Surface potential measurement of organic photo-diode consisting of fullerene/copper phthalocyanine double layered device

We investigated the surface potential built across the electrode/fullerene (C₆₀) or copper phthalocyanine (CuPc) interface and C₆₀/CuPc interface as a function of the thickness of the semiconductor film in the dark condition and under illumination. The surface potential of C₆₀ on Au, Al and Mg changes negatively with the increment of film thickness and it saturates at − 0.25, − 1.0 and − 1.5 V within 20 nm. The Fermi level alignment at C₆₀/electrode interface is established within ∼ 20 nm from electrode, and very high electric field exists due to the displacement of negative electronic charges from electrode into C₆₀. On the other hand, the surface potential of CuPc on ITO changes to + 0.1 V, and the work functions of C₆₀ and CuPc were estimated as 5.0 eV and 4.7 eV. C₆₀ film also accepts electrons from CuPc at hetero-junction interface, and the Fermi-level alignment was again obtained at C₆₀/CuPc interface under illumination. The built-in potential of ca. 0.3 V formed at C₆₀/CuPc interface was considered as the origin of the reduction of open-circuit voltage in ITO/CuPc/C₆₀/Au device compared with the optimum value of 0.6 V. On the other hand, the very high electric field formed at C₆₀/Mg contact improved the photovoltaic properties.     

A multiscale simulation of polymer processing using parameter-based bridging in melt rheology

To investigate the effect of molecular structure on macroscopic flow behavior of polymeric liquid, attempts have been made to embed the microscopic information into the flow simulation. Constitutive equation based on the theory of polymer dynamics is ideal but the theory is still under development. The CONNFFESSIT approach (where microscopic simulation is embedded into calculation grid in macroscopic simulation) is another promising direction but the computational cost is not practical yet. In this study, we propose another simple method using parameter-based bridging where the parameters for phenomenological constitutive equations in macroscopic flow simulation are obtained from coarse-grained molecular simulation. As an example, we performed a simulation of injection molding and examined the effect of molecular weight on warpage of the molded product. We used the primitive chain network simulation to calculate linear viscoelasticity of linear monodispersed polystyrenes from molecular weight. The obtained linear viscoelasticity was converted into the relaxation spectrum and into the flow curve to be used in the macroscopic simulations. From the flow curve, the parameters of an inelastic non-Newtonian constitutive equation were obtained and used for the simulation of filling process. The relaxation spectrum was used to calculate residual stress from the flow profile in the filling process. From the residual stress and thermal shrinkage, warpage of the product was obtained. For the examined thin plate product, significant change in the warpage direction was demonstrated according to the molecular weight of the material. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Dietary supplementation of gamma-linolenic acid improves skin parameters in subjects with dry skin and mild atopic dermatitis

Disruption of the skin barrier function caused by epidermal hyper-proliferation, results in the skin becoming dry and showing high transepidermal water loss (TEWL). Gamma linolenic acid (GLA) is reportedly efficacious for treating TEWL and epidermal hyper-proliferation. In this study, to elucidate the effect of GLA-rich oil on skin function, GLA-containing food was given to adults with dry skin or mild atopic dermatitis and skin parameters were evaluated. In the results, we recognized beneficial effects on the TEWL index. The efficacy of GLA was also demonstrated to be statistically significant especially in subjects with pro-inflammatory features. The results suggest that the mechanism of improvement of skin barrier has been associated with possible generation of anti-inflammatory metabolites from GLA. The clinical physician also confirmed that none of the subjects showed any noteworthy side effects. GLA-enriched food appears to be safe and to improve skin barrier function in subjects with dry skin conditions and mild atopic dermatitis.     

Polymer electrolyte membrane with nanomatrix channel prepared by sulfonation of natural rubber grafted with polystyrene

High‐proton‐conductive polymer electrolyte with a nanomatrix channel was prepared by graft copolymerization of styrene onto deproteinized natural rubber followed by sulfonation with chlorosulfonic acid. First, natural rubber latex was purified with urea in the presence of surfactant to remove almost all proteins present in the rubber. Second, graft copolymerization of styrene onto deproteinized natural rubber was carried out with tert‐butyl hydroperoxide/tetraethylenepentamine as an initiator at 30°C in latex stage. The graft‐copolymerized natural rubber (DPNR‐graft‐PS) was sulfonated with chlorosulfonic acid in chloroform solution at an ambient temperature. The resulting sulfonated DPNR‐graft‐PS was characterized by FTIR spectroscopy, solid state ¹³C CP/MAS NMR spectroscopy, elemental analysis, and transmission electron microscopy. High proton conductivity of about 0.1 S/cm, less water uptake of 24 wt % and comparatively good stress at break of 9 MPa were accomplished at suitable contents of styrene units and sulfur, i.e., 32 wt % and 75 mol %, respectively. The high proton conductivity, excellent stability, and good mechanical properties were associated with not only the formation of the nanomatrix channel but also a specific concentration of sulfuric acid group. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011.     

