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We use a carbon-cycle data assimilation system to estimate the terrestrial biospheric CO(2) flux until 2090. The terrestrial sink increases rapidly and the increase is stronger in the presence of climate change. Using a linearized model, we calculate the uncertainty in the flux owing to uncertainty in model parameters. The uncertainty is large and is dominated by the impact of soil moisture on heterotrophic respiration. We show that this uncertainty can be greatly reduced by constraining the model parameters with two decades of atmospheric measurements.  相似文献   
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Enabling the widespread utilization of poly[(3‐hydroxybutyrate)‐co‐(3‐hydroxyvalerate)] (PHBV) is strongly associated with enhancing its crystallization kinetics. In this article, we utilize a highly surface active (one reactive group per nanometer square) anion exchanged layered‐double hydroxide (LDH) functionalized by stearic acid to probe the crystallization kinetics of PHBV. Our prior work has shown that the addition of LDH decreases the cold crystallization and induces a melt recrystallization peak in PHBV. Since the melt‐recrystallization temperature shifted to higher temperature and its corresponding enthalpy increased with increasing LDH loading, this article is focused on understanding the effect of LDH on kinetics and energetics of PHBV crystallization. Both Avrami and Lauritzen–Hoffman modeling are utilized to develop a comprehensive understanding of thermal history effects through differential scanning calorimetry and polarized optical microscopy measurements. Five concentrations by weight of LDH are used: 1, 3, 5, and 7%. The results show that the addition of LDH promoted both primary and secondary nucleation at low concentrations but additional LDH resulted in primary nucleation alone. The crystallization rate and activation energy show a significant increase, which is accompanied by a decrease in the nucleation constant, the surface energy and the work of chain folding for PHBV crystallization. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2013  相似文献   
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The study describes the transformation of mangoes of the local variety \"Assabonou\" and papaya solo No.8 into alcohol and then into vinegar through the process of directed fermentation. Indeed, mango and papaya juices extracted from ripe fruits contained in vials are first subjected to an alcoholic fermentation with Saccharomyces cerevisiae in anaerobic conditions and secondly to an acetic fermentation with strains of acetic acid bacteria cultivated from unpasteurized cider vinegar. To assess the quality of the vinegars produced, their profile and composition in organic acid and volatile compounds were compared to those of an unpasteurized cider vinegar from France and a vinegar produced in Côte d’Ivoire. The ethanol content for both juices is more or less high with 9.24 ± 0.04 g/L for mango and 12.68 ± 0.39 g/L for papaya. The concentration of acetic acid is the highest of the organic acids for the four vinegars ranging from 37.46 ± 4.6 g/L to 55.85 ± 9.94 g/L. The acetic acid contents of mango and papaya vinegars are close to that of unpasteurized cider vinegar from France but higher than that of vinegar produced in Côte d'Ivoire. Thus, this study allowed the production of \"Assabonou\" mango and papaya vinegars from two consecutive fermentations (alcoholic then acetic). This process is fast, less expensive and easily applicable. This application case could be an alternative for the processing of seasonal fruits to reduce postharvest losses.  相似文献   
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The direct long‐fiber reinforced thermoplastic (D‐LFT) process offers a streamlined material processing technique and decreases the degradation of the material. To ensure product consistency and process optimization, it is imperative to understand how the process sequence affects degradation and thermal properties of the material during the D‐LFT process. This study investigates variation in molecular weight and thermal properties of the glass fiber reinforced polyamide 6 (PA6) composites throughout the D‐LFT process. Viscosity number (VN) measurements, thermogravimetric analyses (TGA), and differential scanning calorimetry (DSC) analyses were performed on samples taken from different locations along the D‐LFT process. It was found that VN, which is a measure of molecular weight of the PA6 base resin, decreased throughout the processes. In contrast, TGA results suggested that apparent activation energy for decomposition increased during consecutive process stages. Non‐isothermal DSC results showed that there were no significant changes to the degree of crystallization; however, isothermal DSC results indicated that later stages of the process showed a decrease in crystallization half‐time, and the largest changes were observed in areas after the two extrusion portions of the process. POLYM. ENG. SCI., 58:46–54, 2018. © 2017 Society of Plastics Engineers  相似文献   
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The Carnoulès Pb mine closed 40 years ago, leaving tailings (pyrite-rich silts) exposed. In 1982, the tailings were gathered and placed behind a concrete dam, above a drainage pipe, and then covered with a clay layer. The As-rich pyrite in the tailings has oxidized; acidic water with high As concentrations (100–350 mg/L As) now emerges from the base of the dam. Strikingly, there is no oxidation zone at the surface of the tailings. The clay cover and the low hydraulic conductivity of most of the tailings (10−7 m/s) strongly limit rainwater infiltration. Water table variations, water balance calculations, and flow modelling indicate subsurface water input and water flow along the bedrock within a more permeable sandy horizon. This lower horizon is strongly oxidized due to this flow pattern. The As-rich water is mainly produced in the northern part of the tailings area, where seasonal variations in the water table (a succession of aerobic/anaerobic periods) are important. This water flows through a drainage pipe to an acidic spring. The disposal of tailings can release acidic and toxic waters into the environment. Monitoring and modelling of such tailings allow one to define the potential impact and propose remedies.  相似文献   
