Rosemary (<Emphasis Type="Italic">Rosmarinus officinalis</Emphasis>) oil: composition and functionality of the cold-pressed extract

The aim of this work was to investigate cold-pressed rosemary oil (RO) for its lipid classes, subclasses, fatty acid composition, tocochromanols and total phenolics amount. Antiradical activity against 1,1-diphenyl-2-picrylhydrazyl (DPPH^?) and galvinoxyl radicals, antioxidant activity, as measured by the Rancimat test, as well as antimicrobial activity against food-borne bacteria, and dermatophytic fungi of RO were evaluated. In RO, the amount of neutral lipids was highest (ca. 86%), followed by phospholipids (0.92%) and glycolipids (0.88%). The percentages of monounsaturated, polyunsaturated, and saturated fatty acids were 41.7, 42.3, and 15.8%, respectively. Linoleic acid (41.7%) and oleic acid (41.2%) were the major fatty acids while linolenic acid accounted for 1.3% of total fatty acids. The following tocochromanols were detected: α-, β-, γ- and δ-tocopherols, which accounted for 291, 22, 1145, and 41 mg/100 g oil, respectively, as well as α-, β-, γ- and δ-tocotrienols, which accounted for 18, 12, 29, and 158 mg/100 g oil, respectively. RO also contained high levels of phenolic compounds (7.2 mg GAE/g). After 60 min of reaction with free radicals, 67% of DPPH^? and 55% of galvinoxyl radicals were quenched by RO. Rancimat test showed that blending RO with sunflower oil increased the induction period (IP) for blends. The IP of the RO: sunflower oil blend (1:9, v/v) was 390 min, and RO: sunflower oil blend (2:8, v/v) was longer (540 min). RO exhibited high antimicrobial potential against food-borne pathogenic bacteria (E. coli, S. enteritidis, and L. monocytogenes) and high antifungal potential against dermatophyte fungi (T. mentagrophytes, and T. rubrum). RO had unique high level of γ-tocopherol, which is a scavenger of reactive nitrogen species making it a promising material in the food, cosmetic and pharmaceutical applications.     

Induction Motors Broken Rotor Bars Diagnosis Through the Discrete Wavelet Transform of the Instantaneous Reactive Power Signal under Time-varying Load Conditions

Abstract—In this article, a method based on the application of the discrete wavelet transform to the instantaneous reactive power signal, for diagnosing the occurrence of broken rotor bars in induction motors operating under time-varying load conditions, is presented. This method is based on the decomposition of the instantaneous reactive power signal, from which wavelet approximation and detail coefficients are extracted. The energy evaluation of known bandwidths permits to de?ne a fault severity factor. This method has been tested through the simulation of an induction motor using a mathematical model based on the winding-function approach. These simulation results are complemented by experimental tests conducted on an induction motor with several faulty rotors that can be interchanged and both simulation and experimental results have shown the effectiveness of the proposed method for broken rotor bars diagnosis in induction motors even under time-varying load conditions.     

Low molecular weight serine protease from the viscera of sardinelle (Sardinella aurita) with collagenolytic activity: Purification and characterisation

A new low molecular weight (LMW) serine-protease from sardinelle (Sardinella aurita) viscera was purified using ammonium sulphate precipitation and Sephadex G-100 gel filtration, with a 3.82-fold increase in specific activity. The molecular weight of the enzyme was estimated to be 14.2 kDa by SDS-PAGE. The optimum pH and temperature for the enzyme activity were around pH 8.0 and 60 °C, respectively. The purified protease was strongly inhibited by phenylmethylsulphonyl fluoride, a serine-protease inhibitor, and soybean trypsin inhibitor. The N-terminal amino acid sequence of the first 10 amino acids of the purified protease was APVQPCVVVI. This sequence showed low homology with several peptidases, suggesting that the enzyme is a new protease. Interestingly, the protease was found to cleave collagen type I and hydrolyze succinyl-L-Ala-L-Ala-L-Pro-L-Phe-p-nitroanilide (sAAPFpna), an amide substrate of chymotrypsin. Our findings indicate that the S. aurita protease is a new LMW enzyme with collagenolytic activity.     

THERMAL STRESSES FOR AN INFINITE BODY WITH A SPHERICAL CAVITY WITH TWO RELAXATION TIMES

Thermoelastic interactions caused in a homogeneous and isotropic infinite body with a spherical cavity are considered for the two different theories of generalized thermoelasticity, that is, Lord, and Shulman's theory and Green and Lindsay's theory. Analytical expressions for the temperature, displacement, and thermal stress fields are obtained; and the results are compared with the classical dynamical coupled theory.     

Partially bonded near-surface-mounted CFRP bars for strengthened concrete T-beams

A partially bonded strengthening approach for reinforced concrete (RC) beams utilizing near-surface-mounted (NSM) carbon fiber reinforced polymer (CFRP) bars was investigated with the specific objective of improving deformability. A total of six RC T-beams strengthened with NSM CFRP bars of various unbonded lengths were tested. Test results showed a decrease of the stiffness at the post-yield stage of the load–deflection response in the partially bonded beams. This is caused by the delayed increase of the FRP strain within the unbonded length. As a result the beam deformability was increased as the unbonded length increased at the same applied load. Internal slip of the FRP bar and gradual concrete failure were observed near the ultimate state, which caused a complicate nonlinear behavior of the beams. An analytical model is proposed to address the complete beam behavior including the effect of slip of FRP reinforcement and gradual concrete crushing. This model was developed based on the compatibility of deformation of the partially bonded system and was able to represent the ultimate behavior of the beams well.     