Evaporation rate effect on starting point of shrinkage stress development during drying process in solvent cast polymer film

To reveal the effect of drying conditions on shrinkage stress existing between a film and a substrate, a polystyrene/toluene solution was coated on a glass substrate, and the volume fraction of toluene at the time when the stress starts to grow (?_S) was measured at various drying temperatures and evaporation rates. ?_S decreased with increase of drying temperature at a constant evaporation rate, while ?_S increased with increase of evaporation rate at a constant drying temperature. From these results, it was suggested that the dominant factors affecting the starting point of stress were both the chain mobility and the measurement time‐scale. Considering the two factors, the tendency of ?_S with the drying conditions is quite similar to that of the solvent content at glass transition point, and this fact indicates a strong correlation between the starting point of stress and the glass transition of coated solution. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Confocal laser scanning microscopic analysis of ectopic sublingual gland‐like tissue inside the hamster submandibular gland

Based on its histochemical properties, the secretory portion of the hamster submandibular gland has been classified as seromucous cells. The presence of endogenous peroxidase (PO) reaction was shown in the nuclear envelope, cisternae of endoplasmic reticulum and Golgi apparatus. The 3,3′‐diaminobenzidene, tetrahydrochloride (DAB) method revealed bipartite secretory granules containing a PO‐positive dense core surrounded by a less dense halo in these cells. In the present investigation, serous and mucous‐like cells were found in resin‐embedded semi‐thin sections of the DAB‐reacted hamster submandibular gland. These sections were already on glass slides for routine light microscopic observations, therefore electron microscopic analysis could be unrealizable. We then used reflectance‐mode confocal laser scanning microscopy to visualize additional sites of PO activity as detected in these sections. Using this approach, we found mucous cells with PO activity‐negative secretory granules and seromucous cells with PO activity‐positive spot‐like secretory granules of the regular sublingual gland most frequently adjacent to the serous cells with typical electron‐dense secretory granules. These cells clearly differ from the seromucous cells with bipartite secretory granules and the granular duct cells with typical electron‐dense secretory granules of the hamster submandibular gland. Additionally, secretory endpieces of the ectopic sublingual gland‐like tissue empty into the duct of the hamster submandibular gland lobule. Thus, our findings suggest that a mass of sublingual gland tissue extends into the hamster submandibular gland during its development, and PO may be synthesized and secreted into the same duct. Microsc. Res. Tech. 76:1284–1291, 2013. © 2013 Wiley Periodicals, Inc.     

Quantitative evaluation of impedance perception characteristics of humans in the man-machine interface

We investigated impedance perception characteristics of humans in the man-machine interface. Sensibility or operational feel about physical properties of machine dynamics is obtained through perception process. We evaluated the impedance perception characteristics of humans who are operating a mechanical system, based on extended Scheffe’s subjective evaluation method in full consideration of the influence of impedance level, impedance difference, experiment order, individual difference and so on. Constant method based quantitative evaluation was adopted to investigate the influence of motion frequency and change of the impedance on human impedance perception characteristics. Experimental results indicate that humans perceive impedance of mechanical systems based on comparison process of the dynamical characteristics of the systems. The proposed method can be applied to quantify the design requirement of man-machine interface. The effectiveness of the proposed method is verified through experimental results.     

CeO2–ZrO2 Solid Solution Catalyst for Selective Synthesis of Dimethyl Carbonate from Methanol and Carbon Dioxide

CeO₂–ZrO₂ solid solution catalysts are very effective for the selective synthesis of dimethyl carbonate from methanol and CO₂. The activity was much dependent on the calcination temperature. The higher the calcination temperature, the higher the activity of the catalyst for DMC formation, though the BET surface area is lower on the catalyst calcined at higher temperature.     

Construction of an expression system of insect lysozyme lacking thermal stability: the effect of selection of signal sequence on level of expression in the Pichia pastoris expression system

Expression systems of human and silkworm lysozymes were constructedusing the methylotrophic yeast Pichia pastoris as a host. Theleader sequence and its prepro peptide of