First-Principles Calculations on Structure,Elastic and Thermodynamic Properties of Al2X （X=Sc,Y） under Pressure

To understand deeply the structural,elastic and thermodynamic characteristics of Al 2 X (X= Sc,Y) compounds in C15 type (space number 227) Cu 2 Mg structure,we have performed ab-initio density functional theory within the local density approximation (LDA) and the generalized gradient approximation (GGA).The thermodynamic properties of the considered structures are obtained through the quasi-harmonic Debye model.We have presented the results on the basic physical parameters,such as the lattice constant,bulk modulus,pressure derivative of bulk modulus,second-order elastic constants,Zener anisotropy factor,Poisson s ratio,Young s modulus,and isotropic shear modulus.In order to gain further information,the pressure-and temperature-dependent behaviour of the volume,bulk modulus,thermal expansion coefficient,heat capacity,entropy,Debye temperature and Gru¨neisen parameter were also evaluated over a pressure range of 0-20 GPa for Al 2 Sc and 0-17 GPa for Al 2 Y compound and a wide temperature range of 0-2000 K for both compounds.The obtained results were compared with the other reported values.     

A taxonomy and evaluation for developing 802.11‐based wireless mesh network testbeds

The definition of wireless mesh networks (WMNs) has been used in the literature to connote and epitomize the ideal, ubiquitous, pervasive, and autonomic networking technology. An increasing interest has been emerging on the development of 802.11‐based WMN testbeds to test the new ideas and approaches more realistically as opposed to relying solely on simulations. Although the developed testbeds have provided several insights to researchers for furthering the technology, there are still several issues that need to be addressed, particularly, with the approval of new standards, such as IEEE 802.11s, IEEE 802.11n, and IEEE 802.16, and upcoming protocols, such as IEEE 802.11ac, 802.11ad, 802.11ah, and 802.11af TV White Space efforts. In this paper, our goal is to provide a taxonomy and insightful guidelines for the creation of 802.11‐based WMN testbeds as well as to identify several features that future WMN testbeds should possess. Utilizing these features, we evaluate the existing WMN testbeds. Finally, in addition to the existing WMN testbed experiments conducted at several layers of the protocol stack, we provide a list of open future research issues that can benefit from experiments on WMN testbeds. Copyright © 2011 John Wiley & Sons, Ltd.     

Extended sliding frame R-Aloha: Medium access control (MAC) protocol for mobile networks

Proliferation of mobile communication devices necessitates a reliable and efficient medium access control (MAC) protocol. In this paper, A MAC protocol, called extended sliding frame reservation Aloha (ESFRA), based on sliding frame R-Aloha (SFRA) is proposed for network access technique. ESFRA is particularly designed to solve the mobile hidden station (MHS) problem in a mobile ad hoc network (MANET) by including relative locations of transmitting stations in the packet frame information header. The MHS problem is unique in mobile networks and occurs if a mobile station enters in a collision free zone of any ongoing communication and disturbs this communication with its transmission. In addition to the MHS problem, ESFRA simultaneously solves hidden station, exposed station, and neighborhood capture problems typically observed in wireless networks. A Markov model of ESFRA is developed and provided here to estimate throughput, delay and collision probabilities of the proposed protocol. The Markov modeling is extended to the analysis of SFRA and IEEE 802.11 to compare these competing MAC protocols with ESFRA. The analysis shows that ESFRA decreases frame transmission delay, increases throughput, and reduces collision probabilities compared to IEEE 802.11 and SFRA. ESFRA improves the network throughput 28 percent compared to that of IEEE 802.11, and 33 percent compared to that of SFRA. The improved performance is obtained at the expense of the synchronization compared to IEEE 802.11, but there is virtually no extra cost compared to SFRA.     

Evaluation of the shifting of the line of sight and higher order aberrations of eyes with keratoconus after corneal cross-linking

Aim

To evaluate changes in the coordinates of the line of sight (LoS) and higher order aberrations (HOAs) of eyes with keratoconus, following corneal cross-linking (CXL).

Optimized method for simultaneous determination of catechin, gallic acid, and methylxanthine compounds in chocolate using RP-HPLC

The simultaneous determination of catechins, gallic acid, and three methylxanthine compounds was determined in chocolate extract by reversed-phase HPLC. An isocratic HPLC procedure using Hypersil-ODS column with methanol three distilled water-formic acid (48.75:200.5:0.75, v/v/v) as a mobile phase was used and the HPLC profiles of 11 chocolate products were obtained. (-)- Epicatechin, (-)-epigallocatechin gallate, levels were very high whereas (+)-catechin, (-)-epigallocatechin and (-)-epicatechin gallate were lower values. Gallic acid was predominant compounds with extremely high levels in all chocolate samples. The content of three methylxanthine, theobromine, theophylline and caffeine was quantified with this procedure. Caffein amounts were low in all samples, while theobromine levels were high in milk and dark chocolates. Theophylline was at trace levels in some chocolates and could not be detected in some samples. This method was reliable, reproducible and objective for quantitative identification of flavanols and alkaloid compounds in the chocolate industry.     