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In this study, total coliforms, thermotolerant coliforms, Escherichia coli and groundwater nitrate concentration were monitored at 127 groundwater sampling points (only 62 water points for bacteriological parameters) located in the southern part of Abidjan District. Each water sampling location was sampled in March and July 2007, representing respectively the long dry season and the long wet season. Geostatistical methods were used to analyze the spatial variability of nitrates and the groundwater nitrate pollution risk. The maximum seasonal content of total coliforms and thermotolerant coliforms ranged from 400 to 1000 CFU/100 mL and from 200 to 500 CFU/100 mL respectively. Moreover, 94% of these locations presented traces of bacteriological contamination. This contamination was mainly recorded during the rainy period. The degree of correlation between bacterial abundance and chemical parameters is variable. Nitrites, ammonium and potassium favoured coliform abundance. In the 127 water points, groundwater nitrate concentrations ranged from 4 to 198 mg L?1 and were log-normally distributed in the study area. The groundwater contamination risk map indicated that the strongly urbanized west side of the site presented a high probability of exceeding the WHO drinking water standard (50 mg L?1NO3?).  相似文献   
18.
Electro-activation (EA) of a maple sap/syrup beverage was studied. The purpose of the study was to assess the product parameters, such as pH, ORP, transmittance and degree Brix, while minimizing energy consumption. The experiments were conducted using three different configurations of the reactor that differed by the position of the anion (AEM) and cation (CEM) exchange membrane relative to the electrodes as well as the nature of the electrolyte (NaCl vs. Na2CO3) in the central cell of the reactor. The results showed that the type of configuration, the electric current and the temperature influenced the parameters of the electro-activated beverage. At 23 °C, the beverage was acidified to pH 3.89 with a Redox potential (ORP) of 417.33 mV. At 55 °C and 150 mA, the minimum pH of 3.78 and an ORP of 329.67 mV were obtained. The electric resistance of the electro-activation reactor (EAR) decreased during electro-activation, indicating a gain of energy efficiency corresponding to an electric resistance of 266.76 Ω. Moreover, the reactor configuration and electric current affected the presence or absence of a fouling of the ion exchange membrane at the anodic side. The beverages' transmittance increased slightly during EA without any effect on the degree Brix.  相似文献   
19.
Remote-sensing image classification is one of the most important techniques in understanding the dynamics of the Earth's ecosystems. Various approaches have been proposed for performing this classification task. Obtained classification results are generally shown as a thematic (or class) map in which each pixel is assigned a class label. Due to sensor noise and algorithm limitations, obtained thematic maps are very noisy. The noise has a “salt-and-pepper” appearance in homogeneous regions and produces weakly defined interregion borders. In this paper, a new postprocessing approach aiming to produce thematic maps with sharp interregion boundaries and homogeneous regions is presented. This approach is conducted in two steps: (1) relevant features derived from the original multispectral image (edge maps) as well as from the thematic map, the Smoothed Thematic Map (STM), are determined and (2) a region-growing algorithm is applied over the thematic map. This algorithm grows until reaching an edge (from the edge maps) or a class change in the STM. The proposed approach fills the requirements of being independent of the used classification algorithm and not knowledge-based (in the sense that no a priori information concerning the contents of the considered image is needed). Tests have been conducted on a Landsat image covering mainly agricultural areas  相似文献   
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Software development projects are renown for exhibiting chaotic outcomes despite the application of recent development process paradigms. This paper argues that the development culture followed by a software project greatly contributes at a deeper level to its ultimate outcome. Five such cultures are discussed: the calendar driven culture, the requirements driven culture, the documentation driven culture, the quality driven culture, and the architecture driven culture. Each culture is characterized by the priority of objectives that it selects and the artifacts that it predominantly generates. Cultural shifts throughout a project life cycle are also often identified as unconscious responses to pressure exercised by the project stakeholders. This article presents a conceptual model that captures the cultural profile of a software project and estimates the cost and/or difficulty of shifting from one culture to another. Changing cultures can have severe consequences on a project success. An improved knowledge of the nature and objectives of each culture combined with a keen awareness of the impact of shifting cultures can mitigate chaotic outcomes by enabling better decision‐making throughout a software project life cycle. The paper also attempts to establish the extent to which the results are also relevant to the Systems Engineering discipline. © 2005 Wiley Periodicals, Inc. Syst Eng 8: 151–163, 2005  相似文献   
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