alloys to intergranular stress-corrosion cracking occurred at potentials above the pitting potential of the grain boundaries. The intergranular stress-corrosion cracking is caused not by the dissolution of the grain boundary precipitates (S phase) but by the pitting dissolution of the solute-denuded zones along the grain boundaries. Aspects of SCC in the alloys are similar to those in the Al-4%Cu alloy without Mg.