Acoustic emission for detecting deterioration of capacitors under aging

There is continuous pressure on production cost reduction of foil-based capacitors, widely used in domestic appliance. Therefore, investigation of the deterioration mechanisms within capacitors is important to reduce their production costs at maintained reliability. These mechanisms were observed in two capacitors batches of classes Y2 (27 nF) and X2 (470 nF). An acoustic emission signal was observed when the capacitors were polarized by excessive voltage. This signal is induced by partial discharges that can lead to capacitor destruction. Next, the capacitors were aged at elevated temperature and also in presence of excessive polarization. We conclude that the acoustic emission signal can predict deterioration of dielectric insulation resistance in capacitors of class Y2. The observed destruction of capacitor of class X2 is caused mainly by detachment of the sprayed metalized contacts that is induced by overheating during partial discharges sparking.     

Expert system shells in student advising

A student advising expert system has been developed using the EXSYS Professional expert system shell. The motivation of using a commercially-available expert system shell is presented. Examples of IF-THEN-ELSE type of rules are shown. Interrelation of the knowledge base with class offerings, and with the structure of the B.Sc. program in Computer Science is demonstrated. The development process is described in detail. Improvements resulted from testing the system are presented.     

Durability and surface chemistry of horizontally aligned CNT films as electrodes upon electrolysis of acidic aqueous solution

We devised a simple and effective method of electrochemical functionalization of horizontally aligned CNT films in diluted HCl and H₂SO₄ solutions upon their electrolysis under a constant current mode. We were able to cause notable generation of carbon–oxygen and carbon–chlorine functional groups on the CNT film anodes as proven by EDX, XPS, and Raman spectroscopy. As a consequence, we observed significant changes of the morphology of the material under electron microscopy, what translated into improved compatibility of CNTs with hydrophilic media. In turn, application of CNT films as cathodes was found as a powerful tool for a thorough cleaning of the nanotubes. Finally, we demonstrated that by the selection of appropriate conditions, CNT films can act as easy-to-make and flexible electrodes with a high stability and performance superior to graphite for generation of non-oxidizing gases such as hydrogen from solution. CNT film electrodes are two orders of magnitude lighter and require much lower overpotential for faradaic splitting of water.     

Optimal optical design of thin-film photovoltaic devices

In this paper we report the results of an effort to develop a design tool to optimise any solar cell with thin-film structure. An optical admittance analysis which takes into account the interference effects in the multilayer thin-film system is discussed. This method provides a technique for calculating the optical properties of a thin-film device with a multilayer configuration. It also allows us to explore the nature and magnitude of optical losses in p-i-n type single or multi-junction a-Si : H solar cells, and to optimise the structure of such cells to utilise enhanced interference effects to obtain the maximum possible utilisation of incident solar radiation.     

The influence of porous silicon on junction formation in silicon solar cells

In this work the results of a structural investigation by SEM of porous silicon (PS) before and after diffusion processes are reported. The formation of PS n⁺/p structures were carried out on PS p/p silicon wafers with two methods: from POCl₃ in a conventional furnace and from a phosphorous doped paste in an infrared furnace. Sheet resistance was found to be a strong function of PS structure. Further details on sheet resistance distribution are reported. The electrical contacts in prepared solar cells were obtained by screen printing process, with a Du Ponte photovoltaic silver paste for front contacts and home-prepared silver with 3% aluminium paste for the back ones. Metallization was done in the infrared furnace. Solar cell current–voltage characteristics were measured under an AM 1.5 global spectrum sun simulator. The average results for multi-crystalline silicon solar cells without antireflection coating are: I_sc=720 (mA), V_oc=560 (mV), FF=69%, Eff=10.6% (area 25 cm²).     

The preparation of TiO2–nitrogen doped by calcination of TiO2·xH2O under ammonia atmosphere for visible light photocatalysis

The investigation on incorporating nitrogen group into titanium dioxide in order to obtain powdered visible light-active photocatalysts is presented. The industrial hydrated amorphous titanium dioxide (TiO₂·xH₂O) obtained directly from sulphate technology installation was modified by heat treatment at temperatures of 100–800 °C for 4 h in an ammonia atmosphere. The photocatalysts were characterized by UV–VIS–DR and XRD techniques. The UV–VIS–DR spectra of the modified catalysts exhibited an additional maximum in the VIS region (, ) which may be due to the presence of nitrogen in TiO₂ structure. On the basis of XRD analysis it can be supposed that the presence of nitrogen does not have any influence on the transformation temperature of anatase to rutile. The photocatalytic activity of the modified photocatalysts was determined on the basis of decomposition rate of phenol and azo-dye (Reactive Red 198) under visible light irradiation. The highest rate of phenol degradation was obtained for catalysts calcinated at 700 °C (6.55%), and the highest rate of dye decomposition was found for catalysts calcinated at 500 and 600 °C (ca. 40–45%). The nitrogen doping during calcination under ammonia atmosphere is a very promising way of preparation of photocatalysts which could have a practical application in water treatment system under broader solar light spectrum.     

Aspects of dSpace in contemporary design

Computer dependent design space is illustrated with the recent international competition project for Kowloon Arts Center. The spatial condition of design resulted from the deployment of Euclidian geometry and use of the nonrational, complex surfaces. Another aspect of computer dependent space was rooted in the contemporary work situation where architects located on the three different continents collaborated in distributed mode over the internet. The resulting project confirms the creative potential of the above aspects of the digital space in contemporary design.