Microstructure and anodic polarization behavior of experimental Ag–18Cu–15Pd–12Au alloy in aqueous sulfide solution

The anodic corrosion behavior of an experimental Ag–15Pd–18Cu–12Au alloy in 0.1% Na₂S solution in relation to its microstructure was investigated using potentiodynamic and potentiostatic polarization techniques with analyses of corrosion products by X-ray diffractometry, Auger electron spectroscopy, and X-ray photoelectron spectroscopy. The role of Pd in improvement of the corrosion resistance was also investigated. In the potential/current density curve, three distinct current peaks, at –520 mV (peak I), –425 mV (peak II) and –175 mV (peak III), were observed. The Ag-rich ₂ matrix with coarse Cu and Pd-rich lamellae was the most corrosion-susceptible region, and this region was preferentially corroded at peak I with the formation of granular deposits of Ag₂S. A small amount of Ag–Cu mixed sulfide deposited on the Cu and Pd-rich coarse particles and dissolution of Ag as AgO^– might have occurred in parallel with Ag₂S formation at peak II. Enrichment of Pd on the alloy surface occurred at peak III due to preferential dissolution of Ag and Cu. A high level of corrosion resistance was attained with the formation of a thin Pd-rich sulfide film, which enhanced the passivity of the alloy in an alkaline sulfide solution. It was found that passivity is an important phenomenon not only for base metal alloys but also for noble metal alloys to maintain high levels of resistance to corrosion and tarnishing in sulfide environments.     

Aligned bioactive mesoporous silica coatings for implants

Ongoing research is reported aimed at preparing mesoporous silica coatings on various substrates for medical applications by a biomimetic approach (self-assembling of organic/inorganic sol-gel systems into ordered structures). Tetraethylorthosilicate (TEOS) was selected as the silica precursor, and amphiphilic triblock copolymers poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide), and the cationic surfactant cetyltrimethyl ammonium chloride (CTAC), as structure-directing agents. The mesochannels diameter could be adjusted by changing the directing agent, and a preferred alignment of the mesostructure was observed independently of the used substrate (glass, silicon, Ti or Ti6Al4V). Three different treatments (thermocalcination, photocalcination, and solvent extraction) have been also studied to remove the organic templates, of which photocalcination showed to be the most versatile. When soaked in a simulated body fluid, mesoporous silica coatings induced apatite formation after seven days.     

Inference-Based Ambiguity Management in Decentralized Decision-Making: Decentralized Control of Discrete Event Systems

Decentralized decision-making requires the interaction of various local decision-makers in order to arrive at a global decision. Limited sensing capabilities at each local site can create ambiguities in a decision-making process at each local site. We argue that such ambiguities are of differing gradations. We propose a framework for decentralized decision-making (applied to decentralized control in particular) that allows computation of such ambiguity gradations and utilizes their knowledge in arriving at a global decision. Each local decision is tagged with a certain grade or level of ambiguity, with zero being the minimum ambiguity level. A global decision is taken to be the same as a ldquowinningrdquo local decision, i.e., one having the minimum level of ambiguity. The computation of an ambiguity level for a local decision requires an assessment of the self-ambiguities as well as the ambiguities of the others, and an inference based upon such knowledge. For the existence of a decentralized supervisor, so that for each controllable event the ambiguity levels of all winning disablement or enablement decisions are bounded by some number N (such a supervisor is termed N-inferring), the notion of N-inference observability is introduced. We show that the conjunctive-and-permissive (C&P) V disjunctive-and-antipermissive (D&A) co-observability is the same as the zero-inference observability, whereas the conditional C&P V D&A co-observability is the same as the unity-inference observability. We also present examples of higher order inference-observable languages. Our framework does not require the existence of any a priori partition of the controllable events into permissive/antipermissive sets, nor does it require a global control computation based on conjunction/disjunction of local decisions, exhibiting that our ambiguity-based approach is more efficient.     

