Clarification of tomato juice by cross‐flow microfiltration

Clarification of fruit and vegetable juice is one of the integrated parts of modern industrial juice processing. This paper describes the clarification of tomato juice through microfiltration process. In this regard, the influence of transmembrane pressure (1, 2 and 3 bar), cross‐flow velocity which corresponds with Reynolds number (300, 1500 and 2500) and temperature (30, 40 and 50 °C) on permeate flux and some properties of clarified juice such as colour, turbidity, density, viscosity, pH and total soluble solid have been studied. The results revealed that the investigated parameters had an increasing effect on the permeate flux and colour and the greatest effect on the permeate flux and colour was supplied by cross‐flow velocity. The other permeate properties did not significantly change with variations of the operating parameters. Eventually, the statistical analysis indicated that the interactional effect of cross‐flow velocity and TMP on the permeate flux was significant.     

Graft copolymerization of methyl methacrylate onto sago starch using ceric ammonium nitrate and potassium persulfate as redox initiator systems

The graft copolymerization of methyl methacrylate (MMA) onto sago starch was carried out in aqueous media by different initiators of ceric ammonium nitrate (CAN) and potassium persulfate (PPS) and under a nitrogen gas atmosphere. Using CAN as an initiator, the maximum percentage of grafting (%G) was ascertained to be 246% at the following optimum conditions: a 70°C reaction temperature, a 2‐h reaction period, 2.0 mmol of CAN, 0.4 mmol of nitric acid, and 141 mmol of MMA. The maximum %G achieved with PPS as the initiator was 90%. The optimum conditions were a 50°C reaction temperature, a 1.5‐h reaction period, 47 mmol of monomer, and 1.82 mmol of PPS. The grafting of MMA onto sago starch was confirmed by the IR spectra of pure sago starch, MMA, and MMA grafted sago starch. This material may have application as a biodegradable plastic. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 1375–1381, 2001     

Determination of free bile acids in pharmaceuticals by thin layer chromatography and high performance liquid chromatography

High-performance liquid chromatography with evaporative light scattering detection (HPLC-ELSD) and thin layer chromatography with flame ionization detection (TLC-FID) have been applied to the separation of five main free bile acids present in humans: cholic (CA), chenodeoxycholic (CDCA), deoxycholic (DCA), lithocholic (LCA) and ursodeoxycholic (UDCA) acid. HPLC separation was performed on Biospher Si 100 column using a mixture of n-heptane, isopropanol, ethylacetate, methanol and glacial acetic acid as a mobile phase. All the compounds were separated in less than 12 minutes by using a gradient elution mode. TLC-FID separation was performed on S-II Chromarods with a mixture of isooctane, ethylacetate and glacial acetic acid as a mobile phase. HPLC-ELSD method was applied to the determination of CDCA and UDCA in pharmaceuticals and their purity control when LCA, DCA and CA were considered as impurities.     

A survey of temporal decorrelation from spaceborne L-Band repeat-pass InSAR

In this paper we quantify the effects of temporal decorrelation in repeat pass synthetic aperture radar interferometry (InSAR). Temporal decorrelation causes significant uncertainties in vegetation parameter estimates obtained using various InSAR techniques, which are desired on a global scale. Because of its stochastic nature temporal decorrelation is hard to model and isolate. In this paper we analyze temporal decorrelation statistically as observed in a large swath of SIR-C L-Band InSAR data collected over the eastern United States, with a repeat pass duration of one day in October 1994 and a near zero perpendicular baseline. The very small baseline for this particular pair makes the effect of volumetric scattering on correlation magnitude statistics nearly imperceptible, allowing for a quantitative analysis of temporal effects alone. The swath analyzed in this paper spans more than a million hectares of terrain comprised primarily of deciduous and evergreen forests, agricultural land, water and urban areas. The relationships of these different land-cover types, phenology and weather conditions (i.e. precipitation and wind) on the measures of interferometric correlation is analyzed in what amounts to be the most geographically extensive analysis of this phenomenon to date.     

Design of an RMPC with a time‐varying terminal constraint set for tracking problem

This paper presents a robust model predictive control algorithm with a time‐varying terminal constraint set for systems with model uncertainty and input constraints. In this algorithm, the nonlinear system is approximated by a linear model where the approximation error is considered as an unstructured uncertainty that can be represented by a Lipschitz nonlinear function. A continuum of terminal constraint sets is constructed off‐line, and robust stability is achieved on‐line by using a variable control horizon. This approach significantly reduces the computational complexity. The proposed robust model predictive controller with a terminal constraint set is used in tracking set‐points for nonlinear systems. The effectiveness of the proposed method is illustrated with a numerical example. Copyright © 2015 John Wiley & Sons, Ltd.     

