Numerical techniques for solving solidification and melting phase change problems

This article reviews several mathematical formulations including the corresponding boundary conditions for numerical predictions of solidification and melting. Emphasis is on techniques that are used in solving solid–liquid interface phenomena. The fixed grid enthalpy method is reviewed based on the solution techniques of conduction and convection related phase change problems. Variable grid methods are categorized and then analyzed based on their accuracy, computational efforts and convergence characteristics. The article concludes with some guidance for selecting the accurate solution techniques for solving solidification and melting problems.     

Development and optimization of self-nanoemulsifying drug delivery systems (SNEDDS) for curcumin transdermal delivery: an anti-inflammatory exposure

The purpose of this work is to develop novel lipid-based self-nanoemulsifying drug delivery systems (SNEDDS) as carriers for transdermal delivery of curcumin. SNEDDS containing black seed oil, medium chain mono- and diglycerides and surfactants, were prepared as curcumin delivery vehicles. Their formation spontaneity, morphology, droplet size, and drug loading were evaluated. Gel preparation containing two of the SNEDDS formulations were used in the carrageenan induced paw edema to evaluate the anti-inflammatory effect. Results showed droplet size as low as 71?nm. The highest drug loading was observed with SNEDDS-F6 of ～45?mg/g. In in-vivo investigation, SNEDDS-F6 exhibited significant anti-inflammatory activities in terms of 80% reduction in paw edema when compared with positive control. The prepared SNEDDS with the elevated entrapment efficiency, good transdermal penetration ability could be a suitable candidate for effective transdermal curcumin skin delivery.     

Extended sliding frame R-Aloha: Medium access control (MAC) protocol for mobile networks

Proliferation of mobile communication devices necessitates a reliable and efficient medium access control (MAC) protocol. In this paper, A MAC protocol, called extended sliding frame reservation Aloha (ESFRA), based on sliding frame R-Aloha (SFRA) is proposed for network access technique. ESFRA is particularly designed to solve the mobile hidden station (MHS) problem in a mobile ad hoc network (MANET) by including relative locations of transmitting stations in the packet frame information header. The MHS problem is unique in mobile networks and occurs if a mobile station enters in a collision free zone of any ongoing communication and disturbs this communication with its transmission. In addition to the MHS problem, ESFRA simultaneously solves hidden station, exposed station, and neighborhood capture problems typically observed in wireless networks. A Markov model of ESFRA is developed and provided here to estimate throughput, delay and collision probabilities of the proposed protocol. The Markov modeling is extended to the analysis of SFRA and IEEE 802.11 to compare these competing MAC protocols with ESFRA. The analysis shows that ESFRA decreases frame transmission delay, increases throughput, and reduces collision probabilities compared to IEEE 802.11 and SFRA. ESFRA improves the network throughput 28 percent compared to that of IEEE 802.11, and 33 percent compared to that of SFRA. The improved performance is obtained at the expense of the synchronization compared to IEEE 802.11, but there is virtually no extra cost compared to SFRA.     

Energy savings and emissions reductions for rewinding and replacement of industrial motor

Electric motors consume 30-80% of total industrial energy around the world. This study estimates the economic viability of replacing rewound and standard motors with high efficiency motors (HEMs) in the industrial sector. The efficiency of a motor is degraded when it is rewound and it is better to rewind a larger motor compared with a smaller motor. It was found that a HEM can save on average 5.5% of energy compared with a standard motor. In addition, the payback period was found to be reasonable when a motor is operated at a 50% load. HEMs will also save a sizeable amount of energy and reduce emissions. It was estimated that 67,868 MWh/year energy and US$ 4,343,531 per year could be saved by introducing HEMs. By contrast, 44,582 tons of CO₂, 333 tons of SO₂ and 122 tons of NO_x emissions could be reduced through the aforementioned energy savings. This study found that rewound motors of a larger size and HEMs are economically viable.     

Variation of splat shape with processing conditions in plasma sprayed alumina coatings

This paper is on various splat shapes obtained using three alumina based powders sprayed on various substrates. The parameters considered were substrate preheating temperature, nozzle diameter, and secondary and primary gas flow rates. The splat shape was found to be strongly dependent on spraying conditions. The substrate preheating temperature determined the degree of substrate wetting by the splat. A change in either nozzle diameter or primary gas flow rate brought about a change in the particle momentum and subsequently, a change in splat shape. The splat shape differed widely on an as - sprayed bond coat as compared to a polished one, owing to splat confinement by surface asperities. Sub-microscale surface roughness of polished substrate surfaces showed an increase with the preheating temperature and this in turn, resulted in better substrate wetting by the splats.     

