The effect of molding conditions on mechanical and morphological properties at the interface of film insert injection molded polypropylene‐film/polypropylene matrix

An extensive study on the peel strength between a polypropylene (PP) film and PP substrate fabricated using film insert injection molding technique was carried out through a 180° peel test. Injection molding conditions such as barrel temperature, injection speed and holding pressure were varied to gauge their effects on the mechanical and morphological properties. Morphological observations were made at the film‐substrate interfacial regions by means of transmission electron microscopy (TEM). The injection molded products, with the films still attached, were subjected to bending and impact tests to determine if there is any relationship between film‐substrate adhesion and bulk properties. Observation of the load‐displacement curves during the peel test revealed three unique and interesting curves, corresponding to different peeling and film fracture mechanisms. Increases in injection speed, barrel temperature and holding pressure lead to increased bonding between the film and substrate surfaces. The enhancement of bonding between these two polymer surfaces could be attributed to polymer‐polymer interdiffusion. Substantiating evidence from TEM, which shows the fading of the interface as the bond strengthens, further boosts the accuracy of this assumption. The hope that the films could contribute to enhancing bulk properties has been diminished since the bending properties appeared to be similar with or without the film attached. Polym. Eng. Sci. 44:2327–2334, 2004. © 2004 Society of Plastics Engineers.     

Electric field calculation in composite dielectrics by surface charge method based on electric flux continuity condition

We propose a new surface charge method based on the continuity of electric flux passing through each partial area on the dielectric boundary. N partial areas divided on the boundary give the boundary equations for solving N unknown variables representing the surface charge density distribution. The electric flux is numerically calculated by integrating the normal component of electric flux density on each partial area. This method permits us to exclude the singularity of edge parts from the boundary equations because these parts do not contribute to the integration area. In this paper, we apply first‐order functions to simulate both triangular surface shape and charge density distribution on its surface as well. First, we have computed the electric field for a spherical dielectric under a uniform field. The calculated results show that the accuracy of the electric field at the spherical center is almost equal to the accuracy of the total surface area of the polygon which represents the sphere. Furthermore, this method has improved the accuracy of the field by about one order compared with the conventional surface charge methods. Second, we have computed the electric field for a dielectric human model under a uniform field. The calculated results demonstrates that the proposed method works well for a complicated shaped object with a dielectric constant greatly different from that of an ambient medium. © 2002 Scripta Technica, Electr Eng Jpn, 138(4): 10–17, 2002; DOI 10.1002/eej.1133     

TETHER-LINKED [60]FULLERENE-DONOR DYADS

A series of [60]fullerene bis-adducts having a π-electron-rich aromatic ring as a donor in a face-to-face arrangement were synthesized by the bis-cyclopropanation of [60]fullerene with tether-linked bis-malonates. One of the bis-adducts showed a photoinduced intramolecular electron transfer which caused the dramatic quenching of its fluorescence in a polar solvent.     

Effects of Particle Strength of Feedstock Powders on Properties of Warm-Sprayed WC-Co Coatings

Warm spray (WS) process, which can control the temperature of a combustion gas jet used to propel powder, has been successfully applied to deposit WC-Co coatings. Detrimental reactions resulting from dissolution of WC into Co binder and decarburization were suppressed effectively by keeping the WC-Co particles’ temperature below the m.p. of the binder phase. In this study, three nano-structured WC-12Co powders with different particle strengths were prepared by changing the sintering conditions of spray-dried powder and were deposited by WS. The deposition efficiency and porosity of the coatings decreased with increasing the particle strength. The coating deposited from the powder with very low particle strength showed significant phase changes, while those deposited from the higher particle strengths showed almost no change. Particle Image Velocimetry revealed significant disintegration of the weakest powder, which explains the changes observed. The hardness and wear properties of the former coating, therefore, were inferior to the other two.     

Improvement of thermal characteristics of latent heat thermal energy storage units using carbon-fiber brushes: experiments and modeling

Brushes made of carbon fibers with a high thermal conductivity are inserted on the shell side of a heat exchanger to enhance the conductive heat transfer rates in phase change materials. The experimental results show that the brushes essentially improve the heat exchange rate during the charge and discharge processes even when the volume fractions of the fibers are about one percent. A three-dimensional model describing the heat transfer in the heat exchanger is numerically solved. The model predicts well the experimental outlet fluid temperatures and the local temperatures in the composite.     

