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71.
Poly(p-tert-butoxycarbonyloxystyrene): a convenient precursor to p-hydroxystyrene resins 总被引:1,自引:0,他引:1
An efficient synthetic route to pure, high molecular weight poly(p-hydroxystyrene) is reported. The route involves synthesis of a new monomer, p-tert-butoxycarbonyloxystyrene, polymerization by radical initiation or by cationic initiation in liquid SO2, followed by thermolysis or acidolysis of the tert-butoxycarbonyl protecting group. Porous, crosslinked resin beads containing the nucleophilic, phenol pendant group have been prepared in a similar fashion from the precursor terpolymer of p-tert-butoxycarbonyloxystyrene, styrene and divinylbenzene. The utility of this resin for solid-phase synthesis has been demonstrated. 相似文献
72.
This study was undertaken to elucidate the state of a polymer in the amorphous state through a change of motion of the molecular chain caused by heat treatment below the glass transition temperature. From dielectric measurements of amorphous poly(ethylene terephthalate) heat-treated below Tg, it was found that the average relaxation time, the distribution of relaxation time and the dielectric strength increase with increase of heat treatment. From these results, it was concluded that the amorphous state becomes more random by heat treatment. 相似文献
73.
Taisuke Ito 《Polymer》1982,23(10):1412-1434
Results for the compressibilities of a wide range of polymer crystals along the fibre- and the transverse crystal axes are presented. Good agreement is found between the theoretical and the experimental results of different authors. 相似文献
74.
H. Matsushima T. Nishida Y. Konishi Y. Fukunaka Y. Ito K. Kuribayashi 《Electrochimica acta》2003,48(28):2446-4125
Water electrolysis was conducted in both alkaline (25 wt.% KOH, 2 wt.% KOH) and acid (0.1N H2SO4) solutions for 8 s under microgravity environment realized in a drop shaft. The gas bubble formation of hydrogen and oxygen on platinum electrodes was observed by CCD camera. In alkaline solutions, a bubble froth layer grew on the electrode surface. Hydrogen bubble size was smaller than that of oxygen. The current density at constant potential decreased continually with time. In spite of the growth of a bubble froth layer on the electrode, the electrolysis never stopped, apparently because fresh electrolyte is supplied to the electrode surface by microconvection induced by the gas bubble evolution. In acid solution, hydrogen gas bubbles frequently coalesced on the cathode surface, yielding a larger average bubble than that of oxygen. The current density did not vary at constant potentials from –0.4 to −0.8 V versus reversible hydrogen electrode (RHE), because the effective electrode surface area was significantly reduced by the larger bubble size compared to alkaline electrolyte. The present experiments indicate that, especially in a microgravity environment, the bubble evolution behavior and the resultant current–potential curves are significantly influenced by the wettability of the electrode in contact with the electrolyte. 相似文献
75.
Shigenobu Kobayashi Tomiji Wakida Shouhua Niu Satoshi Hazama Taisuke Ito Yoshiyuki Sasaki 《Coloration Technology》1995,111(3):72-76
Three kinds of aramid fabrics, Technora (modified p-aramid), Conex (m-aramid) and Kevlar (p-aramid), were subjected to sputter etching and argon low-temperature plasma treatments after dyeing in black with disperse dyes. The depth of shade increased considerably on Technora and Kevlar with the sputter etching treatment, but not on Conex fabrics. Argon low-temperature plasma treatment had virtually no effect on the depth of shade on the aramid fabrics. 相似文献
76.
