On the corrosion inhibition and adsorption behaviour of some benzotriazole derivatives during copper corrosion in nitric acid solutions: a combined experimental and theoretical study

Copper corrosion inhibition in 1 M HNO₃ solution by some benzotriazole derivatives, namely N-(2-thiazolyl)-1H-benzotriazole-1-carbothioamide (TBC), N-(furan-2-ylmethyl)-1H-benzotriazole-1-carbothioamide (FBC) and N-benzyl-1H-benzotriazole-1-carbothioamide (BBC), was investigated by ac impedance, dc polarization and weight loss techniques. A significant decrease in the corrosion rate of copper was observed in presence of the investigated compounds. The corrosion rate was found to depend on the concentration and type of the inhibitor. The degree of surface coverage of the adsorbed inhibitor was determined by weight loss technique, and it was found that the results obeyed Langmuir adsorption isotherm. Tafel polarization data indicated that the three selected inhibitors were of mixed type. The reactivities of the compounds under investigation were analyzed through Fukui indices, derived from density functional theory (DFT), to explain their inhibition performance.     

Effect of Partial Unbonding on Prestressed Near-Surface-Mounted CFRP-Strengthened Concrete T-Beams

The flexural behavior of RC T-beams strengthened with prestressed near-surface-mounted (NSM) carbon fiber-reinforced-polymer (CFRP) reinforcement was investigated. The specific objective was to study the effect of partial unbonding of the CFRP reinforcement on the beam flexural behavior to increase the deformability. A total of eight RC T-beams were tested under four-point monotonic loading. The main variables were the level of prestressing force in the CFRP bars and the unbonded length at the midspan of the beam. The test results showed that all of the prestressed strengthened beams effectively improved the ultimate load-carrying capacity and the serviceability performance compared to the unstrengthened beam. The partially bonded prestressed beams exhibited an enhancement of the deformability compared to the fully bonded beams while minimizing the reduction of the load-carrying capacity. Partial unbonding was more effective to improve the deformability at higher levels of prestressing force. The general behavior of the partially bonded beams was reasonably well predicted by an analytical model developed previously by the writers.     

Optimizing Material Procurement and Storage on Construction Sites

Efficient planning of materials procurement and storage on construction sites can lead to significant improvements in construction productivity and project profitability. Existing research studies focus on material procurement and storage layout as two separate planning tasks without considering their critical and mutual interdependencies. This paper presents the development of a new optimization model for construction logistics planning that is capable of simultaneously integrating and optimizing the critical planning decisions of material procurement and material storage on construction sites. The model utilizes genetic algorithms to minimize construction logistics costs that cover material ordering, financing, stock-out, and layout costs. The model incorporates newly developed algorithms to estimate the impact of potential material shortages on-site because of late delivery on project delays and stock-out costs. An application example is analyzed to demonstrate the capabilities of the construction logistics planning model in simultaneously optimizing material procurement decisions and storage layout plans.     

Effect of short polyethylene terephthalate fibers on properties of ethylene-propylene diene rubber composites

The alteration in some properties of electron beam (EB) cured ethylene-propylene diene rubber (EPDM) reinforced by polyethylene terephthalate (PET) fiber was investigated in this study. Bonding system Resorcinol/Hexamethylenetetramine/Silica (RHS) was used to enhance the fiber/EPDM adhesion and to maintain optimum composite strength properties. Mechanical properties of composites namely; tensile strength, hardness and modulus at 100 % elongation have been enhanced by adding PET fibers and increasing irradiation dose. Moreover, the effect of fiber loading and irradiation dose on the soluble fraction behavior of the composite in benzene was also investigated. The soluble fraction of the composites decreased with increasing the fiber loading and irradiation dose. The extent of fiber alignment and strength of fiber-rubber interface adhesion were analyzed from the anisotropic swelling measurements. In addition, thermal stability of the composites was increased. Besides, the mechanical properties like tensile strength and stiffness were improved by thermal ageing. Scanning electron microscopy (SEM) for the fractured surfaces and Wide- angle X- ray diffraction (WAXD) of the investigated samples confirmed that the adhesion occurred between fibers and EPDM.     

Investigation of the mixing efficiency of a chaotic micromixer using thermal lens spectrometry

This work investigates the efficiency of a chaotic micromixer using thermal lens spectrometry. The outlet of the mixing device was connected to a thermal lens detection head integrating the probe beam optical fibers and the sample capillary. The chaotic micromixer consisted of a Y-shaped poly(dimethylsiloxane) (PDMS) microchip in which ribbed herringbone microstructures were etched on the floor of the main channel. Due to the solvent composition dependence of the thermal lens response, the photothermal method was shown to be highly sensitive to nonhomogeneous mixing compared to fluorescence detection. The apparatus was applied to the determination of Fe2+ with 1,10-phenanthroline using flow injection analysis; a limit of detection of 11 microg L(-1) of iron was obtained.     

