Karbonatisierungszellen – Ein Beitrag zur Korrosion von Stahl in karbonatisiertem Beton

Carbonation cells – On the corrosion of steel in carbonated concrete Corrosion of steel in carbonated concrete involves the activity of active-passive galvanic couples (carbonation cells). Carbonation cells consisting of mortar electrodes in wet condition and subjected to wet-dry cycles have been investigated by means of current and potential measurements. The corrosion current can be explained in terms of oxygen diffusion through the mortar cover. The stationary current gives realistic values for the diffusion coefficient of oxygen in concrete. Changes from wet to dry and vice versa always increase the corrosion rate. Electrolytically and gravimetrically determined weight loss are in good agreement only for constant moisture conditions. In case of wetdry cycles oxidation and reduction reactions within the corrosion products are assumed to contribute to the total corrosion loss.     

A New Allenic Fatty Acid in Phlomis (Lamiaceae) Seed Oil

A new allenic fatty acid, phlomic acid, 7,8-eicosadienoic acid or 20:2Δ7,8allene, has been observed in several genera of the Lamiaceae, subfamily Lamioideae. The occurrence of this fatty acid seems to be correlated with the presence of an unusual 20:1 acid, 20:1Δ9cis or 20:1n–11. Phlomic acid is apparently produced by chain-elongation of the major seed oil fatty acid, laballenic acid or 18:2Δ5,6allene.     

A learning fedforward control strategy for the concentration control of recycle reactors. Part I: Set-point control

Unknown reaction rates make concentration control in laboratory recycle reactors a difficult task, particularly when gas chromatographs or other analytical equipment with long analysis times from part of the control system. For such time-delay systems, a model-based feedforward control technique is developed which uses some kind of learning linear mapping to provide estimates of the reaction rates. Regarding the number of time steps necessary to satisfy a new set point, in a variety of simulation studies, this technique has proven superior to similar but simpler control strategies.     

Evaluation of Crystallographic Data with the Program DIAMOND

The new crystal structure information system DIAMOND is presented. It handles all kinds of crystallographic databases on PCs including SHELX files and Chemical Information Files (CIF’s). DIAMOND, because of its graphics capability, is a powerful tool for establishing structural relationships and for evaluating crystallographic data.     

Evaluation of piping damage in German nuclear power plants

Information relating to piping damage in safety-relevant systems in German nuclear power plants with light water reactors (both pressurized water reactors (PWRs) and boiling water reactors (BWRs)) were analyzed with respect to the modes and the causes of damages. In general, the total range of observed piping damage is low. The incidents (82) in plants with PWRs affected mainly pipes with small diameters. Almost all damaged piping showed wall-penetrating cracks combined with leakages, which revealed the damage. Initial cracks at piping with larger diameters were discovered in isolated cases during in-service inspections. With regard to the incidents (71) in plants with BWRs, piping with small as well as large diameters was affected to different degrees. Wall-penetrating cracks combined with leakages were detected at piping with small diameters. For large-diameters pipes, cracks were indicated during in-service inspections and supplementary examinations. The results of the incident evaluations confirm the conservativeness of the safety concept chosen for the design of German nuclear power plants with light water reactors.     

The formation of hydroxy monocarboxylic acids and dicarboxylic acids by alkaline thermochemical degradation of cellulose

Treatment of cotton cellulose with 3 M sodium hydroxide solution at 260°C and 280°C gave a mixture of carboxylic acids with a yield of > 95%. The identified 50 carboxylic acids included both hydroxy monocarboxylic acids and dicarboxylic acids; their routes of formation are discussed. Among the main compounds were lactic, glycolic, 2-hydroxy-2-methylpropanoic, 2-hydroxybutanoic, 3,4-dideoxypentonic, anhydroisosaccharinic, 2,3-dideoxypentaric, and 3,4-dideoxyhexaric acids. Technical utilisation of this kind of acid mixture requires further studies. Investigations of the cyclic compounds, formed in small amounts only, resulted in identification of mainly alkyl-substituted 2-cyclopenten-1-ones.