Modulation of nanotube formation in apatite single crystal via organic molecule incorporation

Hydroxyapatite materials are potentially useful for biomedical application, especially as vehicles for functional molecules. Structural control of bulk apatite materials, such as in the fabrication of hollow microspheres or porous structures, has been studied for this purpose. However, control of the internal structure of the source apatite crystal itself is still a challenge. Here, we show that small organic molecules incorporated in apatite crystals act as porogens which control the porous structure of apatite single crystal. The presence of amino acid under apatite synthesis conditions leads to firm bindings and encapsulation of the amino acid in apatite single crystals. Amino acid elimination by heating or electron beam irradiation enhances the pore formation in apatite single crystal. Moreover, incorporation of an acidic amino acid in apatite induces peapod like nanotubes in apatite single crystals. This study suggests the potential of using small organics for nano-structural control of apatite single crystals which would be valuable for enhancing drug loadings or modulating material digestion in vivo.     

Thin reduced graphene oxide interlayer with a conjugated block copolymer for high performance non-volatile ferroelectric polymer memory

Polymer ferroelectric-gate field effect transistors (Fe-FETs) employing ferroelectric polymer thin films as gate insulators are highly attractive as a next-generation non-volatile memory. For minimizing gate leakage current of a device which arises from electrically defective ferroelectric polymer layer in particular at low operation voltage, the materials design of interlayers between the ferroelectric insulator and gate electrode is essential. Here, we introduce a new solution-processed interlayer of conductive reduced graphene oxides (rGOs) modified with a conjugated block copolymer, poly(styrene-block-paraphenylene) (PS-b-PPP). A FeFET with a solution-processed p-type oligomeric semiconducting channel and ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE) insulator exhibited characteristic source–drain current hysteresis arising from ferroelectric polarization switching of a PVDF-TrFE insulator. Our PS-b-PPP modified rGOs (PMrGOs) with conductive moieties embedded in insulating polymer matrix not only significantly reduced the gate leakage current but also efficiently lowered operation voltage of the device. In consequence, the device showed large memory gate voltage window and high ON/OFF source–drain current ratio with excellent data retention and read/write cycle endurance. Furthermore, our PMrGOs interlayers were successfully employed to FeFETs fabricated on mechanically flexible substrates with promising non-volatile memory performance under repetitive bending deformation.     

Dynamic connection provisioning with shared protection in IP/WDM networks

Internet protocol (IP) traffic connections arrive dynamically at wavelength‐division multiplexing (WDM) network edges with low data rates compared with the wavelength capacity, availability, and quality‐of‐service (QoS) constraints. This paper introduces a scheme to be integrated into the control and management plane of IP/WDM networks to satisfy the availability and QoS required for IP traffic connections bundled onto a single wavelength (lightpath) in WDM networks protected by shared‐backup path protection (SBPP). This scheme consists of two main operations: (i) routing multi‐granular connections and traffic grooming policies, and (ii) providing appropriate shared protection on the basis of subscribers’ service‐level agreements in terms of data rate, availability, and blocking probability. Using the Markov chain process, a probabilistic approach is developed to conceive connection blocking probability models, which can quantify the blocking probability and service utilization of M:N and 1:N SBPP schemes. The proposed scheme and developed mathematical models have been evaluated in terms of bandwidth blocking ratio, availability satisfaction rate, network utilization, and connection blocking probability performance metrics. The obtained research results in this paper provide network operators an operational setting parameter, which controls the allocation of working and backup resources to dynamic IP traffic connections on the basis of their priority and data rate while satisfying their requirements in terms of bandwidth and availability. Copyright © 2013 John Wiley & Sons, Ltd.     

A Note on Incorporating Simultaneous Multi‐level Failure Time Data in System Reliability Assessments

In this article, we present a method how to evaluate the likelihood for simultaneous failure time data when monitoring is stopped when the system fails. Our method is based on the reliability structure of the system, listing all possible events consistent with the simultaneous data and calculating their contributions to the likelihood. The method is simple to understand and is based on standard probabilistic calculations. We also consider the Jackson and Mosleh 5 method, and some results suggest that the two methods are equivalent. Copyright © 2015 John Wiley & Sons, Ltd.