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71.
72.
    
Tough and self‐recoverable hydrogel membranes with micrometer‐scale thickness are promising for biomedical applications, which, however, rarely be realized due to the intrinsic brittleness of hydrogels. In this work, for the first time, by combing noncovalent DN strategy and spin‐coating method, we successfully fabricated thin (thickness: 5–100 µm), yet tough (work of extension at fracture: 105–107 J m?3) and 100% self‐recoverable hydrogel membranes with high water content (62–97 wt%) in large size (≈100 cm2). Amphiphilic triblock copolymers, which form physical gels by self‐assembly, were used for the first network. Linear polymers that physically associate with the hydrophilic midblocks of the first network, were chosen for the second network. The inter‐network associations serve as reversible sacrificial bonds that impart toughness and self‐recovery properties on the hydrogel membranes. The excellent mechanical properties of these obtained tough and thin gel membranes are comparable, or even superior to many biological membranes. The in vitro and in vivo tests show that these hydrogel membranes are biocompatible, and postoperative nonadhesive to neighboring organs. The excellent mechanical and biocompatible properties make these thin hydrogel membranes potentially suitable for use as biological or postoperative antiadhesive membranes.  相似文献   
73.
    
The modeling of particle aggregation under a simple shear flow and the extension of the model to a stirred vessel is described. The model quantitatively demonstrates the change of the number of aggregates with time for each shear rate. This number increased with higher shear rate and, conversely, the aggregate size became small when raising the shear rate. This was because aggregates were broken by the stronger shear force. The number of aggregates for different impellers was determined. The shear rate was back‐calculated from the experimentally obtained aggregate size and the model equation. This shear rate was different from that estimated from the Metzner‐Otto method, consequently, some revisions of the Metzner‐Otto equation might be necessary for its application to particle aggregation.  相似文献   
74.
    
Imprint lithography has emerged as a reliable, reproducible, and rapid method for patterning colloidal nanostructures. As a promising alternative to top-down lithographic approaches, the fabrication of nanodevices has thus become effective and straightforward. In this study, a fusion of interference lithography (IL) and nanosphere imprint lithography on various target substrates ranging from carbon film on transmission electron microscope grid to inorganic and dopable polymer semiconductor is reported. 1D plasmonic photonic crystals are printed with 75% yield on the centimeter scale using colloidal ink and an IL-produced polydimethylsiloxane stamp. Atomically smooth facet, single-crystalline, and monodisperse colloidal building blocks of gold (Au) nanoparticles are used to print 1D plasmonic grating on top of a titanium dioxide (TiO2) slab waveguide, producing waveguide-plasmon polariton modes with superior 10 nm spectral line-width. Plasmon-induced hot electrons are confirmed via two-terminal current measurements with increased photoresponsivity under guiding conditions. The fabricated hybrid structure with Au/TiO2 heterojunction enhances photocatalytic processes like degradation of methyl orange (MO) dye molecules using the generated hot electrons. This simple colloidal printing technique demonstrated on silicon, glass, Au film, and naphthalenediimide polymer thus marks an important milestone for large-scale implementation in optoelectronic devices.  相似文献   
75.
Therapeutic vascular catheterization techniques are sometimes hampered by the frictional forces between the blood vessel and the catheter, when contact points of the vessel are changing and deforming during the movement of the catheter. The goal of the present study was to characterize frictional interactions between the blood vessel wall and the catheter using experimental and numerical analysis. First, the frictional force was measured with an experimental apparatus that uses a ball and flattened porcine aorta to simulate frictional forces between the catheter and the vessel. Second, catheter motion was characterized by two-dimensional numerical calculations based on the experimental results. Experimental analysis demonstrated that slip occurred and that friction coefficient between the vessel and the catheter and the deformation of the specimen were small when the contact between the ball and the aorta occurred at a small angle. The compliance of the specimen in the normal direction obtained by the experiment was by far larger than that calculated according to the Hertzian contact theory. Numerical analysis shows that this difference of the parameter of the vessel, which must be determined accurately in surgical simulator, could affect the trajectory of the catheter.  相似文献   
76.
    
Warm spray (WS) process, which can control the temperature of a combustion gas jet used to propel powder, has been successfully applied to deposit WC-Co coatings. Detrimental reactions resulting from dissolution of WC into Co binder and decarburization were suppressed effectively by keeping the WC-Co particles’ temperature below the m.p. of the binder phase. In this study, three nano-structured WC-12Co powders with different particle strengths were prepared by changing the sintering conditions of spray-dried powder and were deposited by WS. The deposition efficiency and porosity of the coatings decreased with increasing the particle strength. The coating deposited from the powder with very low particle strength showed significant phase changes, while those deposited from the higher particle strengths showed almost no change. Particle Image Velocimetry revealed significant disintegration of the weakest powder, which explains the changes observed. The hardness and wear properties of the former coating, therefore, were inferior to the other two.  相似文献   
77.
In this study, homogenized elastic-viscoplastic behavior of an ultra-fine plate-fin structure fabricated for compact heat exchangers is investigated. First, the homogenized behavior is numerically analyzed using a fully implicit mathematical homogenization scheme of periodic elastic-inelastic solids. A power-law creep relation is assumed to represent the viscoplasticity of base metals at high temperatures. The plate-fin structure is thus shown to exhibit significant anisotropy as well as noticeable compressibility in both the elastic and viscoplastic ranges of the homogenized behavior. Second, a non-linear rate-dependent macroscopic constitutive model is developed using the quadratic yield function proposed for anisotropic compressible plasticity. The resulting constitutive model is shown to be successful for simulating the anisotropy, compressibility, and rate dependency in the homogenized behavior in multi-axial stress states.  相似文献   
78.
79.
To determine all of the components of in situ stress from core discing, both the directions and magnitudes of the principal in situ stresses must be determined for a disc of a given thickness. In this study, we analyzed the direction and magnitude of tensile stress below an HQ core stub for 11 core lengths using stress conditions under which core discing is likely to occur. First, based on an analysis of the direction of tensile stress below the core stub, we propose a method for determining directions of in situ stress from the height distribution at the periphery of the end surface of a disc. This method can be used with a disc of any thickness. Next, based on an analysis of the magnitude of tensile stress in the central part of a core, we propose a linear criterion for core discing, which can be applied to a core of any length. This criterion was in good agreement with an empirical formula obtained previously in laboratory experiments. By combining information on the direction of in situ stress and the linear criterion for core discing, we propose a method for determining all of the components of in situ stress from core discing under the assumption that vertical stress is given by the overburden stress. Finally, these methods were applied to discs obtained from a field where hydraulic fracturing was performed to measure horizontal stresses. The results showed that the azimuths of the principal stresses estimated from core discing were consistent with those of the principal horizontal stresses determined by hydraulic fracturing and that while the magnitudes of the principal horizontal stresses estimated from core discing showed a large scatter, they were similar to those determined by hydraulic fracturing.  相似文献   
80.
The design and fabrication of an 8-ch, 500 GHz-spacing arrayed waveguide grating on (Pb,La)(Zr,Ti)O3 has been successfully achieved for the first time. An insertion loss of 22.1 dB, including a 10 dB coupling loss, and an adjacent crosstalk of -23.1 dB have been obtained. The device is expected to be monolithically integrated into high-speed optical switches to form integrated chips such as a reconfigurable add-drop multiplexer  相似文献   
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