Toshihiro Nagao Yuji Shimada Yoshie Yamauchi-Sato Takaya Yamamoto Masaaki Kasai Kentaro Tsutsumi Akio Sugihara Yoshio Tominaga 《Journal of the American Oil Chemists' Society》2002,79(3):303-308
A commercial product of CLA contains almost equal amounts of cis-9,trans-11 (c9,t11)-CLA and trans-10,cis-12 (t10,c12)-CLA. We attempted to enrich the two isomers by a two-step selective esterification using Candida rugosa lipase that acted on c9,t11-CLA more strongly than on t10,c12-CLA. An FFA mixture containing CLA isomers was esterified with an equimolar amount of lauryl alcohol in a mixture of 20%
water and the lipase. When the esterification of total FA reached 50%, two isomers were fractionated in a good yield: t10,c12-CLA was enriched in FFA, and c9,t11-CLA was recovered in lauryl esters. The FFA were esterified again to enrich t10,c12-CLA. At 27.3% esterification of total FA, the t10,c12-CLA content in FFA increased to 64.8 wt% with 89.3% recovery: The ratio of the content of t10,c12-CLA to that of two isomers was 95.9%. Lauryl esters obtained by the single esterification were employed for enrichment
of c9,t11-CLA. After the esters were hydrolyzed, the resulting FFA were esterified again with lauryl alcohol. At 62.0% esterification
of total FA, the c9,t11-CLA content in lauryl esters increased to 73.3 wt% with 79.4% recovery: The ratio of the content of c9,t11-CLA to that of two isomers was 95.6%. In a 600-g-scale purification, molecular distillation was effective in separating
the reaction mixture into lauryl alcohol, FFA, and lauryl ester fractions. 相似文献
77.
Electrocodeposition of Sm and Co on a Cu substrate was investigated in a molten LiCl-KCl-SmCl3 (0.5 mol.%)-CoCl2 (0.1 mol.%) system at 723 K. Phase of the deposited Sm-Co alloys could be controlled by electrolysis potential. SmCo3 was formed on a Cu substrate by potentiostatic electrolysis in the potential range of 0.20-0.90 V (vs. Li+/Li). Sm2Co17 was obtained in the potential range of 0.90-1.50 V. 相似文献
78.
Koichiro Fukuda Iwao Maki Suketoshi Ito 《Journal of the American Ceramic Society》1997,80(6):1595-1598
Crystals of β-Ca2 SiO4 (space group P 121 / n 1) were examined by high-temperature powder X-ray diffractometry to determine the change in unit-cell dimensions with temperature up to 645°C. The temperature dependence of the principal expansion coefficients (αi ) found from the matrix algebra analysis was as follows: α1 = 20.492 × 10−6 + 16.490 × 10−9 ( T - 25)°C−1 , α2 = 7.494 × 10−6 + 5.168 × 10−9 ( T - 25)°C−1 , α3 =−0.842 × 10−6 − 1.497 × 10−9 ( T - 25)°C−1 . The expansion coefficient α1 , nearly along [302] was approximately 3 times α2 along the b -axis. Very small contraction (α3 ) occurred nearly along [ 01]. The volume changes upon martensitic transformations of β↔αL ' were very small, and the strain accommodation would be almost complete. This is consistent with the thermoelasticity. 相似文献
79.
Masanori Hirano Keisuke Ota Takaharu Ito 《Journal of the American Ceramic Society》2005,88(12):3303-3310
Anatase-type TiO2 powder containing sulfur with absorption in the visible region was directly formed as particles with crystallite in the range 15–88 nm by thermal hydrolysis of titanium(III) sulfate (Ti2 (SO4 )3 ) solution at 100°–240°C. Because of the presence of ammonium peroxodisulfate ((NH4 )2 S2 O8 ), the yield of anatase-type TiO2 from Ti2 (SO4 )3 solution was accelerated, and anatase with fine crystallite was formed. Anatase-type TiO2 doped with ZrO2 up to 9.8 mol% was directly precipitated as nanometer-sized particles from the acidic precursor solutions of Ti2 (SO4 )3 and zirconium sulfate in the presence and the absence of (NH4 )2 S2 O8 by simultaneous hydrolysis under hydrothermal conditions at 200°C. By doping ZrO2 into TiO2 and with increasing ZrO2 content, the crystallite size of anatase was decreased, and the anatase-to-rutile phase transformation was retarded as much as 200°C. The anatase-type structure of ZrO2 -doped TiO2 was maintained after heating at 1000°C for 1 h. The favorable effect of doping ZrO2 to anatase-type TiO2 on the photocatalytic activity was observed. 相似文献
80.