Seasonal Variations in Fatty Acid Composition of Different Tissues of Mirror Carp,Cyprinus Carpio,in Orenler Dam Lake,Afyonkarahisar, Turkey

The seasonal variations of fatty acids compositions in the muscle, liver, and ovarian tissues of mirror carp (Cyprinus carpio) living in Örenler Dam Lake were determined by using gas chromatography. The results obtained were subjected to statistical analyses by employing SPSS software and p < 0.05 was accepted as significant value. In the statistical analyses, multiple comparisons tests were performed. The results showed that monounsaturated fatty acids levels were found to be higher than that of polyunsaturated fatty acids and saturated fatty acids in all seasons. Palmitic and stearic acid levels were the highest in ovaries (19.95% in winter and 7.79% in summer, respectively). Oleic and palmitoleic levels were at the highest levels in liver tissues (34.53% in summer and 18.37% in winter, respectively). Docosahexaenoic (C22:6ω3, DHA), eicosapentaenoic (C20:5ω3, EPA), eicosatrienoic acid, and arachidonic (C20:4ω6, AA) levels were at the highest level as 17.27, 2.54, and 8.41% in ovaries in the winter and 6.37% in muscle tissues in the spring, respectively. ω3/ω6 ratios were 0.62–0.98 in muscle, 1.54–2.82 in the liver, and 2.82–3.89 in the ovaries. From the point of total fatty acid variations, the highest variations were observed as follows: muscle in spring (26.73%), liver in winter (33.85%), and ovaries in winter 36.38%.     

Apricot Nectar Processing by Pulsed Electric Fields

Application of pulsed electric fields to process apricot nectar by determining the pH, °Brix, total acidity, conductivity, color, non-enzymatic browning index, concentration of mineral ions, and retention of ascorbic acid and beta carotene as well as inactivation of Escherichia coli O157:H7, Listeria monocytogenes, Staphylococcus aureus, Pseudomonas syringae subs. syringae, Erwinia carotowora, Penicillum expansum, and Botrytis cinerea was explored in this study. Processing of apricot nectar did not cause a significant difference in measured attributes (p > 0.05). However, inactivation of all microorganisms was significantly increased with increased electric field strength and treatment time (p ≤ 0.05). Microbial inactivation data fit both the Weibull distribution and log-logistic model.     

Control of buoyancy-induced temperature and flow fields with an embedded adiabatic thin plate in porous triangular cavities

Natural convection has been performed in an insulated horizontally thin plate embedded in a triangular enclosure filled with fluid saturated porous medium, numerically. Bottom and inclined wall of triangular enclosure are isothermally heated and cooled, respectively. Vertical wall of enclosure is adiabatic. Steady, two-dimensional, laminar governing equations, which are written with Darcy model, were solved with finite-difference method. Calculations are conducted for different lengths and locations of thin plate, different aspect ratios, and Darcy-modified Rayleigh number. Prandtl number was chosen as 0.71. It is observed that the change on plate location in vertical and horizontal axes makes small effect on heat transfer; however flow field and temperature distribution strongly affected from these parameters.     

Natural convection in a vertically divided square enclosure by a solid partition into air and water regions

Numerical analyses of the flow and heat transfer due to buoyancy forces in a square enclosure divided by an impermeable partition between air and water filled chests were carried out using a finite difference technique. The enclosure was heated from left wall and cooled from right, isothermally. Horizontal walls were adiabatic. The partition divided the enclosure into air and water regions. Thus, two cases were examined: left side of partition was filled with air and right side was filled with water (Case I, air-partition-water) and left side was filled with water and right side with air (Case II, water-partition-air). Epoxy was chosen as partition material. Results were obtained for different Grashof numbers (10³  Gr  10⁶), thickness of the partition (0.05  ε  0.2) and location of the partition (0.25  c  0.75). An analytical treatment has been performed for low Grashof numbers. Numerical and analytical results gave an acceptable agreement. It was found that filling of fluid into chests is important for obtaining maximum heat transfer and energy saving. When left chest was filled with air (Case I), higher heat transfer was formed. It was an interesting result that heat transfer decreased with increasing of location of the partition for all values of partition thickness at Case I. On the contrary, heat transfer was a decreasing function of increasing value of location of the partition.