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531.
Toshiyuki Kondo Takahiro Imaoka Hiroyuki Hirakata Masayuki Sakihara Kohji Minoshima 《Acta Materialia》2013,61(16):6310-6327
The dominant mechanics and mechanisms of fatigue crack propagation in ca. 500 nm thick free-standing copper films were evaluated at the submicron level using fatigue crack propagation experiments at three stress ratios, R = 0.1, 0.5 and 0.8. Fatigue cracking initiated at the notch root and propagated stably under cyclic loading. The fatigue crack propagation rate (da/dN) vs. stress intensity factor range (ΔK) relation was dependent on the stress ratio R;da/dN, increases with increasing R. Plots of da/dN vs. the maximum stress intensity factor (Kmax) exhibited coincident features in the high-Kmax region (Kmax ? 4.5 MPa m1/2) irrespective of R, indicating that Kmax is the dominant factor in fatigue crack propagation. In this region, the fatigue crack propagated in tensile fracture mode irrespective of the R value. The region ahead of the fatigue crack tip is plastically stretched by tensile deformation, causing necking deformation in the thickness direction and consequent chisel-point fracture. In contrast, in the low-Kmax region (Kmax < 4.5 MPa m1/2), the da/dN vs. Kmax function assumes higher values with decreasing R; in this region, the fracture mechanism depends on R. At the higher R value (R = 0.8), the fatigue crack propagates in the tensile fracture mode similar to that in the high-Kmax region. On the other hand, at the lower R values (R = 0.1 and 0.5), a characteristic mechanism of fatigue crack propagation appears: within several grains, intrusions/extrusions form ahead of the crack tip along the Σ3 twin boundaries, and the fatigue crack propagates preferentially through the intrusions/extrusions. 相似文献
532.
Lately, it is required that the bandwidth of PWM (pulse width modulation) power amplifier is extended. For example, it is in application of the testing power supply of a low frequency immunity examination, or a class-D amplifier. In this paper, the authors show that the bandwidth of PWM power amplifier can be controller. This controller is implemented on a DSP (digital can be made wider with this controller. extended by using an approximate 2DOF (2-degree-of-freedom) digital signal processor). It is demonstrated from experiments that the bandwidth 相似文献
533.
Mouri E Okazaki Y Komune S Yoshinaga K 《Journal of nanoscience and nanotechnology》2011,11(3):2486-2495
We have studied poly(methyl methacrylate)-grafted(PMMA) particle monolayer systems at the air-water interface. In previous papers, we reported that PMMA chains grafted from particles (silica particle and polystyrene latex) were extended on water surfaces. Through observing deposited particle monolayers on substrates using SEM, we have confirmed that PMMA of large molecular weights were either dispersed or arrayed in structure with long inter-particle distances approximately 500 nm. In contrast, low molecular weight PMMA were observed to aggregate upon deposition. We speculated that the difference in morphology in deposited particle monolayers would be attributed to the affinity between the grafted polymer and the substrate. To examine the effect of this affinity three new polymer-grafted silica particles were synthesized with a fairly high graft density of about 0.14 approximately 0.43 nm(-2). As well as PMMA-grafted silica particles (SiO2-PMMA), poly(2-hydroxyethyl methacrylate) and poly(t-butyl methacrylate)--grafted silica particles (SiO2-PHEMA and SiO2-PtBuMA) were also prepared and subjected to pi-A isotherm measurements and SEM observations. These pi-A isotherms indicated that polymer-grafted silica formed monolayer at the air-water interface, and the onset area of increasing surface pressure suggests that the polymer chains are extended on a water surface. However, the morphology of the deposited monolayer is highly dependent on polymer species: SiO2-PHEMA showed that the dispersed particle monolayer structure was independent of grafted molecular weight while SiO2-tBuMA showed an aggregated structure that was also independent of grafted moleculer weight. SiO2-PMMA showed intermediate tendencies: dispersed structure was observed with high grafted molecular weight and aggregated structure was observed with low grafted molecule weight. The morphology on glass substrate would be explaiened by hydrophilic interaction between grafted polymer and hydrophilic glass substrate. 相似文献
534.
535.
Lorenzo Marcucci Hiroki Fukunaga Toshio Yanagida Mitsuhiro Iwaki 《International journal of molecular sciences》2021,22(13)
Muscle energetics reflects the ability of myosin motors to convert chemical energy into mechanical energy. How this process takes place remains one of the most elusive questions in the field. Here, we combined experimental measurements of in vitro sliding velocity based on DNA-origami built filaments carrying myosins with different lever arm length and Monte Carlo simulations based on a model which accounts for three basic components: (i) the geometrical hindrance, (ii) the mechano-sensing mechanism, and (iii) the biased kinetics for stretched or compressed motors. The model simulations showed that the geometrical hindrance due to acto-myosin spatial mismatching and the preferential detachment of compressed motors are synergic in generating the rapid increase in the ATP-ase rate from isometric to moderate velocities of contraction, thus acting as an energy-conservation strategy in muscle contraction. The velocity measurements on a DNA-origami filament that preserves the motors’ distribution showed that geometrical hindrance and biased detachment generate a non-zero sliding velocity even without rotation of the myosin lever-arm, which is widely recognized as the basic event in muscle contraction. Because biased detachment is a mechanism for the rectification of thermal fluctuations, in the Brownian-ratchet framework, we predict that it requires a non-negligible amount of energy to preserve the second law of thermodynamics. Taken together, our theoretical and experimental results elucidate less considered components in the chemo-mechanical energy transduction in muscle. 相似文献
536.
