Effects of gating design on structural and mechanical properties of high manganese steel by optimizing casting process parameters

Journal of Mechanical Science and Technology - The impacts of gating design and riser system on structure-property relationship of high manganese steel specimens produced by CO2 sand molding...     

Phase-Field Modeling of Sigma-Phase Precipitation in 25Cr7Ni4Mo Duplex Stainless Steel

Phase-field modeling is used to simulate the formation of sigma phase in a model alloy mimicking a commercial super duplex stainless steel (SDSS) alloy, in order to study precipitation and growth of sigma phase under linear continuous cooling. The so-called Warren–Boettinger–McFadden (WBM) model is used to build the basis of the multiphase and multicomponent phase-field model. The thermodynamic inconsistency at the multiple junctions associated with the multiphase formulation of the WBM model is resolved by means of a numerical Cut-off algorithm. To make realistic simulations, all the kinetic and the thermodynamic quantities are derived from the CALPHAD databases at each numerical time step, using Thermo-Calc and TQ-Interface. The credibility of the phase-field model is verified by comparing the results from the phase-field simulations with the corresponding DICTRA simulations and also with the empirical data. 2D phase-field simulations are performed for three different cooling rates in two different initial microstructures. A simple model for the nucleation of sigma phase is also implemented in the first case. Simulation results show that the precipitation of sigma phase is characterized by the accumulation of Cr and Mo at the austenite-ferrite and the ferrite-ferrite boundaries. Moreover, it is observed that a slow cooling rate promotes the growth of sigma phase, while a higher cooling rate restricts it, eventually preserving the duplex structure in the SDSS alloy. Results from the phase-field simulations are also compared quantitatively with the experiments, performed on a commercial 2507 SDSS alloy. It is found that overall, the predicted morphological features of the transformation and the composition profiles show good conformity with the empirical data.

     

Spectral and kinetic characterization of orange-red emitting Sr3Al2O6:Eu/Smphosphor

We report, for the first time Sm³⁺ doped nanocrystalline Sr₃Al₂O₆ phosphor. Effect of Eu³⁺ doping in the present host is also studied. XRD results match with standard data from JCPDS file confirming cubic structure with Pa3 space group. PL Maximum for Eu/Sm is obtained at 590 nm and 573 nm respectively, and corresponds to orange-red region of electromagnetic spectrum. Morphology of combustion synthesized powder is platelet, while for calcined powders, cubic shaped crystallites are obtained. Information on various trapping parameters is obtained from thermally stimulated Luminescence (TSL) studies. Non-shifting T_m property is applied to define the order of kinetics and is thereafter assumed as 1. T_m − T_stop procedure and repeated initial rise method are applied to estimate apparent activation energies and peak positions. Further, chi-square minimization procedures via computerized glow curve deconvolution (CGCD) technique provide best-fit results. The figure of merit for deconvoluted Eu and Sm doped samples are 0.48% and 0.67% respectively. The apparent activation energies for Eu doped samples are 0.89 eV, 1.05 eV, 1.30 eV, while, for Sm doped samples, the activation energies are 0.84 eV and 1.06 eV. Persistence behavior of the present phosphor is attributed to contribution due to shorter and longer components as are obtained during phosphorescence decay studies. In both the cases; probability of recombination is more in comparison to the retrapping within a quasi continuous framework of trapping sites.     

A Study of the Thallium- and Bismuth-based High-temperature Superconductors in the Framework of the Generalized BCS Equations

Presented here in the framework of the generalized BCS equations??which are based on multiple phonon exchanges for the formation of Cooper pairs (CPs)??is continuation of a study carried out earlier for MgB₂ Nb₃Sn and YBCO. Addressed now are the principal members of the Tl- and Bi-based high-T _c superconductors. For any of these, with the input of any two parameters from the set {critical temperature, two gaps}, and the Debye temperature, it is shown that one can calculate the remaining parameter. This is similar to what normal BCS equations achieve for a simple superconductor. Further, we show that these equations lead to upper bounds on the gap- and the T _c -values of a HTSC, beyond which one must invoke 2/3-phonon mechanism for the formation of CPs. Our considerations suggest the interesting possibility that senior members of the said families of cuprates may be three-gap SCs.     

