全文获取类型
收费全文 | 664篇 |
免费 | 32篇 |
国内免费 | 4篇 |
专业分类
电工技术 | 43篇 |
综合类 | 3篇 |
化学工业 | 183篇 |
金属工艺 | 18篇 |
机械仪表 | 11篇 |
建筑科学 | 15篇 |
能源动力 | 27篇 |
轻工业 | 60篇 |
水利工程 | 5篇 |
无线电 | 51篇 |
一般工业技术 | 138篇 |
冶金工业 | 52篇 |
原子能技术 | 38篇 |
自动化技术 | 56篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 8篇 |
2021年 | 16篇 |
2020年 | 11篇 |
2019年 | 12篇 |
2018年 | 14篇 |
2017年 | 12篇 |
2016年 | 23篇 |
2015年 | 19篇 |
2014年 | 26篇 |
2013年 | 40篇 |
2012年 | 36篇 |
2011年 | 78篇 |
2010年 | 38篇 |
2009年 | 38篇 |
2008年 | 39篇 |
2007年 | 32篇 |
2006年 | 21篇 |
2005年 | 22篇 |
2004年 | 19篇 |
2003年 | 18篇 |
2002年 | 16篇 |
2001年 | 11篇 |
2000年 | 12篇 |
1999年 | 19篇 |
1998年 | 19篇 |
1997年 | 15篇 |
1996年 | 11篇 |
1995年 | 6篇 |
1994年 | 7篇 |
1993年 | 9篇 |
1992年 | 3篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 4篇 |
1983年 | 6篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 3篇 |
排序方式: 共有700条查询结果,搜索用时 15 毫秒
61.
62.
63.
It has been shown that the films of a soluble conjugated polymer poly[(9,9-dioctyl-2,7-divinylene fluorenylene)-alt-{2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene}] for electronic devices can be prepared by the electrophoretic deposition with polymer suspensions derived from dilute polymer solutions which are so dilute that the conventional spin-coating technique is not applicable. For example, a 100 nm-thick film can be prepared on an indium-tin-oxide (ITO) electrode from a suspension from solution containing 0.1 g/l of the polymer. The thickness of the polymer film deposited is found to be almost proportional to the concentration of the polymer, and the linearity down to 5.0 × 10?3 g/l is confirmed. On the other hand, it has been found that coating the ITO electrode with poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) salt results in low and nonlinear deposition rate. 相似文献
64.
Kazuya Aida Yasuhiko Benino Vesselin Dimitrov Takayuki Komatsu Ryuji Sato 《Journal of the American Ceramic Society》2000,83(5):1192-1198
The kinetics of enthalpy relaxation (recovery) at the glass transition in x K2 O·(20− x )MgO·80TeO2 glasses has been examined from heat capacity measurements using differential scanning calorimetry to clarify the features of the structural relaxation in ternary TeO2 -based glasses. Ternary glasses such as 10K2 O·10MgO·80TeO2 show high thermal resistance against crystallization compared with binary glasses. The degree of fragility m estimated from the activation energy for viscous flow E η and the glass transition temperature T g is m = 55–62, indicating a fragile character in TeO2 -based glasses. Large heat capacity changes of 43.1–48.2 J·mol−1 ·K−1 are also observed at the glass transition. The activation energy for enthalpy relaxation Δ H is evaluated from the cooling rate dependence of the limiting fictive temperature, and values of Δ H = 897–1268 kJ·mol−1 are obtained. Negative deviation from additivity in Δ H is also observed. Values of the Kovacs–Aklonis–Huchinson–Ramos (KAHR) parameter θ estimated from Δ H and T g are 0.33–0.42 K−1 . It has been proposed that ternary glasses have more homogeneous and constrained glass structure compared with binary glasses. 相似文献
65.
3,4‐Dihydrocoumarin (DHCM) is an aromatic six‐membered lactone, which does not undergo anionic homopolymerization. However, it does undergo copolymerization with an epoxide. The striking feature of this copolymerization is its 1:1 alternating nature, which allows for the formation of polyesters. In this mini‐review, we describe the copolymerization behavior, the polymer structure and the advantages that can be achieved by addition of DHCM to the epoxy‐imidazole curing system. Another focus is our development of DHCM analogues, which bring the advantages of DHCM to their applications as comonomers for the curing system. Copyright © 2009 Society of Chemical Industry 相似文献
66.
67.
68.
Masayuki Nonaka Hiroaki Matsushima Kazuhiro Endoh Kazuya Matsuo Kazuo Fujibayashi 《亚洲传热研究》2002,31(8):626-638
R22 (HCFC22) has been widely used as the refrigerant in air conditioners. According to the Montreal protocol for ozone layer protection, the total production of HCFCs has been capped since the beginning of 1996. Zeotropic refrigerant mixture R407C and nearly azeotropic refrigerant mixture R410A have been selected as alternatives to R22. We examined refrigerant passages in heat exchangers used in heat pump‐type room air conditioners using zeotropic refrigerant R407C through simulation, and obtained the following conclusions. In an indoor heat exchanger, a counter flow configuration when operating as a condenser has higher temperature efficiency. When an outdoor heat exchanger operates as an evaporator, a configuration that suppresses the temperature glide by partially reducing the refrigerant passage not only produces high efficiency, but also reduces the frost formation on fins. © 2002 Wiley Periodicals, Inc. Heat Trans Asian Res, 31(8): 626–638, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.10064 相似文献
69.
The morphology of composite films consisting of conjugated polymers and C60 prepared by electrophoretic deposition (EPD) has been studied. While C60 exists as nanocrystals uniformly embedded in the composite films based on poly[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylene vinylene], a spontaneous stratification of the composite films into polymer-C60-mixture and C60-microcrystal layers is observed in the films based on a polyfluorene derivative, poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt-{2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene}]. The results suggest that EPD can be a useful tool for controlling the morphology of bulk heterojunction systems for organic photocells. 相似文献
70.
Kazuya Nakata Keizo Udagawa Tsuyoshi Ochiai Hideki Sakai Taketoshi Murakami Masahiko Abe Akira Fujishima 《Materials Chemistry and Physics》2011
TiO2-polydimethylsiloxane (TiO2-PDMS) composite films are prepared using the sol–gel method from a Ti(OBu)4–benzoylacetone solution containing PDMS. The prepared films are cured by irradiation with ultraviolet (UV) light. Structural changes in the films after UV irradiation are confirmed by UV–vis absorption experiments, which show that an absorption band characteristic of the benzoylacetonate chelate rings disappears. This finding is ascribed to structural changes associated with the dissociation of the chelate rings. The IR spectra of the thin films exhibit a broad absorption band after UV irradiation, indicating that a Ti–O–Ti network forms in the thin film. Contact angles are measured for the TiO2-PDMS thin films, showing wettability conversion from hydrophobic to superhydrophilic states by irradiation with oxygen plasma for 1 s. This phenomenon is explained by XPS experiments which reveal that the number of carbon atoms decreases, whereas the number of oxygen atoms increases on the surface of the TiO2-PDMS composite films. Finally, hydrophobic–superhydrophilic patterns are fabricated based on a patterned TiO2-PDMS composite film. The film displays a rapid change to superhydrophilicity over the whole film surface upon plasma irradiation for 1 s, which means that the wettability patterns are rapidly erasable. 相似文献