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31.
Formation of Tetravalent Fe Ions in LaFeO3 Perovskite Through Mechanochemical Modification by Ball Milling
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Tomoki Uchiyama Maiko Nishibori Hisahiro Einaga Yasutake Teraoka 《Journal of the American Ceramic Society》2015,98(4):1047-1051
Mechanochemical modification of previously synthesized LaFeO3 perovskite‐type oxide by a high‐energy ball milling was investigated to introduce Fe4+ ions or transform some Fe3+ into Fe4+ in LaFeO3. X‐ray absorption fine structure studies revealed that the formation of Fe4+ ions into LaFeO3 perovskite has been achieved at first time by ball milling at room temperature without any additives or replacement of La3+ ions by some divalent cations. The structural model of Fe4+ containing LaFeO3 could be described as with a modified perovskite having equal amounts of La and Fe vacancies, which is supported by a good correlation between the results of Fe K‐edge XANES spectra and O2‐TPD. The synthesis of Fe4+‐containing LaFeO3 perovskite by ball milling was able to produce the O2 adsorption capacity of nonsubstituted perovskite‐type oxide. 相似文献
32.
Munehisa Yasuniwa Shinsuke Tsubakihara Koji Iura Yoshinori Ono Yusuke Dan Kazuhisa Takahashi 《Polymer》2006,47(21):7554-7563
The crystallization behavior of poly(l-lactic acid) was studied in the range of 80-160 °C. The peak crystallization time (τp) was defined and obtained from the crystallization isotherm measured with a differential scanning calorimeter (DSC). Isothermal crystallization temperature (Tc) dependence of log(τp) discretely changed at 113 °C (= Tb). The linear growth rate of spherulite, G, was measured with a polarizing microscope. The Tc dependence of G and the size of the spherulite also discretely changed at Tb. Crystal structures for samples isothermally crystallized at temperatures which were higher and lower than Tb were orthorhombic (α-form) and trigonal (β-form), respectively. The discrete change of the crystallization behavior was explained by the formation of different crystal. 相似文献
33.
To obtain a durable Ni coating with excellent adhesion strength on an AZ91D Mg alloy, a pretreatment was performed with a small amount of Cu2+ ions added to the activation bath used in the pretreatment prior to the plating process. In the pretreatment activation process, a high density Cu layer was deposited on both the α-phase and β-phase areas of the substrate accompanied with Mg dissolution. The Cu deposit acted as nucleation seeds for the Zn deposition in the following zincate process which provided a uniform and dense Zn layer almost completely covering the substrate. Then a thin Cu layer was electroplated on this zincated substrate as an undercoating for the succeeding electroplating with Ni. Cross-sectional scanning electron microscopy observations showed that the Cu deposited by the pretreatment enabled the deposition of a protective Ni layer with few defects. This structure also contributed to the improvement of adhesion strength and corrosion resistance as compared with the non-Cu added sample. 相似文献
34.
Kaname Uno Shohei Iyoshi Masato Yoshihara Kazuhisa Kitami Kazumasa Mogi Hiroki Fujimoto Mai Sugiyama Yoshihiro Koya Yoshihiko Yamakita Akihiro Nawa Tomohiro Kanayama Hiroyuki Tomita Atsushi Enomoto Hiroaki Kajiyama 《International journal of molecular sciences》2022,23(8)
Epithelial ovarian cancer (EOC) is the most lethal gynecologic malignancy and has a unique metastatic route using ascites, known as the transcoelomic root. However, studies on ascites and contained cellular components have not yet been sufficiently clarified. In this review, we focus on the significance of accumulating ascites, contained EOC cells in the form of spheroids, and interaction with non-malignant host cells. To become resistant against anoikis, EOC cells form spheroids in ascites, where epithelial-to-mesenchymal transition stimulated by transforming growth factor-β can be a key pathway. As spheroids form, EOC cells are also gaining the ability to attach and invade the peritoneum to induce intraperitoneal metastasis, as well as resistance to conventional chemotherapy. Recently, accumulating evidence suggests that EOC spheroids in ascites are composed of not only cancer cells, but also non-malignant cells existing with higher abundance than EOC cells in ascites, including macrophages, mesothelial cells, and lymphocytes. Moreover, hetero-cellular spheroids are demonstrated to form more aggregated spheroids and have higher adhesion ability for the mesothelial layer. To improve the poor prognosis, we need to elucidate the mechanisms of spheroid formation and interactions with non-malignant cells in ascites that are a unique tumor microenvironment for EOC. 相似文献
35.
This paper describes the classification of various human actions from brain activity. In particular, we focus on grasping movements and estimate grasping patterns from electroencephalogram (EEG) data. EEG data is converted to grasping features by using a common spatial pattern filter (CSP filter), and the features are subsequently classified into grasping categories by using the k-nearest neighbor method. We tested the pipeline of feature extraction and classification on the EEG dataset. The EEG data were acquired while participants grasped an object according to the Cutkosky’s grasping taxonomy, in which grasping movements are categorized into nine power-type grasping patterns and seven precision-type grasping patterns. The best classification rate for 9-class power-type grasping patterns was 48% and for 7-class precision-type grasping patterns was 40%. 相似文献
36.
37.
Koh Matsumoto Kazutada Ikenaga Jun Yamamoto Kazuki Naito Yoshiki Yano Akinori Ubukata Hiroki Tokunaga Tadanobu Arimura Katsuaki Cho Toshiya Tabuchi Akira Yamaguchi Yasuhiro Harada Yuzaburo Ban Kousuke Uchiyama 《半导体学报》2011,32(1):21-23
Growth rate has a direct impact on the productivity of nitride LED production.Atmospheric pressure growth of GaN with a growth rate as high as 10μm/h and also Al0.1Ga0.9N growth of 1μm/h by using 4 inch by 11 production scale MOVPE are described.XRD of(002) and(102) direction was 200 arcsec and 250 arcsec, respectively.Impact of the growth rate on productivity is discussed. 相似文献
38.
39.
日本では,21世紀半ばに人工の固体物質の代表である解体コンクリート塊の排出量がピークを迎えると同時に,最終処分が困難になる状況が想定されていることから,コンクリート材料の完全資源型の利活用要求はより一層高まるといえる.本研究は,副産微粉,再生骨材などの二次副産材を積極的に混和し,同一産地*種類型の調合条件のもとで,コンクリートの物性改善,資源有効利活用を目的としたコンクリートを製造し,その基礎的物性の評価と環境影響評価を行い,環境保全に資するコンクリート材料の発展的利用のあり方を検討した. 相似文献
40.