T‐norms in subtractive clustering and backpropagation

The tuning of a fuzzy model is discussed in the context of choices made between different t‐norms. The effects of the choice is illustrated by looking at two fuzzy models initially generated, respectively, by grid partition and a novel variant of subtractive clustering. The new variant of subtractive clustering introduced in the paper is based on the standard method of subtractive clustering, where in this new method, the measure of similarity and thus also cluster shapes depend on a choice of t‐norm T. © 2010 Wiley Periodicals, Inc.     

Retrotransposable elements R1 and R2 in the rDNA units of Drosophila mercatorum: abnormal abdomen revisited

R1 and R2 retrotransposable elements are stable components of the 28S rRNA genes of arthropods. While each retrotransposition event leads to incremental losses of rDNA unit expression, little is known about the selective consequences of these elements on the host genome. Previous reports suggested that in the abnormal abdomen (aa) phenotype of Drosophila mercatorum, high levels of rDNA insertions (R1) in conjunction with the under-replication locus (ur), enable the utilization of different ecological conditions via a population level shift to younger age. We have sequenced the R1 and R2 elements of D. mercatorum and show that the levels of R1- and R2-inserted rDNA units were inaccurately scored in the original studies of aa, leading to several misinterpretations. In particular, contrary to earlier reports, aa flies differentially underreplicate R1- and R2-inserted rDNA units, like other species of Drosophila. However, aa flies do not undergo the lower level of underreplication of their functional rDNA units (general underreplication) that is seen in wild-type strains. The lack of general underreplication is expected to confer a selective advantage and, thus, can be interpreted as an adaptation to overcome high levels of R1 and R2 insertions. These results allow us to reconcile some of the apparently contradictory effects of aa and the bobbed phenotype found in other species of Drosophila.     

IMGT, the international ImMunoGeneTics database

Propofol emulsion supports bacterial growth. Extrinsic contamination of propofol has been implicated as an etiological event in postsurgical infections. When added to propofol, local anesthetics (e.g., lidocaine) alleviate the pain associated with injecting it. Because local anesthetics have antimicrobial activity, we determined whether lidocaine would inhibit microbial growth by comparing the growth of four microorganisms in propofol and in mixtures of propofol and lidocaine. Known quanta of Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, and Candida albicans were inoculated into solutions of 1% propofol, 0.2% lidocaine in propofol, 0.5% lidocaine in propofol, 0.5% lidocaine in isotonic sodium chloride solution, and 0.9% isotonic sodium chloride solution. All microorganisms were taken from stock cultures and incubated for 24 h. Growth of microorganisms in each solution was compared by counting the number of colony-forming units grown from a subculture of the solution at 0, 3, 6, 12 and 24 h. Propofol supported the growth of E. coli and C. albicans. Propofol maintained static levels of S. aureus and was bactericidal toward P. aeruginosa. The addition of 0.2% and 0.5% lidocaine to propofol failed to prevent the growth of the studied microorganisms. The effect of 0.5% lidocaine in isotonic sodium chloride solution did not differ from the effects of isotonic sodium chloride solution alone. We conclude that lidocaine, when added to propofol in clinically acceptable concentrations, does not exhibit antimicrobial properties. IMPLICATIONS: Local anesthetics such as lidocaine have antimicrobial activity. Propofol supports the growth of bacteria responsible for infection. Bacteria were added to propofol and propofol mixed with lidocaine. The addition of lidocaine to propofol in clinically relevant concentrations did not prevent the growth of bacteria. The addition of lidocaine to propofol cannot prevent infection from contaminated propofol.     

SOLVENT EXTRACTION OF PAKISTANI COALS (ii): EXTRACTION AND CHARACTERIZATION OF METHANOL-BENZENE EXTRACTS

Structural characterization of the solvent extracts from four different Pakistani lignitic coals has been carried out by their proximate, elemental analysis and FT-Infrared and ¹H n.m.r. spectra. The yield of each extracts was greater with 1:1 benzene-methanol mixture in comparison to the total yield obtained by separate extractions with benzene and methanol. The extracts contained significantly less amount of ash and fixed carbon along with an increase in the percentage of volatile matter. The FTIR and ¹H n.m.r. spectra indicated that basically all the extracts contained less condensed aromatic rings in comparison to the coal. The FTIR spectra showed sharp well resolved peaks which have been assigned to various functional groups.

The ¹H n.m.r. spectra were used to obtain average structural parameters for all the extracts. A detailed analysis of the FTIR and n.m.r. spectra of the coal and their extracts provided an important in-sight into the differences between various extracts and also between various coals and their corresponding extracts.