Effects of moving lid direction on MHD mixed convection in a linearly heated cavity

Effects of moving lid-direction on MHD mixed convection in a cavity with the bottom wall being linearly heated are analyzed using a numerical technique. Vertical walls of the enclosure are adiabatic and the sliding wall at the top has constant temperature. The lid moves in the negative and positive x-direction. Finite volume method has been used to solve the governing equations. Results are presented for different values of Hartmann number (0 ? Ha ? 30), Reynolds number (100 ? Re ? 1000) and Grashof number (10⁴ ? Gr ? 10⁶). It is found that direction of lid is more effective on heat transfer and fluid flow in the case of mixed convection than it is the case in forced convection. Heat transfer is also decreased with increasing of magnetic field for all studied parameters.     

Modeling railroad track structures using the finite segment method

In the finite segment method, the dynamics of a deformable body is described using a set of rigid bodies that are connected by elastic force elements. This approach can be used, as demonstrated in this investigation, in the simulation of some rail movements. In order to ensure that the rail geometry is not distorted as the result of the finite segment displacements, a new track model that consistently integrates the absolute nodal coordinate formulation (ANCF) geometry and the finite segment method is developed. ANCF finite elements define the track geometry in the reference configuration as well as the change in the geometry due to the movement of the finite segments of the track. Using ANCF geometry and the finite segment kinematics, the location of the wheel/rail contact point is predicted online and used to update the creepage expressions due to the finite segment displacements and rotations. The location of the wheel/rail contact point and the updated creepage expressions are used to evaluate the creep forces. A three-dimensional elastic contact formulation (ECF-A) which allows for wheel/rail separation is used in this investigation. The rail displacement due to the applied loads is modeled by a set of rigid finite segments that are connected by a set of spring-damper elements. Each rail finite segment is assumed to have six rigid body degrees of freedom. The equations of motion of the finite segments are integrated with the railroad vehicle system equations of motion in a sparse matrix formulation. The resulting dynamic equations are solved using a predictor–corrector numerical integration method that has a variable order and variable step size. The finite segments may be used to model specific phenomena that occur in railroad vehicle applications, including rail rotations and gauge widening. The procedure used in this investigation to implement the finite segment method in a general purpose multibody system (MBS) computer program is described. Two simple models are presented in order to demonstrate the implementation of the finite segment method in MBS algorithms. The limitations of using the finite segments approach for modeling the track structure and rail flexibility are also discussed.     

A novel aspartic protease from the viscera of Sardinelle (Sardinella aurita): Purification and characterisation

A novel aspartic protease was extracted from the defatted viscera of sardinelle (Sardinella aurita) and purified, with a 9.5-fold increase in specific activity and 23.3% recovery. The molecular weight of the purified enzyme was estimated to be 17 kDa by sodium dodecyl sulphate–polyacrylamide gel electrophoresis (SDS–PAGE). The purified enzyme appeared as a single band on native-PAGE. The optimum pH and temperature for protease activity were around 3.0 and 40 °C, respectively. The enzyme showed pH stability between 2.0 and 5.0 and retained more than 50% of its activity after heating for 30 min at 50 °C. The enzyme lost 90% of its activity after incubation with pepstatin A at room temperature, but was not inhibited by soybean trypsin inhibitor or phenylmethylsulfonyl fluoride. Its K_m value was determined to be 0.73 × 10⁻⁴ M using haemoglobin as a substrate. The N-terminal 12 amino acid sequence of the purified acidic protease was R V I I E D X D Q F C T. This sequence showed low homology with aspartic peptidases of several other species of fish, suggesting that the enzyme is a new aspartic protease.     

An automated system for optimizing post-disaster temporary housing allocation

In the aftermath of natural disasters, emergency management agencies need to provide adequate temporary housing solutions to accommodate the large number of displaced families. Disaster impact software systems, such as HAZUS-MH (FEMA) and MAEviz (MAE Center), enable emergency planners to estimate the expected displacement of families after natural disasters; however they lack the capability of providing temporary housing solutions. This paper presents the development of an automated system to support decision-makers in optimizing post-disaster temporary housing arrangements. The system has been integrated in MAEviz and provides the capability of optimizing a number of important objectives, including minimizing negative socioeconomic impacts, maximizing housing safety, minimizing negative environmental impacts, and minimizing public expenditures; in addition to other user-defined objectives. The system consists of three main models: (1) data collection; (2) automated optimization; and (3) output analysis and visualization. A large-scale application example is optimized to illustrate the use of the system and demonstrate its unique capabilities.     

Incremental modified pushover analysis

The recently developed Incremental Dynamic Analysis (IDA) requires nonlinear time history analyses at different levels of intensity of an ensemble of ground motions, which is time‐consuming due to the high computational efforts involved. In the current study, a simplified method named as Incremental Modified Pushover (IMP) is developed and evaluated. In this method, the response of the structure is obtained using one pushover analysis at any specified level of ground motion intensity. The associated higher mode effects are explicitly considered when determining target roof displacement and lateral load pattern. In the bilinear idealization of the pushover curves, a new approach has been used. Moment resisting steel frames with 4, 8, 12 and 16 stories, as well as their corresponding soft‐story models are used for verifying the proposed method. The studied frames were subjected to seventeen different scaled earthquake ground motions. The results of the presented method, IMP, are verified in terms of maximum roof displacement, maximum inter‐story drift and maximum plastic hinge rotation at different ground motion intensities. The results show that the IMP method gives higher response values compared with IDA, which can be viewed as being more conservative. Copyright © 2008 John Wiley & Sons, Ltd.