The role of geometry on the viscoelastic materials properties: tensile and stress relaxation of the yarn

The time-dependent mechanical behavior of textiles has particular importance. One of such behaviors is stress relaxation. When strain is applied constantly, there is a decreased stress with time in viscoelastic materials, which is called stress relaxation. The aim of this study is to investigate the effect of knot’s geometry (surgeon, square and eight) and the number of knots on the tensile and stress relaxation properties of the polyester yarn. Significant differences were observed for the tensile characteristics of the yarn in the presence of the knot. Generally, the knotted yarns demonstrated lower tensile stress and strain at failure. Moreover, the results revealed that the stress relaxation behavior of the yarn is affected by the number of knots and their geometry. The yarn without knot exhibited the highest stress relaxation percent while the yarn with the surgeon’s knot displayed the least stress relaxation percent. On the other hand, increasing the number of knots led to a decrease in the percentage of yarn stress relaxation.     

Performance investigation of an automotive car radiator operated with nanofluid-based coolants (nanofluid as a coolant in a radiator)

Water and ethylene glycol as conventional coolants have been widely used in an automotive car radiator for many years. These heat transfer fluids offer low thermal conductivity. With the advancement of nanotechnology, the new generation of heat transfer fluids called, “nanofluids” have been developed and researchers found that these fluids offer higher thermal conductivity compared to that of conventional coolants. This study focused on the application of ethylene glycol based copper nanofluids in an automotive cooling system. Relevant input data, nanofluid properties and empirical correlations were obtained from literatures to investigate the heat transfer enhancement of an automotive car radiator operated with nanofluid-based coolants. It was observed that, overall heat transfer coefficient and heat transfer rate in engine cooling system increased with the usage of nanofluids (with ethylene glycol the basefluid) compared to ethylene glycol (i.e. basefluid) alone. It is observed that, about 3.8% of heat transfer enhancement could be achieved with the addition of 2% copper particles in a basefluid at the Reynolds number of 6000 and 5000 for air and coolant respectively. In addition, the reduction of air frontal area was estimated.     

Synthesis and characterization of catalysts produced from paper mill sludge: I. Determination of NOx removal capability

Characteristics and catalytic properties of a series of carbon-based catalysts (CBCs) produced from paper mill sludge were evaluated. The major processes involved in the production of the catalysts were chemical activation, impregnation, pyrolysis, and post pyrolysis rinsing. The porous structure, catalytic activity and thermostability of the catalysts were tailored during the production stage by introducing hetero-atoms (zinc chloride, and ferric nitrate) in the carbon structure. Characterization of the produced CBCs included determination of the surface area, pore size, and pore size distribution (PSD) from standard N₂-adsorption isotherm data. The extent of graphitization and the presence of metal crystals were identified from X-ray diffraction (XRD). The limit of the catalyst gasification was estimated from thermogravimetric analysis (TGA) conducted in an oxidized environment. The NO_x reduction capability of the produced catalysts was evaluated in the presence of carbon monoxide using a fixed bed reactor. The reaction temperature ranged from 300 to 500°C. It was shown that paper mill sludge is an excellent precursor for the production of CBCs with NO_x removal capability of 66–94%. The catalytic capability of the produced CBCs varied according to the method of production, catalyst surface properties (surface area, pore structure, PSD), metal composition and reaction temperature. The highest NO_x removal capacity was observed for the catalytic reactions carried out at 400°C. The mesoporous catalyst produced with a Zn:Fe molar ratio of 1:0.5 exhibited the maximum NO_x removal catalytic activity of 94%.     

Heavy metal accumulation in different varieties of wheat (Triticum aestivum L.) grown in soil amended with domestic sewage sludge

The concentrations of heavy metals (HMs) in plants served to indicate the metal contamination status of the site, and also revealed the abilities of various plant species to take up and accumulate them from the soil dressed with sewage sludge. A study to comprehend the mobility and transport of HMs from soil and soil amended with untreated sewage sludge to different newly breaded varieties of wheat (Anmol, TJ-83, Abadgar and Mehran-89) in Pakistan. A pot-culture experiment was conducted to study the transfer of HMs to wheat grains, grown in soil (control) and soil amended with sewage sludge (test samples). The total and ethylenediaminetetraaceticacid (EDTA)-extractable HMs in agricultural soil and soil amended with domestic sewage sludge (SDWS) and wheat grains were analysed by flame atomic absorption spectrometer/electrothermal atomic absorption spectrometer, prior to microwave-assisted wet acid digestion method. The edible part of wheat plants (grains) from test samples presented high concentration of all HMs understudy (mgkg(-1)). Significant correlations were found between metals in exchangeable fractions of soil and SDWS, with total metals in control and test samples of wheat grains. The bio-concentration factors of all HMs were high in grains of two wheat varieties, TJ-83 and Mehran-89, as compared to other varieties, Anmol and Abadgar grown in the same agricultural plots.