Finite element analysis of laser inert gas cutting on Inconel 718

Inconel 718 has high strength, which makes it difficult to cut using conventional cutting methods. In the present study, the laser inert gas cutting of Inconel 718 was simulated by finite element analysis software ANSYS. Finite element method was used to predict thermal stress and kerf width formation during the laser cutting process. ANSYS Parameter Design Language was used to model the Gaussian-distributed heat flux from the laser beam acting on the workpiece. The removal of melted material during laser cutting to form the kerf width was modeled by employing the element death methodology in ANSYS. In addition, laser cutting was simulated at continuous wave (CW) and the effects of laser power and cutting speed on kerf width were investigated. A series of experiments were carried out to verify the predictions. The temperature fields on the workpiece were measured using thermocouples. The kerf width size was measured using a profile projector, whereas the metallurgical and morphological changes at the cutting edge were examined using scanning electron microscopy. A good correlation was found between the simulation and experimental results.     

Preparation and characterization of a new coagulant based on the sago starch biopolymer and its application in water turbidity removal

A new organic coagulant, sago starch (SS)‐graft‐polyacrylamide (PAm), was prepared by the ceric‐ion‐induced redox polymerization of acrylamide (Am) onto SS at room temperature. The effects of the variation of the concentration of Am and the initiator on the percentages of yield and total conversion were investigated. The chemical composition, viscosity, and side‐chain‐average molecular weight of the obtained graft copolymers were determined. The newly obtained coagulant was tested for the treatment of the turbidity of water. The SS‐g‐PAm coagulants were found to achieve water turbidity removal up to 96.6%. The results of this study suggest that SS‐g‐PAm copolymer is a potential coagulant for reducing turbidity during water treatment. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Constructing biocatalytic nanochannel membranes for unidirectional isomer conversion and separation

Isomer conversion and separation are crucial in the chemical, pharmaceutical, and food industries. However, this process remains challenging due to the reversed conversion of isomers and their similar boiling points and kinetic diameters. Herein, an enzyme-catalyzed nanochannel membrane with a hierarchical structure is fabricated for selective and directional isomeric conversion and separation. The enzyme is embedded in a confined polymer network that shows high stability and retains 95% of its initial activity after 50 reaction cycles. Studying the transport mechanisms between isomers through the membrane shows that the hierarchical layers of the membrane impose unequal energy barriers to the forward and backward transport of products, promoting unidirectional diffusion of products and interrupting the equilibrium of the isomerization reaction to increase the conversion rate by 43%. Overall, this work opens a new avenue for the design of biocatalytic nanochannel membranes and the directional production and in situ separation of isomers.     

Advanced Functional Carbon Nitride by Implanting Semi-Isolated VO2 Active Sites for Photocatalytic H2 Production and Organic Pollutant Degradation

It is critical to facilitate surface interaction for liquid–solid two-phase photocatalytic reactions. This study demonstrates more advanced, efficient, and rich molecular-level active sites to extend the performance of carbon nitride (CN). To achieve this, semi-isolated vanadium dioxide is obtained by controlling the growth of non-crystalline VO₂ anchored into sixfold cavities of the CN lattice. As a proof-of-concept, the experimental and computational results solidly corroborate that this atomic-level design has potentially taken full advantage of two worlds. The photocatalyst comprises the highest dispersion of catalytic sites with the lowest aggregation, like single-atom catalysts. It also demonstrates accelerated charge transfer with the boosted electron–hole pairs, mimicking heterojunction photocatalysts. Density functional theory calculations show that single-site VO₂ anchored into the sixfold cavities significantly elevates the Fermi level, compared with the typical heterojunction. The unique features of semi-isolated sites result in a high visible-light photocatalytic H₂ production of 645 µmol h⁻¹ g⁻¹ with only 1 wt% Pt. They also represent an excellent photocatalytic degradation for rhodamine B as well as tetracycline, surpassing the activities obtained from many conventional heterojunctions. This study presents exciting opportunities for the design of new heterogeneous metal oxide for a variety of reactions.