ABSTRACT: The Nano Spray Dryer B-90 offers a new, simple and alternative approach for the production of drug nanocrystals. Among attractive drugs, calpain inhibitor that inhibits programmed cell death "apoptosis" is candidate for curing apoptosis-mediated intractable disease such as Alzheimer's and Parkinson's disease. In this study, the preparation of calpain inhibitor nanocrystals by Nano Spray Dryer B-90 was demonstrated. The particle sizes were controlled by means of selecting mesh aperture sizes. The obtained average particle sizes were in the ranges of around 300 nm to submicron meter. 相似文献
537.
Kajornsak Faungnawakij Naohiro Shimoda Tetsuya Fukunaga Ryuji Kikuchi Koichi Eguchi 《Applied Catalysis A: General》2008,341(1-2):139-145
Cu-based spinel-oxides CuB2O4 (B = Fe, Mn, Cr, Ga, Al, or Fe0.75Mn0.25) were synthesized via a sol–gel method and subsequent solid-state reaction. The spinels mechanically mixed with γ-Al2O3 were evaluated for production of hydrogen from dimethyl ether steam reforming (DME SR). The reduction behavior and crystal property of these spinel-oxides, and the Cu oxidation state in spinel catalysts were investigated by temperature-programmed reduction, X-ray diffraction, and X-ray photoelectron spectroscopy techniques. The reduced phases of the Cu-based spinel catalysts that strongly affected the catalytic activity and durability were composed of metallic copper with metal oxides (MnO (B = Mn), Cr2O3 (B = Cr), and Al2O3 (B = Al)) or with spinels (CuGa2O4 (B = Ga), Fe3O4 (B = Fe), and MnFe2O4 (B = Fe0.75Mn0.25). The stability of B metal oxides and the interaction between copper species and B metal oxides significantly contributed to the reforming performance. 相似文献
539.
Salmon Protamine Decreases Serum and Liver Lipid Contents by Inhibiting Lipid Absorption in an In Vitro Gastrointestinal Digestion Model and in Rats 下载免费PDF全文
Ryota Hosomi Kazumasa Miyauchi Daiki Yamamoto Hirofumi Arai Toshimasa Nishiyama Munehiro Yoshida Kenji Fukunaga 《Journal of food science》2015,80(10):H2346-H2353
Protamine has been used as an antiheparin drug and a natural preservative in various food products. However, limited studies have evaluated the physicochemical and functional properties of protamine. Hence, we assessed the mechanisms underlying the inhibition of lipid absorption following salmon protamine intake in in vitro and in vivo studies. In initial experiments, a salmon protamine hydrolyzate (PH) was prepared using in vitro simulated gastrointestinal digestion suppressed pancreatic lipase activity and micellar cholesterol solubility. This PH had higher bile acid‐binding capacity and emulsion breakdown activity than casein hydrolyzate and l ‐arginine. However, the hypolipidemic functions of protamine were dramatically reduced by pancreatin digestion. In further experiments, groups of male Wistar rats were fed an AIN‐93G diet containing 5% (wt/wt) salmon protamine or a protamine amino acid mixture. After 4 wk of feeding with experimental diets, reductions in serum and liver triacylglycerol (TAG) and cholesterol contents were observed in the presence of protamine, reflecting inhibition of TAG, cholesterol, and bile acid absorption. These data suggest that the formation of insoluble PH–bile acid complexes is critical before the bile acid‐binding capacity is reduced. Therefore, dietary salmon protamine may ameliorate lifestyle‐related diseases such as hyperlipidemia and obesity. 相似文献
540.
Yuan Li Naoki Hori Masahiro Arai Ning Hu Yaolu Liu Hisao Fukunaga 《Composites Part A》2009,40(12):2004-2012
In order to improve the interlaminar mechanical properties of CFRP laminates, hybrid CFRP/VGCF laminates have been fabricated by using a newly-developed method, i.e., powder method, where the powder of vapor grown carbon fiber (VGCF) is added at the mid-plane of [0°/0°]14 CFRP laminates. Experimental results of double cantilever beam (DCB) tests indicate the improvement on the interlaminar mechanical properties of Mode-I fracture behavior with much higher critical load PC and fracture toughness GIC with VGCF interlayer. Crack propagation and fracture surface have also been observed to interpret this improvement mechanism. Moreover, based on experimental GIC, numerical simulations using finite element method (FEM) with cohesive elements have been carried out to analyze the delamination propagation. The interlaminar tensile strength of hybrid CFRP/VGCF laminates, which is obtained by matching the numerical load–COD (crack opening displacement) curves to experimental ones, is higher than that of base CFRP laminates. 相似文献