An investigation of speech enhancement using wavelet filtering method

This paper investigates the utilization of wavelet filters via multistage convolution by Reverse Biorthogonal Wavelets (RBW) in high and low pass band frequency parts of speech signal. Speech signal is decomposed into two pass bands of frequency; high and low, and then the noise is removed in each band individually in different stages via wavelet filters. This approach provides better outcomes because it does not cut the speech information, which occurs when utilizing conventional thresholding. We tested the proposed method via several noise probability distribution functions. Subjective evaluation is engaged in conjunction with objective evaluation to accomplish optimal investigation method. The method is simple but has surprise high quality results. The method shows superiority over Donoho and Johnstone thresholding method and Birge-Massart thresholding strategy method.     

Privacy Analysis of Forward and Backward Untraceable RFID Authentication Schemes

In this paper, we analyze the first known provably secure Radio Frequency Identification (RFID) authentication schemes that are designed to provide forward untraceability and backward untraceability: the L-K and S-M schemes. We show how to trace tags in the L-K scheme without needing to corrupt tags. We also show that if a standard cryptographic pseudorandom bit generator (PRBG) is used in the S-M scheme, then the scheme may fail to provide forward untraceability and backward untraceability. To achieve the desired untraceability features, we show that the S-M scheme can use a robust PRBG which provides forward security and backward security. We also note that the backward security is stronger than necessary for the backward untraceability of the S-M scheme.     

CRETACEOUS SOURCE ROCKS AT THE ABU GHARADIG OIL- AND GASFIELD, NORTHERN WESTERN DESERT, EGYPT

The Abu Gharadig oil- and gasfield is located in the north of the Western Desert of Egypt. In this paper, the geochemical characteristics of kerogens from Cretaceous shales at this field are described. The shale samples came from the Abu Roash Formation E and G Members (late Cenomanian- Turonian), the Bahariya Formation (early Cenomanian) and the Betty Formation (Neocomian- Barremian). Kerogen type and quality was evaluated by optical microscopy and by standard methods (elemental analysis, infrared spectroscopy and Rock-Eval pyrolysis). The results show that the shale samples analysed contain fair to high quantities of organic matter, and that this takes the form of marine amorphous sapropelic and structured liptinite macerals which can be classified as Types I and II kerogens.
Maturation indicators and burial history curves indicate that shales from the Abu Roash E and G Members are currently located in the oil-generation window. Oil generation in these units has taken place since the late Palaeocene-early Eocene—i.e. since the formation of structural traps in the Abu Gharadig area, which occurred in the Maastrichtian—Eocene. Shales in the Bahariya and Betty Formations passed through the oil window during the Late Cretaceous before the traps were formed, but the shales reached the wet-gas zone in the late Miocene - early Pliocene.
Most of the liquid hydrocarbons in the Abu Gharadig field are sourced by Cretaceous shales in the Abu Roash E and G Members; and most gas is generated by shales in the underlying Bahariya and Betty Formations. The Jurassic Khatatba Formation may also have generated some gas.     

Low-Temperature Preparation and Magnetic Properties of V-Doped SnO2 Nanoparticles

A solid solution of vanadium (V)-doped tin oxide (SnO₂) particles of average diameter 2 nm and V content of 19 at.% was prepared at normal pressure and low temperature (100°C) by mixing wet SnO₂ gel SnO₂· x H₂O with a boiling solution of vanadium oxide (V₂O₅). Experimental characterizations using X-ray, electron diffraction, and transmission electron microscope show evidence of a pure single phase. The nanoparticles exhibit a mixed magnetic behavior, namely paramagnetic and ferromagnetic. Their thermal stability is also investigated. At higher temperature, 850°C, some amount of Fe precipitates from the solid solution.     

Infrared spectra, Raman laser, XRD, DSC/TGA and SEM investigations on the preparations of selenium metal, (Sb2O3, Ga2O3, SnO and HgO) oxides and lead carbonate with pure grade using acetamide precursors

Ga₂O₃, Se metal, SnO, Sb₂O₃, HgO and PbCO₃ are formed upon the reaction of acetamide aqueous solutions with Ga(NO₃)₃, SeO₂, SnCl₂, SbCl₃, HgCl₂ and Pb(NO₃)₂, respectively, at 90°C. Different amorphous or crystalline phases can be obtained depending upon the experimental conditions (molar ratios, metal salts and temperature). The chemical mechanisms for the formations of this metal, oxides or carbonate are discussed and the X-ray diffraction, scanning electron microscopy (SEM) and atomic force microscope (AFM) are described. The type of metal ions plays an important role in the decomposition of acetamide, leading to the formation of solid stable (metal, oxides or carbonate), soluble and gases species. These new precursors are more stable preventing the rapid precipitation of metal, oxides or carbonate. Furthermore, this route allows the formation of pure compounds in solutions.