Characteristics of multistage column crystallizer for gas-liquid reactive crystallization of calcium carbonate

Crystallization of calcium carbonate using a gas (CO₂)-liquid (Ca(OH)₂) reaction was conducted using a three-stage column crystallizer. In this study, the staging effect of the multistage column crystallizer and the effect of the operating parameters on the particle size distribution were experimentally and theoretically investigated. From an economic viewpoint, the multistage column crystallizer has been developed to replace a cascade of MSMPR crystallizers, which requires a large installation area and high operating cost because some crystallizers are connected in a series. In the multistage column crystallizer, a narrower particle size distribution was obtained compared to that obtained in the standard column crystallizer. The theoretical approach to predict the particle size distribution is based on the population balance equation which takes account of the back flow into the crystallizer. The calculation results of particle size distribution fairly coincide with the experimental results, which indicates the particle size distribution in the multistage column crystallizer can be roughly predicted by this theoretical model.     

Efficient construction of cDNA microarrays utilizing normalized cDNA libraries of Arabidopsis thaliana

We have demonstrated the utility of normalization for efficient cDNA microarray preparation using Arabidopsis as a model. Nonredundant cDNAs including 5722 species were efficiently collected from random 7914 expressed sequence tags (ESTs) in four normalized cDNA libraries. The prepared microarrays were successfully used to monitor gene expression. These methodologies should be applicable to the study of other species in plant biotechnology.     

Analysis of main pigments and other ingredients in lac color product

The contents of the main pigments and other ingredients in commercial lac color products were determined by HPLC using an RP-18 column with 0.1 mol/L citric acid buffer solution-methanol (16:5) as the mobile phase, and a photodiode array (PDA) detector set at 280 nm and 490 nm. The main pigments were confirmed by PDA and electrospray ionization mass spectrometry. Laccaic acids A, B, C and E were detected in all lac color products, and the ratio of content of laccaic acid A in all products was over 50%. The total contents of laccaic acids A, B and C in lac color food additive products and reagent products were 775-858, 797 and 779 g/kg, respectively. As for the contents of ingredients except pigments in commercial food additive products, the maximum moisture content was about 10%, and ether-soluble substances amounted to 0.5-3.6%.     

Mask design compensation for sloped sidewall structures fabricated by X-ray lithography

We have investigated and report in this paper the factors influencing the deformation caused by the dependence between the absorbed X-ray energy on the resist and the shape of the absorber on the X-ray mask. Based on the measurement of errors that occurred during the transferring process between the 2-D shape of mask pattern and the resulting wall of the fabricated 3-D structure, we have developed newly useful graphical data on the absorbed X-ray energy, dosage, and shape of a microstructure. As a result, it is being reported as a method for compensation for the deformed shape after the fabrication of a quadruplets-microneedle. We have considered a number of factors affecting the deformation and finally realized that the effect of a dose–depth nonlinear curve is the most possible cause. Without the compensation of the mask design, we could observe the deformed shapes of the sloped sidewall on the exposed structures. Polymethylmethacrylate microneedle structures fabricated by X-ray lithography with an additional plane-pattern to cross-section transfers technique are directly influenced by the absorber on the X-ray mask pattern. The sidewall of the microneedle was improved by changing the mask pattern from a double right-triangular pattern to a double semi-circular pattern, modeled by comparing the results from a mask-pattern and the actual structure.     

A multilevel PWM strategy suitable for high‐voltage motor direct drive systems with consideration of the adverse effect of dead time

Recently, high‐voltage motor direct drive systems have been put to practical use, and various multilevel PWM strategies have also been proposed. This paper describes a multilevel PWM strategy [our group calls it the Carrier Phase Selection Method (CPS)] that has the lowest line voltage harmonic distortion in order to prevent the degradation of high‐voltage motor winding insulations. This method takes the adverse effect of dead time into consideration, and it controls the shift direction of a carrier phase. Therefore, a favorable output waveform without instantaneous voltage surges is achieved even if the line voltage level changes. Moreover, the switching transitions across all switching devices are well‐balanced, so the utilization of inverter unit cells is equalized. This is an important factor when designing the entire system. Based on simulation and experimental results, it is shown that this CPS method is particularly effective in high‐voltage motor direct drive systems. © 2008 Wiley Periodicals, Inc. Electr Eng Jpn, 165(2): 77–88, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20474     

Morphology of nanoholes formed in silicon by wet etching in solutions containing HF and H2O2 at different concentrations using silver nanoparticles as catalysts

Holes with diameters of tens of nanometers were bored in Si(1 0 0) in aqueous solutions containing hydrofluoric acid and hydrogen peroxide utilizing silver nanoparticles as catalysts. The holes grew deeply in the [1 0 0] direction when the concentration of hydrogen peroxide was about 0.18 M. In addition to these vertical holes, holes were generated horizontal to the surface in the 〈1 0 0〉 directions near the surface of the sample. We found that the silver particles making the deep holes in the [1 0 0] direction were more spherical than those making the horizontal holes near the surface. These results indicate that the shape of the silver particles is an important factor controlling the direction of the holes. When the hydrogen peroxide concentration was increased to 1.8 M, as well as the vertical and horizontal holes, a microporous layer was formed on the top surface region. On the other hand, when the hydrogen peroxide concentration was lowered to 0.0018 M, holes did not show any preference for growing direction and were crooked. Even in HF solutions that did not contain hydrogen peroxide, holes were generated at a very slow rate in random directions if the solutions contained oxygen.     

Direct observation of internal structure in spray-dried yttria-doped zirconia granule

Spray-dried yttria-doped zirconia granules were made transparent by immersion in a liquid and the internal structure was characterized using an optical microscope. This unique technique was found to be applicable for this system by using an immersion liquid with appropriate refractive index, and it enabled observation of the internal structure to be made over the entire volume of granules, in clear contrast to conventional SEM observation. Distinct features, which were considered to be agglomerates, were found in the granules. This was supported by SEM observation.     

Microstructure Control of Sintered Porous Yttria-Stabilized Zirconia as a Durable Thermal Shielding Material

The microstructure of a thermal shielding material affects its thermal conductivity and mechanical property. In this study, the effects of the sintering temperature and the polymethyl methacrylate powder as a pore-former on the microstructure of a sintered porous yttria-stabilized zirconia (YSZ), which is used as a durable thermal shielding material, were investigated. It became clear that the microstructure of the sintered YSZ could be controlled by the particle size and the amount of the pore-former and the sintering temperature. The effect of the yttria amount in the YSZ on the microstructure was also clarified.