不锈钢在扭转/拉伸复合载荷下近门槛值的疲劳裂纹扩展行为

研究了带环状预裂纹的奥氏体不锈钢圆棒试样在循环扭转／拉伸复合载荷下,门槛值附近的疲劳裂纹扩展行为,分析了复合加载时不同载荷比对裂纹扩展的影响,对裂纹扩展的初始阶段进行了详细研究,用应力强度因子表征了裂纹扩展开始的门槛值．提出了椭圆方程表达的疲劳裂纹扩展开始的门槛值模型,该方程可在裂纹尖端位移准则的基础上导出．疲劳裂纹扩展停止的门槛值条件也可用椭圆方程表达．     

Direct and Indirect Exciton Dynamics in Few‐Layered ReS2 Revealed by Photoluminescence and Pump‐Probe Spectroscopy

Atomically thin‐layered ReS₂ with a distorted 1T structure has attracted attention because of its intriguing optical and electronic properties. Here, the direct and indirect exciton dynamics of a three‐layered ReS₂ is investigated by polarization‐resolved transient photoluminescence (PL) and ultrafast pump‐probe spectroscopy. The various time scales of the decay signals of the time‐resolved PL (<10 ps), with monitoring of the populations of electron–hole pairs (exciton), and the transient differential reflectance (≈1 and 100 ps), with monitoring of the populations of electrons and/or holes in the excited states, are observed. These results reveal the characteristic exciton dynamics: rapid relaxation of direct excitons (electron–hole pairs) and slow relaxation of the momentum‐mismatched indirect excitons accompanied by a one‐phonon emission process. These findings provide important information regarding the indirect bandgap nature of few‐layered ReS₂ and its characteristic exciton dynamics, boosting the understanding of the novel electronic and optical properties of atomically thin‐layered ReS₂.     

Low-Noise and High-Frequency Resolution Electrooptic Sensing of RF Near-Fields Using an External Optical Modulator

We developed an electrooptic (EO) sensing system using an external optical intensity modulator for radio frequency (RF) electric near-field measurements. This low-noise, high-frequency resolution system is based on the photonic heterodyning technique in which a RF near-field signal is mixed with modulated light by an EO crystal and downconverted to the difference frequency. Because the optical modulator has a bandwidth extending from DC to several gigahertz, the frequency resolution of this system is determined by that of the RF synthesizer it uses. The intensity noise of the modulated light is quite low, and the noise level of the EO signal can be reduced to almost the shot-noise level by using a balanced detection scheme.     

Chirp and stability of mode-locked semiconductor lasers

A numerical study of mode-locked semiconductor lasers is presented with special attention to the chirp characteristics and to dispersion-related criteria for stable pulse-train emission. The dependence of the pulse chirp upon the refractive-index change, both with carrier density and carrier temperature changes, is discussed. The experimental observation of blue-chirped pulses for passive mode-locking in contrast to red-chirped pulses for active mode-locking is found to be due to the different contributions of gain and absorber media to the refractive-index change. In addition, it is revealed that the boundary of the stable operation regime is critically influenced by the spectral characteristics of laser and external cavity. Design considerations toward the achievement of high pulse energy, narrow spectral bandwidth, and linear chirp are given     

Quantum Transport Simulation of Silicon-Nanowire Transistors Based on Direct Solution Approach of the Wigner Transport Equation

In this paper, we present a self-consistent and 3D quantum simulator for Si-nanowire transistors based on the Wigner function model and multidimensional Schrodinger-Poisson algorithm. To achieve a sufficient numerical accuracy for calculating subthreshold current, we introduced a third-order differencing scheme for discretizing the drift term in the Wigner transport equation. By comparing with semiclassical Boltzmann and nonequilibrium Green's function approaches, the validity of the present simulator is confirmed. We also demonstrate that the source-drain tunneling is a critical physical phenomenon related to a scaling limit of nanowire devices, and the semiclassical simulation measurably underestimates a minimum gate length.     

Ion beam induced luminescence of polyethylene terephthalate foils under MeV H and He ion bombardment

The evolution of the ion beam induced luminescence (IBIL) of the polyethylene terephthalate (PET) foils was studied under the irradiation of H and He ions of MeV energy. The optical and chemical changes of the samples were also examined by photo-stimulated luminescence and optical absorption measurements after the irradiation. A prominent broad emission peak of IBIL appeared at around 380 nm, and its intensity monotonically decreased during the ion irradiation. The decay curves of the emission intensity were quantitatively explained as a function of the electronic energy deposition of the incident H and He ions. On the contrary, to the decrease of the main emission peak, a growth of new peaks was observed in the wavelengths between 500 and 600 nm.     

Mixing speed-controlled gold nanoparticle synthesis with pulsed mixing microfluidic system

Gold nanoparticles with diameters of a few tens of nanometer and a narrow size distribution were synthesized using a pulsed mixing method with a microfluidic system which consists of a Y-shaped mixing microchannel and two piezoelectric valveless micropumps. This mixing method enables control of the mixing speed of gold salts and reducing agent by changing the switching frequency of the micropumps, which was our focus to improve the particle size distribution, which is an essential parameter in gold nanoparticle synthesis. In the proposed method, the mixing time was inversely proportional to the switching frequency and the minimum mixing time was 95 ms at a switching frequency of 200 Hz. During synthesis experiments, the mean diameter of the synthesized gold nanoparticles was found to increase, and the coefficient of variation of particle size was found to decrease with decreasing mixing time. We successfully improved the coefficient of variation to less than 10% for a mean diameter of around 40 nm.     

Germanium recovery using polyphenol microspheres prepared by horseradish peroxidase reaction

BACKGROUND: The formation of polyphenol microspheres by the polymerization of 3‐methylcatechol was performed in a methanol/phosphate buffer solution using horseradish peroxidase (HRP), without the use of a surfactant or a water/oil interface, to be used for germanium recovery. RESULTS: The polyphenol microspheres were of diameter 1 mm. The functional group density of phenol group in the polymer was approximately 15 mol kg^?1 determined by the Folin‐Denis method. In batchwise experiments, the amount of germanium adsorbed was 0.23 mol kg^?1. CONCLUSION: Because germanium is a rare metal, a system for its recovery is required. Using the proposed system, continuous recovery of germanium can be achieved using multilayered microspheres. Copyright © 2011 Society of Chemical Industry     

Synthesis of charge transporting block copolymers containing 2,7-dimethoxycarbazole units for light emitting device

The block copolymers consisting of 2,7-dimethoxycarbazole- and oxadiazole-containing segments as hole and electron transporting units, respectively, were synthesized by NMRP manner. OLED devices were fabricated using block copolymer, random copolymer, and polymer blend for matrix of the emitting layer with Ir(ppy)₃ as a phosphorescent dopant in order to investigate morphological effect on the performance. From the finding that the block copolymer system overwhelmed the others in EQE, we assumed that a morphology with dimethoxycarbazole units assembled to the surface of PEDOT:PSS played a considerable role for effective recombination of charges as well as sufficient charge injection into the emitting layer.