Effect of separation distance on cavitation erosion of vibratory and stationary specimens in a vibratory facility

Vibratory cavitation erosion with vibratory and stationary specimens is studied for three materials in tap water at room temperature. The separation distance is varied from 0.127 to 6.096 mm. Test materials were commercially pure lead, soft (1100-O) aluminum and type 316 stainless steel. The double-horn amplitude was 58.4 μm (2.3 × 10^?3in) in a 20 kHz facility. The total duration of all tests was 10 min.The weight loss of both vibratory and stationary specimens of course depends on materials. The weight loss of stationary specimens is best correlated as a function of the reciprocal of the separation distance.     

Catalytic hydrotreatment of heavy liquids prepared from coals of different rank

Heavy liquids prepared from a bituminous, a sub-bituminous and a brown coal were hydrotreated with commercial and titania-supported nickel-molybdenum catalysts to examine the reactivity and selectivity of the catalysis in relation to catalyst structure and catalytic functions. Liquids from the sub-bituminous and the brown coals behaved very similarly in the depolymerization scheme of conversion from preasphaltene to asphaltene, where the titania-supported catalysts exhibited preferential activity for the preasphaltene fraction with only limited conversion of the asphaltene fraction. The commercial catalyst showed no preferential selectivity in spite of the similar reaction scheme. Preasphaltene from the bituminous coal behaved in a contrasting manner on both catalysts, requiring the ring-opening reaction as deduced from the structural analyses in the same conversion without any preference for asphaltene. The effect of solvent composition was examined in some tests in order to improve conversion.     

Logistics Support System for Construction Robotics Implementation

Abstract: A logistics and scheduling microcomputer system for construction robotics implementation has been developed within the framework of the Construction Robotic Equipment Management System (CREMS) at Purdue University. This paper addresses the main procedures and software developed to effectively manage multiple robots in diverse construction sites. The current version of the software is used with HyperCard, QuickBASIC, and Think-Pascal on an Apple Macintosh microcomputer. This paper presents an example microcomputer application to optimal robot implementation assignment decision support for use with multiple concurrent construction projects.     

Selective recovery of gold by simultaneous adsorption–reduction using microalgal residues generated from biofuel conversion processes

BACKGROUND: This research provides a new approach to the effective use of microalgal biomass waste generated by biofuel conversion processes. In this study, a novel adsorbent for Au(III) recovery was prepared by treating microalgal residues with concentrated sulfuric acid. RESULTS: The prepared adsorbent, crosslinked microalgae, exhibited high affinity and selectivity for Au(III) over other precious and base metal ions in a hydrochloric acid medium. From the adsorption isotherms, the maximum adsorption capacity of the crosslinked microalgae for Au(III) was estimated to be 3.25 mol kg^?1 (640 g kg^?1), which was about eight times higher than the adsorption capacity of the microalgal residue. Microphotographs, scanning electron microscopy, and X‐ray diffraction confirmed the formation of metallic Au, suggesting that a redox reaction had taken place between the adsorbent and Au(III) ions during adsorption. Comparison of Fourier‐transform infrared spectra before and after adsorption indicated that hydroxyl groups as well as ether oxygen atoms in the crosslinked microalgae participated in the Au(III) uptake mechanism. It also suggested that the reduction of Au(III) to Au(0) was facilitated by hydroxyl groups in the crosslinked microalgae. CONCLUSION: The results presented in this paper are very promising for the practical use of microalgal residues for the recovery of Au(III) because of good selectivity and favorable adsorption capacity for Au(III). Copyright © 2011 Society of Chemical Industry     

Regeneration of initial activity of a pitch-based ACF for NO–NH3 reaction at ambient temperature

The reactivity of adsorbed NO (including NO₂) and NH₃ in the presence of 4.0% oxygen in He was examined over a pitch-based ACF calcined at 800°C. Regeneration at 30°C by 4% O₂ in He without NH₃ was found to be optimum for the recovery of the initial activity with complete removal of NO within 3 h, with minimum leaks of adsorbed NO and NH₃. A higher temperature of 40°C for regeneration increased the liberation of adsorbed NO, and NH₃ over ACF was rather slow at a lower temperature of 25°C, slow regeneration being achieved. Oxygen appears necessary to regenerate the ACF through enhancing the reaction of adsorbed NO and NH₃ for the initial activity, which was ascribed to the catalytic activity for NO–NH₃ and adsorption of both NO and NH₃. NH₃ in the gas phase appears to inhibit the regeneration reaction of adsorbed species, by using the leaking amount during the regeneration.     