Investigation of gas-liquid interface in atmospheric-pressure micro plasma with solution

An atmospheric-pressure glow-discharge micro plasma in contact with liquid paraffin is stably generated by using a capacitively coupled plasma method with a mesh electrode. When characteristics of the plasma are measured in the boundary between the micro plasma (gas-phase) and liquid paraffin (liquid-phase) using optical emission spectroscopy, spectrum peaks of the emission of CH and C₂ which dissociate from paraffin are observed. The result indicates that solution can feed particles to the plasma at gas-liquid interface and this plasma is accordingly expected to promote an attractive plasma process for creating materials consisting of elements in various solutions.     

定向反射管束对辐照均匀性的影响

为使多孔陶瓷板燃气辐射器加热物体能量定向集中，减少向周围环境散失的热量，在辐射器的前方，设计了定向反射管束，并进行了被加热物体表面辐照度分布特性数值计算研究。利用蒙特卡罗法中的辐射分配因子计算并分析了相关参数，例如管束布置(顺排、叉排及节距)、加热距离、管间距及管长与半径比等对被加热物体表面辐照度均匀性的影响。通过计算得出定向反射管间距是影响均匀加热面积大小的主要因素，管束布置方式对辐照度均匀性影响较小；随管长与半径比增加，物体表面辐照度均匀时，对应的加热距离增加。计算结果为实际装置的优化设计提供了理论依据。     

Lateral Inhomogeneity in the Electronic Structure of a Conjugated Poly(3‐hexylthiophene) Thin Film

How annealing influences the morphology of a highly regioregular poly(3‐hexylthiophene) (RR‐P3HT) film at the substrate interface as well as the lateral inhomogeneity in the electronic structure of the film are elucidated. Whereas previous studies have reported that high‐molecular‐weight (MW) RR‐P3HT films tend to show low crystallinity even after annealing, it is found that high‐MW RR‐P3HT does show high crystallinity after annealing at high temperature for a long time. Photoemission electron microscopy (PEEM), X‐ray photoemission spectroscopy, and ultraviolet photoemission spectroscopy results clearly resolve a considerable lateral inhomogeneity in the morphology of RR‐P3HT film, which results in a variation of the electronic structure depending on the local crystallinity. The PEEM results show how annealing facilitates crystal growth in a high‐MW RR‐P3HT film.     

Design of plant safety model in plant enterprise engineering environment

Plant enterprise engineering environment (PEEE) is an approach aiming to manage the plant through its lifecycle. In such environment, safety is considered as the common objective for all activities throughout the plant lifecycle. One approach to achieve plant safety is to embed safety aspects within each function and activity within such environment. One ideal way to enable safety aspects within each automated function is through modeling. This paper proposes a theoretical approach to design plant safety model as integrated with the plant lifecycle model within such environment. Object-oriented modeling approach is used to construct the plant safety model using OO CASE tool on the basis of unified modeling language (UML). Multiple views are defined for plant objects to express static, dynamic, and functional semantics of these objects. Process safety aspects are mapped to each model element and inherited from design to operation stage, as it is naturally embedded within plant's objects. By developing and realizing the plant safety model, safer plant operation can be achieved and plant safety can be assured.     

1.8-V 800-Mb/s/pin DDR2 and 2.5-V 400-Mb/s/pin DDR1 compatibly designed 1Gb SDRAM with dual-clock input-latch scheme and hybrid multi-oxide output buffer

This paper describes three circuit techniques for a DDR1/DDR2-compatible chip architecture designed for both high-speed and high-density DRAMs: 1) a dual-clock input-latch scheme, which reduces the excessive timing margin for random input commands by using a pair of latch circuits controlled by dual-phase one-shot clock signals, achieves a 0.9-ns reduction in cycle time from 3.05 to 2.15 ns; 2) a hybrid multi-oxide output buffer reduces the area penalty of the output buffer caused by compatible chip design from 1.35% to 0.3%; and 3) a quasi-shielded distributed data transfer scheme enables a 2.6-ns reduction in access time to 10.25 ns in both 2-b and 4-b prefetch operations. By using these techniques, we developed a 175.3-mm/sup 2/ 1-Gb SDRAM that operates as an 800-Mb/s/pin DDR2 or 400-Mb/s/pin DDR1.