Synthesis of 1,3-dicapryloyl-2-docosahexaenoylglycerol by a combination of nonselective and <Emphasis Type="Italic">sn</Emphasis>-1,3-selective lipase reactions

A two-step consecutive synthetic method for the production of symmetrical, structured lipids by a combination of nonselective and sn-1,3 regioselective ester exchange reactions was investigated. In the first step, TAG with unspecifically substituted DHA were obtained by reacting tricapryloylglycerol (CCC) with ethyl docosahexanoate (EtDHA) using the lipase QLM (from Alcaligenes sp.), followed by removing the ethyl ester and CCC by molecular distillation. In the second step, sn-1,3 regioselective ester exchange was achieved by reacting the resulting TAG with ethyl caprylate (EtC) using the immobilized lipase Novozyme 435 (Candida antarctica lipase), followed by distillation of the ethyl ester and CCC to give sn-1,3-dicapryloyl-sn-2-docosahexaenoylglycerol (CDC). The acylglycerol composition of CDC was analyzed by GLC, which showed that the content of dicapryloyl-docosahexaenoylglycerols (2CD) in the product was 76.4%, and that the ratio of CDC to sn-1,2-dicapryloyl-sn-3-docosahexaenoylglycerol contained in 2CD was 82.7∶17.3 (%). The distillates CCC, EtDHA, and EtC could be recycled repeatedly to produce CDC as the substrate for the consecutive ester exchange reaction. In addition, separation of CCC and EtDHA was unnecessary for reuse. The present method is considered to meet the requirements for industrial utilization, in which simplicity in scaleup, high yields, compact reaction system, and minimal formation of by-products are important factors.     

Redundancy index of lifelines for mitigation measures against seismic risk

Basic consideration is made on how comprehensively we can evaluate potential seismic risk of lifeline systems and gain an insight into the safety by way of information entropy, which transmits information of various kinds under uncertainties. It is clarified that a redundancy index R_E defined via Shannon's information entropy can be an index to represent redundancy of a system and whose value plays a role to choose the best alternative for designing a system or for finding the best damage mitigation measure against earthquake hazard. The redundancy index R_E takes a value between zero and unity with zero for no redundancy, and unity for maximum redundancy. After the validity of R_E is justified to represent a redundancy measure, a case study is conducted for a Kobe water supply system to evaluate a mitigation measure against earthquake risk where the 1995 Hyogoken-Nanbu earthquake is used as the input hazard.     

Assignment and quantification of 2-aminopyridine derivatized oligosaccharide isomers coeluted on reversed-phase HPLC/MS by MSn spectral library

2-Aminopyridine (PA)-derivatized oligosaccharides from IgG were analyzed by using reversed-phase HPLC/mass spectrometry (RP-HPLC/MS) and a MS(n) spectral library, in particular, focusing on two pairs of isomers incompletely separated or coeluted in chromatograms. We previously reported that MS(n) spectral matching considering both major fragment ions (m/z) and intensities is useful and applicable to the structural assignment of PA-oligosaccharide isomers. In this study, MS(n) spectral matching based on the MS(n) spectral library was applied to the assignment of these PA-oligosaccharide isomers in IgG. Its usefulness was investigated by comparing it to the conventional two-dimensional mapping method based on retention time indexes. Specifically, we focus on the assignment and quantification of the isomers, which are coeluted in chromatograms. From this, we propose a new method using MS(n) spectral matching and the working curve on which are plotted the relative intensities of selected fragment ions in their MS(2) spectra versus various mixtures of the isomers. This new method demonstrated that the obtained quantities coincide very well with those estimated after separating by a combination of lectin and reversed-phase columns. This means that separation by RP-HPLC/MS is greatly simplified because complete separation of the isomers is no longer required. Application of this new method was tested by using the two other pairs of fucosylated and nonfucosylated PA-oligosaccharides from IgG. The results showed that this method works for them as well.     

Reappraisal of Size Effect of Bearing Capacity from Plastic Solution

A simplified method for estimating the ultimate bearing capacity of surface footings on sand is described with special attention to the dependency of the angle of internal friction of sand on confining stress. An extended slip line method is developed, in which the dependency of the angle of internal friction on the confining stress is formulated from results of conventional triaxial compression tests for various sands. Based on results from a comprehensive series of calculations employing the extended slip line method, the writers reappraise size effects on bearing capacity and investigate the relationship between strength parameters of sand and size effects on bearing capacity. A modified formula and several diagrams that provide a simple estimation method are proposed to consider size effects on bearing capacity. A comparison between estimations using the formula and ultimate bearing capacities measured from several series of centrifuge tests demonstrates the practicability of the proposed method for both strip and circular footings.     

The Safety and Anti-Tumor Effects of Ozonated Water in Vivo

Ozonated water is easier to handle than ozone gas. However, there have been no previous reports on the biological effects of ozonated water. We conducted a study on the safety of ozonated water and its anti-tumor effects using a tumor-bearing mouse model and normal controls. Local administration of ozonated water (208 mM) was not associated with any detrimental effects in normal tissues. On the other hand, local administration of ozonated water (20.8, 41.6, 104, or 208 mM) directly into the tumor tissue induced necrosis and inhibited proliferation of tumor cells. There was no significant difference in the number of terminal deoxynucleotidyl transferase-mediated deoxyuridine triphosphate-biotin nick-end labeling (TUNEL)-positive cells following administration of ozonated water. The size of the necrotic areas was dependent on the concentration of ozonated water. These results indicate that ozonated water does not affect normal tissue and damages only the tumor tissue by selectively inducing necrosis. There is a possibility that it exerts through the production of reaction oxygen species (ROS). In addition, the induction of necrosis rather than apoptosis is very useful in tumor immunity. Based on these results, we believe that administration of ozonated water is a safe and potentially simple adjunct or alternative to existing antineoplastic treatments.